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1.	Chien, Yu-Chuan, 1990-, et al. (författare) Correlations between precipitation reactions and electrochemical performance of lithium-sulfur batteries probed by operando scattering techniques 2022 Ingår i: Chem. - : Elsevier. - 2451-9294. ; 8:5 Tidskriftsartikel (refereegranskat)abstract A comprehensive description of electrochemical processes in the positive electrode of lithium-sulfur batteries is crucial for the utilization of active material. However, the discharge mechanisms are complicated due to various reactions in multiple phases and the tortuosity of the highly porous carbon matrix. In this work, simultaneous measurements of small-angle and wide-angle scattering and cell resistance are performed on operating lithium-sulfur cells. Results indicate that precipitates grow mostly in number, not in size, and that the structure of the carbon matrix is not affected. The comparison of the small-angle and wide-angle scattering reveals the amorphous discharge products found at a low discharge rate. Further analysis demonstrates the correlation between the diffusion resistance and the compositional change of electrolyte in the mesopores at the end of discharge, which suggests that Li-ion deficiency is the limiting factor for sulfur utilization at a medium discharge rate.

Chien, Yu-Chuan, 1990-, et al. (författare)
Correlations between precipitation reactions and electrochemical performance of lithium-sulfur batteries probed by operando scattering techniques
2022
Ingår i: Chem. - : Elsevier. - 2451-9294. ; 8:5
Tidskriftsartikel (refereegranskat)abstract
- A comprehensive description of electrochemical processes in the positive electrode of lithium-sulfur batteries is crucial for the utilization of active material. However, the discharge mechanisms are complicated due to various reactions in multiple phases and the tortuosity of the highly porous carbon matrix. In this work, simultaneous measurements of small-angle and wide-angle scattering and cell resistance are performed on operating lithium-sulfur cells. Results indicate that precipitates grow mostly in number, not in size, and that the structure of the carbon matrix is not affected. The comparison of the small-angle and wide-angle scattering reveals the amorphous discharge products found at a low discharge rate. Further analysis demonstrates the correlation between the diffusion resistance and the compositional change of electrolyte in the mesopores at the end of discharge, which suggests that Li-ion deficiency is the limiting factor for sulfur utilization at a medium discharge rate.

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