| 1. |
- Holtstam, Dan, 1963-, et al.
(författare)
-
Ferri-taramite, a new member of the amphibole supergroup, from the Jakobsberg Mn-Fe deposit, Varmland, Sweden
- 2022
-
Ingår i: European Journal of Mineralogy. - : Copernicus GmbH. - 0935-1221 .- 1617-4011. ; 34:5, s. 451-462
-
Tidskriftsartikel (refereegranskat)abstract
- Ferri-taramite (IMA CNMNC 2021-046), ideally Na-A(B) (CaNa)(C) (Mg3Fe23+)(Si6Al2)O-22(W) (OH)(2), occurs in skarn from the Jakobsberg manganese mine, Varmland, Sweden. Associated minerals are celsian, phlogopite, aegirine-augite, andradite, hancockite, melanotekite, microcline (var. hyalophane), calcite, baryte, prehnite, macedonite and oxyplumboromeite. Conditions of formation, close to peak metamorphism (at circa 650 degrees C and 0.4 GPa), include silica undersaturation, a slightly peralkaline character and relatively high oxygen fugacities. Ferri-taramite forms poikiloblastic crystals up to 5 mm and is dark brownish black with a yellowish grey streak. The amphibole is brittle with an uneven to splintery fracture. Cleavage parallel to {110} is good. Hardness (Mohs) is similar to 6, and D-calc = 3.227(5) g cm(-3). Holotype ferri-taramite has the experimental unit formula (A)(Na0.79K0.16Pb0.01)(Sigma 0.96)(B) (Ca1.26Na0.72Mn0.022+)(Sigma 2)(C )(Mg2.66Mn0.582+ Fe0.162+Zn0.02Fe1.263+ Al0.26Ti0.06)(Sigma)(T)(5.00) (Al1.86Si6.14)Sigma 8O(22)(W) (OH)(2), based on chemical analyses (EDS, laser-ablation ICP-MS) and spectroscopic (Mossbauer, infrared) and single-crystal X-ray diffraction data. The mineral is optically biaxial (-), with alpha = 1.670(5), beta = 1.680(5) and gamma = 1.685(5) in white light and 2 V-meas = 70(10)degrees and 2 V-calc = 70.2 degrees. Ferri-taramite is distinctly pleochroic in transmitted light, with X pale yellow, Y dark brown, Z yellowish brown and absorption Y> Z> X. The eight strongest reflections in the X-ray powder pattern (d values (in angstrom), I-rel, hkl) are 8.44, 60, 110; 3.392, 25, 131; 3.281, 39, 240; 3.140, 100, 310; 2.816, 45, 330; 2.7104, 38, 151; 1.3654, 26, 461; and 1.4451, 33, (6) over bar 61. Refined unit-cell parameters from single-crystal diffraction data are a = 9.89596(13), b = 18.015(2), c = 5.32164(7) angstrom, beta = 105.003(13)degrees and V = 916.38(2) angstrom(3) for Z = 2. Refinement of the crystal structure yielded R = 2.26 % for 2722 reflections with I-0 >2 sigma (I). The Mn2+ and Fe2+ ions show preference for the M1 and M3 octahedrally coordinated sites, whereas Fe3+ is strongly ordered at M2. The A-group cations, K and Na, are split over two subsites, A (m) and A(2), respectively.
|
|
