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- Alwahabi, Z. T., et al.
(författare)
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High resolution polarization spectroscopy and laser induced fluorescence of CO2 around 2 mu m
- 2007
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Ingår i: European Physical Journal D. Atomic, Molecular, Optical and Plasma Physics. - : Springer Science and Business Media LLC. - 1434-6060. ; 42:1, s. 41-47
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Tidskriftsartikel (refereegranskat)abstract
- High resolution Infrared Polarisation Spectroscopy (IRPS) and Infrared Laser Induced Fluorescence (IRLIF) techniques were used to probe CO2/N-2 binary gas mixture at atmospheric pressure and ambient temperature. The probed CO2 molecules were prepared by laser excitation to an overtone and combination ro-vibrational state (12(0)1, J = 15) of CO2, centred at 4988.6612 cm(-1). IRPS and IRLIF line profiles were recorded for several CO2/N-2 binary mixtures. The observed IRLIF line shapes have the expected Lorentzian form while the observed IRPS line shapes are narrower by a factor of two than those recorded with the IRLIF and appear to have a Lorentzian-cubed profile. The recorded line profiles provide measurements of the pressure-broadening coefficient directly at atmospheric pressure. The Full-Width-Half-Maxima (FWHM) pressure broadening coefficients are measured, based on IRLIF, to be 0.2174 0.0092 cm(-1) atm(-1) and 0.1327 +/- 0.0077 cm(-1) atm(-1) for self- and N-2 collision broadening, respectively. The broadening coefficients obtained based on IRPS were measured to be similar to 8% larger than those obtained with IRLIF.
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