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- Dittmer, Staffan, 1970, et al.
(författare)
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Local heating method for growth of aligned carbon nanotubes at low ambient temperature
- 2008
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Ingår i: Low Temperature Physics. - : AIP Publishing. - 1063-777X .- 1090-6517. ; 34:10, s. 834-838
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Tidskriftsartikel (refereegranskat)abstract
- We use a highly localised resistive heating technique to grow vertically aligned multiwalled nanotube films and aligned single-walled nanotubes on substrates with an average temperature of less than 100oC. The temperature at the catalyst can easily be as high as 1000 oC but an extremely high temperature gradient ensures that the surrounding chip is held at much lower temperatures, even as close as 1μm away from the local heater. We demonstrate the influence of temperature on the height of multi-walled nanotube films, illustrate the feasibility of sequential growth of single-walled nanotubes by switching between local heaters and also show that nanotubes can be grown over temperature sensitive materials such as resist polymer.
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- Dolbin, Alexander V, et al.
(författare)
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Radial thermal expansion of single-walled carbon nanotube bundles at low temperatures.
- 2008
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Ingår i: Fizika Nizkikh Temperatur. - : AIP Publishing. - 0132-6414. ; 34:8, s. 860-862
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Tidskriftsartikel (refereegranskat)abstract
- For the first time, the linear coefficient of radial thermal expansion is measured on a system of carbon single-walled nanotube (SWNT) bundles at low temperatures (2.2–120 K). The measurements are performed using a dilatometer with a sensitivity of 2×10−9 cm. A cylindrical sample 7 mm high and 10 mm in diameter was obtained by compressing powder. The resulting bundles of nanotubes are oriented perpendicular to the sample axis. The starting powder consisted of over 90% SWNTs with outer diameter 1.1 nm, the length varying in the range 5–30 µm. A change of sign of the radial thermal expansion coefficient at 5.5 K is observed.
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3. |
- Dolbin, Alexander V., et al.
(författare)
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The effect of the noncentral impurity-matrix interaction upon the thermal expansion and polyamorphism of solid CO-C60 solutions at low temperatures
- 2008
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Ingår i: Fizika Nizkikh Temperatur. - : AIP Publishing. - 0132-6414. ; 34:6, s. 592-598
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Tidskriftsartikel (refereegranskat)abstract
- Orientational glasses with CO molecules occupying 26 and 90% of the octahedral interstitial sites in the C60 lattice have been investigated by the dilatometric method in a temperature interval of 2.5–22 K. At temperatures 4–6 K the glasses undergo a first-order phase transition which is evident from the hysteresis of the thermal expansion and the maxima in the temperature dependences of the linear thermal expansion coefficients a(T), and the thermalization times t1(T) of the samples. The effect of the noncentral CO–C60 interaction upon the thermal expansion and the phase transition in these glasses was clarified by comparing the behavior of the properties of the CO–C60 and N2–C60 solutions.
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4. |
- Grechnev, G. E., et al.
(författare)
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Electronic structure and bulk properties of MB6 and MB12 borides
- 2008
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Ingår i: Low temperature physics (Woodbury, N.Y., Print). - : AIP Publishing. - 1063-777X .- 1090-6517. ; 34:11, s. 921-929
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Tidskriftsartikel (refereegranskat)abstract
- Ab initio band structure calculations are carried out for the higher borides MB6 and MB12. High-precision measurements of the elastic constants are performed for the compounds ZrB12, HoB12, ErB12, TmB12, LuB12, YB6 and LaB6 at low temperatures. The bulk properties of the borides are analyzed on the basis of the calculated equations of states and balanced crystal orbital overlap populations. Our calculations indicate that hexaborides with divalent metals, CaB6, SrB6, BaB6, and YbB6, are semiconductors with small energy gaps. The metallic MB6 hexaborides with trivalent M atoms are found to possess larger bulk moduli values. For dodecaborides the bulk moduli are found to be higher for MB12 with increased filling of the conduction band (ZrB12, HfB12, UB12) in comparison with M3+B12 compounds. The total energy calculations for different magnetic configurations in YbB12 point to the possibility of antiferromagnetic coupling between Yb3+ ions.
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