| 1. |
- A. da Cruz, Márcia G., et al.
(författare)
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Electrochemical Depolymerization of Lignin in a Biomass-based Solvent
- 2022
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Ingår i: ChemSusChem. - : Wiley. - 1864-5631 .- 1864-564X. ; 15:15
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Tidskriftsartikel (refereegranskat)abstract
- Breaking down lignin into smaller units is the key to generate high value-added products. Nevertheless, dissolving this complex plant polyphenol in an environment-friendly way is often a challenge. Levulinic acid, which is formed during the hydrothermal processing of lignocellulosic biomass, has been shown to efficiently dissolve lignin. Herein, levulinic acid was evaluated as a medium for the reductive electrochemical depolymerization of the lignin macromolecule. Copper was chosen as the electrocatalyst due to the economic feasibility and low activity towards the hydrogen evolution reaction. After depolymerization, high-resolution mass spectrometry and nuclear magnetic resonance spectroscopy revealed lignin-derived monomers and dimers. A predominance of aryl ether and phenolic groups was observed. Depolymerized lignin was further evaluated as an anti-corrosion coating, revealing enhancements on the electrochemical stability of the metal. Via a simple depolymerization process of biomass waste in a biomass-based solvent, a straightforward approach to produce high value-added compounds or tailored biobased materials was demonstrated.
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| 2. |
- A. da Cruz, Marcia Gabriely, et al.
(författare)
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On the product selectivity in the electrochemical reductive cleavage of 2-phenoxyacetophenone, a lignin model compound
- 2022
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Ingår i: Green Chemistry Letters and Reviews. - : Informa UK Limited. - 1751-8253 .- 1751-7192. ; 15:1, s. 151-159
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Tidskriftsartikel (refereegranskat)abstract
- Research towards the production of renewable chemicals for fuel and energy industries has found lignin valorization as key. With a high carbon content and aromaticity, a fine-tuning of the depolymerization process is required to convert lignin into valuable chemicals. In context, model compounds have been used to understand the electrocatalyzed depolymerization for mimicking the typical linkages of lignin. In this investigation, 2-phenoxyacetophenone, a model compound for lignin beta-O-4 linkage, was electro-catalytically hydrogenated (ECH) in distinct three-electrode setups: an open and a membrane cell. A deep eutectic solvent based on ethylene-glycol and choline chloride was used to pursue sustainable routes to dissolve lignin. Copper was used as electrocatalyst due to the economic feasibility and low activity towards hydrogen evolution reaction (HER), a side reaction of ECH. By varying the cell type, we demonstrate a simple ECH route for the generation of different monomers and oligomers from lignin. Gas chromatography of the products revealed a higher content of carbonyl groups in those using the membrane cell, whereas the open cell produced mostly hydroxyl-end chemicals. Aiming at high value-added products, our results disclose the cell type influence on electrochemical reductive depolymerization of lignin. This approach encompasses cheap transition metal electrodes and sustainable solvents.
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| 3. |
- Aaby, Anders, et al.
(författare)
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Does the Danish version of the Spinal Cord Lesion-related Coping Strategies Questionnaire measure what we think it measures? : A triangulated mixed-methods validation approach
- 2022
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Ingår i: Spinal Cord. - : SPRINGERNATURE. - 1362-4393 .- 1476-5624.
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Tidskriftsartikel (refereegranskat)abstract
- Study design: Triangulated mixed-methods validation study.Objectives: To validate the Danish version of the Spinal Cord Lesion-related Coping Strategies Questionnaire (SCL-CSQ).Setting: Community in Denmark.Methods: Participants were invited via a patient organization and its specialized hospital. Eligibility criteria were having a spinal cord injury (SCI), being 18 years or older, and able to understand and respond in Danish. Quantitative data were collected to determine internal consistency and criterion validity of the three subscales of SCL-CSQ, i.e., acceptance, fighting spirit, and social reliance. The Three-Step Test-Interview approach was employed to determine whether items measured what they were intended to measure (i.e., construct validity based on response processes).Results: The quantitative sample consisted of 107 participants, and the interview sample comprised 11 participants. The acceptance and fighting spirit subscales showed adequate internal consistency (Cronbach's alpha of 0.72 and 0.76 respectively) and satisfactory criterion validity (expected correlations with quality of life and depression). The social reliance subscale showed inadequate internal consistency (Cronbach's alpha of 0.58) and criterion validity. All fighting spirit items and all but one acceptance items were interpreted congruently by most participants. Conversely, two social reliance items were only interpreted congruently by 9 and 27%.Conclusion: The acceptance and fighting spirit subscales of the Danish version of the SCL-CSQ showed good psychometric properties, while the social reliance subscale showed serious issues and should be revised. Researchers and clinicians are urged to reflect on these findings when revising the SCL-CSQ or adapting it to other languages, cultural contexts, and rehabilitation settings.
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| 4. |
- Aad, G., et al.
(författare)
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A detailed map of Higgs boson interactions by the ATLAS experiment ten years after the discovery
- 2022
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Ingår i: Nature. - : Nature Research. - 0028-0836 .- 1476-4687. ; 607:7917, s. 52-59
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Tidskriftsartikel (refereegranskat)abstract
- The standard model of particle physics1–4 describes the known fundamental particles and forces that make up our Universe, with the exception of gravity. One of the central features of the standard model is a field that permeates all of space and interacts with fundamental particles5–9. The quantum excitation of this field, known as the Higgs field, manifests itself as the Higgs boson, the only fundamental particle with no spin. In 2012, a particle with properties consistent with the Higgs boson of the standard model was observed by the ATLAS and CMS experiments at the Large Hadron Collider at CERN10,11. Since then, more than 30 times as many Higgs bosons have been recorded by the ATLAS experiment, enabling much more precise measurements and new tests of the theory. Here, on the basis of this larger dataset, we combine an unprecedented number of production and decay processes of the Higgs boson to scrutinize its interactions with elementary particles. Interactions with gluons, photons, and W and Z bosons—the carriers of the strong, electromagnetic and weak forces—are studied in detail. Interactions with three third-generation matter particles (bottom (b) and top (t) quarks, and tau leptons (τ)) are well measured and indications of interactions with a second-generation particle (muons, μ) are emerging. These tests reveal that the Higgs boson discovered ten years ago is remarkably consistent with the predictions of the theory and provide stringent constraints on many models of new phenomena beyond the standard model.
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| 5. |
- Aad, G., et al.
(författare)
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Constraints on Higgs boson properties using WW*(-> e nu mu nu)jj production in 36.1 fb(-1) of root s=13 TeV pp collisions with the ATLAS detector
- 2022
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Ingår i: European Physical Journal C. - : Springer. - 1434-6044 .- 1434-6052. ; 82:7
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Tidskriftsartikel (refereegranskat)abstract
- This article presents the results of two studies of Higgs boson properties using the WW*(-> e nu mu nu)jj final state, based on a dataset corresponding to 36.1fb(-1) of root s = 13 TeV proton-proton collisions recorded by the ATLAS experiment at the Large Hadron Collider. The first study targets Higgs boson production via gluon-gluon fusion and constrains the CP properties of the effective Higgs-gluon interaction. Using angular distributions and the overall rate, a value of tan (alpha) = 0.0 +/- 0.4(stat.) +/- 0.3(syst.) is obtained for the tangent of the mixing angle for CP-even and CP-odd contributions. The second study exploits the vector-boson fusion production mechanism to probe the Higgs boson couplings to longitudinally and transversely polarised W and Z bosons in both the production and the decay of the Higgs boson; these couplings have not been directly constrained previously. The polarisation-dependent coupling-strength scale factors are defined as the ratios of the measured polarisation-dependent coupling strengths to those predicted by the Standard Model, and are determined using rate and kinematic information to be a(L) = 0.91(-0.18)(+0.10)(stat.)(-0.17)(+0.09)(syst.) and a(T) = 1.2 +/- 0.4(stat.)(-0.3)(+0.2)(syst.). These coupling strengths are translated into pseudo-observables, resulting in kappa(VV) = 0.91(-0.18)(+0.10)(stat.)(-0.17)(+0.09)(syst.) and epsilon(VV) = 0.13(-0.20)(+0.28)(stat.)(-0.10)(+0.08)(syst.). All results are consistent with the Standard Model predictions.
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| 6. |
- Aad, G., et al.
(författare)
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Emulating the impact of additional proton–proton interactions in the ATLAS simulation by presampling sets of inelastic Monte Carlo events
- 2022
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Ingår i: Computing and Software for Big Science. - : Springer Science and Business Media LLC. - 2510-2044 .- 2510-2036. ; 6:1
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Tidskriftsartikel (refereegranskat)abstract
- The accurate simulation of additional interactions at the ATLAS experiment for the analysis of proton–proton collisions delivered by the Large Hadron Collider presents a significant challenge to the computing resources. During the LHC Run 2 (2015–2018), there were up to 70 inelastic interactions per bunch crossing, which need to be accounted for in Monte Carlo (MC) production. In this document, a new method to account for these additional interactions in the simulation chain is described. Instead of sampling the inelastic interactions and adding their energy deposits to a hard-scatter interaction one-by-one, the inelastic interactions are presampled, independent of the hard scatter, and stored as combined events. Consequently, for each hard-scatter interaction, only one such presampled event needs to be added as part of the simulation chain. For the Run 2 simulation chain, with an average of 35 interactions per bunch crossing, this new method provides a substantial reduction in MC production CPU needs of around 20%, while reproducing the properties of the reconstructed quantities relevant for physics analyses with good accuracy.
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| 7. |
- Aad, G., et al.
(författare)
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Measurement of the c-jet mistagging efficiency in t(t)over-bar events using pp collision data at root s=13 TeV collected with the ATLAS detector
- 2022
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Ingår i: European Physical Journal C. - : Springer. - 1434-6044 .- 1434-6052. ; 82:1
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Tidskriftsartikel (refereegranskat)abstract
- A technique is presented to measure the efficiency with which c-jets are mistagged as b-jets (mistagging efficiency) using t (t) over bar events, where one of theW bosons decays into an electron or muon and a neutrino and the other decays into a quark-antiquark pair. The measurement utilises the relatively large and known W -> cs branching ratio, which allows ameasurement to be made in an inclusive c-jet sample. The data sample used was collected by the ATLAS detector at root s = 13 TeV and corresponds to an integrated luminosity of 139 fb(-1). Events are reconstructed using a kinematic likelihood technique which selects the mapping between jets and t (t) over bar decay products that yields the highest likelihood value. The distribution of the b-tagging discriminant for jets from the hadronic W decays in data is compared with that in simulation to extract the mistagging efficiency as a function of jet transverse momentum. The total uncertainties are in the range 3-17%. The measurements generally agree with those in simulation but there are some differences in the region corresponding to the most stringent b-jet tagging requirement.
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| 8. |
- Aad, G., et al.
(författare)
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Measurement of the energy asymmetry in t(t)over-barj production at 13 TeV with the ATLAS experiment and interpretation in the SMEFT framework
- 2022
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Ingår i: European Physical Journal C. - : Springer Nature. - 1434-6044 .- 1434-6052. ; 82:4
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Tidskriftsartikel (refereegranskat)abstract
- A measurement of the energy asymmetry in jet-associated top-quark pair production is presented using 139 fb(-1) of data collected by the ATLAS detector at the Large Hadron Collider during pp collisions at root s = 13 TeV. The observable measures the different probability of top and antitop quarks to have the higher energy as a function of the jet scattering angle with respect to the beam axis. The energy asymmetry is measured in the semileptonic t (t) over bar decay channel, and the hadronically decaying top quark must have transverse momentum above 350 GeV. The results are corrected for detector effects to particle level in three bins of the scattering angle of the associated jet. The measurement agrees with the SM prediction at next-to-leading-order accuracy in quantum chromodynamics in all three bins. In the bin with the largest expected asymmetry, where the jet is emitted perpendicular to the beam, the energy asymmetry is measured to be -0.043 +/- 0.020, in agreement with the SM prediction of -0.037 +/- 0.003. Interpreting this result in the framework of the Standard Model effective field theory (SMEFT), it is shown that the energy asymmetry is sensitive to the top-quark chirality in four-quark operators and is therefore a valuable new observable in global SMEFT fits.
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| 9. |
- Aad, G., et al.
(författare)
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Measurements of azimuthal anisotropies of jet production in Pb collisions at root(NN)-N-s=5.02 TeV with the ATLAS detector
- 2022
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Ingår i: Physical Review C. - : American Physical Society. - 2469-9985 .- 2469-9993. ; 105:6
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Tidskriftsartikel (refereegranskat)abstract
- The azimuthal variation of jet yields in heavy-ion collisions provides information about the path-length dependence of the energy loss experienced by partons passing through the hot, dense nuclear matter known as the quark-gluon plasma. This paper presents the azimuthal anisotropy coefficients v(2), v(3), and v(4) measured for jets in Pb + Pb collisions at root(NN)-N-s =5.02 TeV using the ATLAS detector at the LHC. The measurement uses data collected in 2015 and 2018, corresponding to an integrated luminosity of 2.2 nb(-1). The v(n) values are measured as a function of the transverse momentum of the jets between 71 and 398 GeV and the event centrality. A nonzero value of v(2) is observed in all but the most central collisions. The value of v(2) is largest for jets with lower transverse momentum, with values up to 0.05 in mid-central collisions. A smaller, nonzero value of v(3) of approximately 0.01 is measured with no significant dependence on jet p(T) or centrality, suggesting that fluctuations in the initial state play a small but distinct role in jet energy loss. No significant deviation of v(4) from zero is observed in the measured kinematic region.
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| 10. |
- Aad, G., et al.
(författare)
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Measurements of Higgs boson production cross-sections in the H→τ+τ− decay channel in pp collisions at √s=13 TeV with the ATLAS detector
- 2022
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Ingår i: Journal of High Energy Physics (JHEP). - : Springer Nature. - 1126-6708 .- 1029-8479. ; :8
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Tidskriftsartikel (refereegranskat)abstract
- Measurements of the production cross-sections of the Standard Model (SM) Higgs boson (H) decaying into a pair of τ-leptons are presented. The measurements use data collected with the ATLAS detector from pp collisions produced at the Large Hadron Collider at a centre-of-mass energy of √s=13 TeV, corresponding to an integrated luminosity of 139 fb−1. Leptonic (τ → ℓνℓντ) and hadronic (τ→hadrons ντ) decays of the τ-lepton are considered. All measurements account for the branching ratio of H→ττ and are performed with a requirement |yH|<2.5, where yH is the true Higgs boson rapidity. The cross-section of the pp→H→ττ process is measured to be 2.94±0.21(stat)+0.37−0.32(syst) pb, in agreement with the SM prediction of 3.17±0.09 pb. Inclusive cross-sections are determined separately for the four dominant production modes: 2.65±0.41(stat)+0.91−0.67(syst) pb for gluon-gluon fusion, 0.197±0.028(stat)+ 0.032−0.026(syst) pb for vector boson fusion, 0.115±0.058(stat)+0.042−0.040(syst) pb for vector-boson associated production, and 0.033±0.031(stat)+0.022−0.017(syst) pb for top-quark pair associated production. Measurements in exclusive regions of the phase space, using the simplified template cross-section framework, are also performed. All results are in agreement with the SM predictions.
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