Selective isomerization of 1-alkenes by binary metal carbonyl compounds

• An efficient and selective isomerization of 1-alkenes to their corresponding 2-alkenes is achieved by using binary metal carbonyls such as Ru-3(CO)(12) as catalysts. Possible mechanisms are discussed. Substituents on the 1-alkene have a significant effect on the isomerization. (C) 2008 Elsevier Ltd. All rights reserved.

Subject headings

NATURVETENSKAP  -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)

NATURAL SCIENCES  -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)

Keyword

substituent effects

clusters

metal carbonyls

isomerization

1-alkenes

Publication and Content Type

art (subject category)

ref (subject category)