| 1. |
- Alshahrani, M. A.M., et al.
(författare)
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High-Temperature Hydrogen Attack on 2.25Cr-1Mo Steel: The Roles of Residual Carbon, Initial Microstructure and Carbide Stability
- 2022
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Ingår i: Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science. - : Springer Science and Business Media LLC. - 1073-5623. ; 54, s. 3682-
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Tidskriftsartikel (refereegranskat)abstract
- High temperature hydrogen attack is a damage mechanism that occurs in critical steel components in petrochemical plants and refineries when the hydrogen penetrates the steel and reacts with the carbides within to produce pores containing methane. With the motivation of understanding the role of carbide stability on the reaction with hydrogen, samples of a classic 214Cr-1Mo steel were subjected to a variety of heat treatments that generate a corresponding variety of precipitates, prior to exposure to high-pressure hydrogen in an autoclave. Using quantitative carbide, porosity and microstructural characterisation, it has been possible to demonstrate the roles of four variables: (a) the carbon residue present in the ferrite; (b) the non-equilibrium chemical composition of carbide; (c) the fraction of the carbide that is closest to the thermodynamic equilibrium state and (d) the initial microstructural state, i.e., whether it is martensitic or bainitic prior to heat treatment.
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| 2. |
- Belelli, F., et al.
(författare)
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Design and Characterization of Al–Mg–Si–Zr Alloys with Improved Laser Powder Bed Fusion Processability
- 2022
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Ingår i: Metallurgical and Materials Transactions. A. - : Springer. - 1073-5623 .- 1543-1940. ; 53:1, s. 331-343
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Tidskriftsartikel (refereegranskat)abstract
- A key-factor for the industrial implementation of beam-based additive manufacturing technologies is the development of novel Al alloys characterized by enhanced hot-tearing resistance. Indeed, most of the standard Al alloys are susceptible to solidification cracking and can hardly be used to produce structural parts by laser-based additive manufacturing processes. In this study, we investigate the strategies to design high-strength Al alloys for Laser Powder Bed Fusion. The addition of Zr to the chemical composition of an Al–Mg–Si alloy (EN AW 6182) was carried out by following two different routes to promote the formation of equiaxed grains which are able to suppress hot cracking and enhance processability of the material. The first route is based on mechanical mixing of ZrH2 particles and gas-atomized Al alloy powder and on the in-situ reaction of the hydride to form Al3Zr nucleants. The second route relies on the use of pre-alloyed gas-atomized powders that feature Zr among the alloy elements. The specimens produced using pre-alloyed powder showed the best mechanical performance. After direct aging from the as-built condition, the alloy showed yield strength and ultimate tensile strength of 354 and 363 MPa, respectively, and elongation at fracture of 9.0 pct. The achieved properties are comparable to those of wrought 6182 alloy processed by conventional routes.
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| 3. |
- Chou, Chia-Ying, et al.
(författare)
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Precipitation Kinetics During Post-heat Treatment of an Additively Manufactured Ferritic Stainless Steel
- 2022
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Ingår i: Metallurgical and Materials Transactions. A. - : Springer Nature. - 1073-5623 .- 1543-1940. ; 53:8, s. 3073-3082
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Tidskriftsartikel (refereegranskat)abstract
- The microstructure response of laser-powder bed fusion (L-PBF)-processed ferritic stainless steel (AISI 441) during post-heat treatments is studied in detail. Focus is on the precipitation kinetics of the Nb-rich phases: Laves (Fe2Nb) and the cubic carbo-nitride (NbC), as well as the grain structure evolution. The evolution of the precipitates is characterized using scanning and transmission electron microscopy (SEM and TEM) and the experimental results are used to calibrate precipitation kinetics simulations using the precipitation module (TC-PRISMA) within the Thermo-Calc Software package. The calculations reproduce the main trend for both the mean radii for the Laves phase and the NbC, and the amount of Laves phase, as a function of temperature. The calibrated model can be used to optimize the post-heat treatment of additively manufactured ferritic stainless steel components and offer a creator tool for process and structure linkages in an integrated computational materials engineering (ICME) framework for alloy and process development of additively manufactured ferritic steels.
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| 4. |
- Dahlström, Alexander, et al.
(författare)
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Effect of Stress on Spinodal Decomposition in Binary Alloys : Atomistic Modeling and Atom Probe Tomography
- 2022
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Ingår i: Metallurgical and Materials Transactions. A. - : Springer Nature. - 1073-5623 .- 1543-1940. ; 53:1, s. 39-49
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Tidskriftsartikel (refereegranskat)abstract
- Self-organizing nanostructure evolution through spinodal decomposition is a critical phenomenon determining the properties of many materials. Here, we study the influence of stress on the morphology of the nanostructure in binary alloys using atomistic modeling and atom probe tomography. The atomistic modeling is based on the quasi-particle approach, and it is compared to quantitative three-dimensional (3-D) atom mapping results. It is found that the magnitude of the stress and the crystallographic direction of the applied stress directly affect the development of spinodal decomposition and the nanostructure morphology. The modulated nanostructure of the binary bcc alloy system is quantified by a characteristic wavelength, λ. From modeling the tensile stress effect on the A-35 at. pct B system, we find that λ001<λ111<λ101<λ112 and the same trend are observed in the experimental measurements on an Fe-35 at. pct Cr alloy. Furthermore, the effect of applied compressive and shear stress states differs from the effect of the applied tensile stress regarding morphological anisotropy.
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| 5. |
- Dahlström, Alexander, et al.
(författare)
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Precision Thermal Treatments, Atom Probe Characterization, and Modeling to Describe the Fe-Cr Metastable Miscibility Gap
- 2021
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Ingår i: Metallurgical and Materials Transactions. A. - : Springer. - 1073-5623 .- 1543-1940. ; 52:4, s. 1453-1464
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Tidskriftsartikel (refereegranskat)abstract
- Abstract: The Fe-Cr metastable miscibility gap has been studied by high-precision thermal treatments, Vickers micro-hardness (HV) measurements, and atom probe tomography (APT). Thermodynamic modeling further supplements the experimental work. The results obtained show that recent thermodynamic descriptions of the metastable miscibility gap found in literature generally overestimates the consolute temperature. We can show that the source of ambiguity in previous studies is most likely a lack of clear distinction between Cr-Cr clustering and α′ formation. This distinction is here made by APT results, and it leads to a determined consolute temperature of 580 ± 1 °C for Fe0.50Cr0.50. The revised thermodynamic modeling of the metastable miscibility gap captures the experimental results and is consistent with the overall picture from the Fe-Cr data in the literature. Graphic Abstract: [Figure not available: see fulltext.]
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| 6. |
- Das, Yadunandan, et al.
(författare)
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Quantitative Nanostructure and Hardness Evolution in Duplex Stainless Steels : Under Real Low-Temperature Service Conditions
- 2022
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Ingår i: Metallurgical and Materials Transactions. A. - : Springer Nature. - 1073-5623 .- 1543-1940. ; 53:2, s. 723-735
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Tidskriftsartikel (refereegranskat)abstract
- Duplex stainless steels are a group of widely used stainless steels, because of their attractive combination of strength and corrosion resistance. However, these steels embrittle because of a phase separation phenomenon in the ferrite phase when exposed to temperatures within the miscibility gap. This manuscript investigates the phase separation in two commercial stainless steels, the duplex stainless steel (DSS) 22Cr-5Ni (2205 or UNS S32205), and the super-duplex stainless steel (SDSS) 25Cr-7Ni (2507 or UNS S32750), and its subsequent effect on mechanical property evolution. Long-term isothermal aging heat treatments were carried out at industrially relevant temperatures between 250 °C and 350 °C for up to 48,000 hours, and quantitative measurements of the amplitude and wavelength of the phase separated nanostructure were obtained using Small-Angle Neutron Scattering (SANS). These quantifications were used as input parameters in hardness models to predict the hardness evolution. It is concluded that the quantitative information from SANS combined with these hardness models enables the prediction of hardness evolution in DSS at low temperatures, which in turn correlates with the embrittlement of the DSS.
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| 7. |
- Deng, B., et al.
(författare)
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Toughness Improvement in a Novel Martensitic Stainless Steel Achieved by Quenching–Tempering and Partitioning
- 2021
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Ingår i: Metallurgical and Materials Transactions. A. - : Springer Nature. - 1073-5623 .- 1543-1940. ; 52:11, s. 4852-4864
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Tidskriftsartikel (refereegranskat)abstract
- In the present work, a novel medium carbon martensitic stainless steel (MCMSS) with an excellent combination of strength, ductility, and impact toughness was designed on the basis of quenching-tempering and partitioning (Q–T&P) technology. Q–T&P is an identical heat treatment with a standard quenching and tempering (Q–T) process but has the same role with quenching and partitioning (Q&P) on microstructure control, i.e., promoting carbon-rich retained austenite via inhibiting carbide precipitation. Results show that, without compromise on strength, the total elongation and room temperature impact toughness, i.e., 9.6 pct and 90 J cm−2, of the proposed alloy (23Cr13MnSi) increase by 14 and 110 pct, respectively, as compared to those of the commercial AISI 420. The significant improvement of ductility and impact toughness in the proposed alloy is mainly a result of the gradual transformation induced plasticity (TRIP) effects, which are caused by carbon-rich retained austenite with heterogeneous stability and carbide-free martensite formed in the Q–T&P process
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| 8. |
- Deng, Dunyong, et al.
(författare)
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On the Dwell-Fatigue Crack Propagation Behavior of a High-Strength Ni-Base Superalloy Manufactured by Selective Laser Melting
- 2020
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Ingår i: Metallurgical and Materials Transactions. A. - : SPRINGER. - 1073-5623 .- 1543-1940. ; 51, s. 962-972
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Tidskriftsartikel (refereegranskat)abstract
- This study focuses on the dwell-fatigue crack propagation behavior of IN718 manufactured via selective laser melting (SLM). The dwell-fatigue test condition is 823 K (550 with a long 2160-s dwell-holding period. Effects of heat treatment and loading direction on dwell-fatigue crack propagation rates are studied. A grain boundary delta precipitate seems to be slightly beneficial to the dwell-fatigue cracking resistance of SLM IN718. A comparison has been made between SLM IN718 and forged counterparts at different temperatures, indicating that a creep damage mechanism is likely dominant for SLM IN718 under the present test condition. A general discussion of the inferior creep resistance of SLM IN718 is also included. The anisotropic dwell-fatigue cracking resistance has also been studied and rationalized with the effective stress intensity factor calculated from finite element modeling.
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| 9. |
- Dhar, S., et al.
(författare)
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Multi-axial Fatigue of Head-Hardened Pearlitic and Austenitic Manganese Railway Steels: A Comparative Study
- 2020
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Ingår i: Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science. - : Springer Science and Business Media LLC. - 1073-5623. ; 51:11, s. 5639-5652
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Tidskriftsartikel (refereegranskat)abstract
- Switches and crossings (S&Cs) in rail networks suffer from damage and deformation due to severe loading of their complex geometric shapes. This article presents a comparative study of the cyclic deformation characteristics and fatigue behavior of two typical crossing materials, namely head-hardened pearlitic steel and Hadfield manganese steel, as well as the associated microstructural changes. Both uniaxial and biaxial loadings (proportional and non-proportional) are studied. The pearlitic steel endured more cycles to failure for a given strain amplitude compared to the manganese steel. The cyclic response of manganese steel shows significant hardening whereas softening was observed for the pearlitic steel except under biaxial non-proportional loading. The microstructures developed in the two types of steels after deformation are characterized by optical (OM) and transmission electron microscopy (TEM). TEM micrographs reveal that the deformed microstructure of the pearlitic steel consists of threading dislocations and dislocation tangles in the ferrite lamellae. The microstructures in the manganese steel after the different loadings are composed of dislocation cells with dislocation tangles inside, intersected by straight stacking fault lamellae. The observed microstructures are related to the results of the mechanical test, and the suitability of the steels for use in S&Cs is discussed.
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| 10. |
- Eriksson, Emil, 1990, et al.
(författare)
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The Effect of Grain Boundary Carbides on Dynamic Recrystallization During Hot Compression of Ni-Based Superalloy Haynes 282
- 2022
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Ingår i: Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science. - : Springer Science and Business Media LLC. - 1073-5623. ; 53:1, s. 29-38
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Tidskriftsartikel (refereegranskat)abstract
- In alloys where carbides are the main grain boundary phase, the role of carbides during hot working is not known. Here, we address the effect of grain boundary carbides on the dynamic recrystallization during hot compression of Ni-base superalloy Haynes 282. When excluding variations from experimental factors neither stress evolution nor final microstructure indicated that carbides exerted a significant influence on the dynamic recrystallization. The carbide solvus temperature is not a critical limit during thermomechanical processes.
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