| 1. |
- Wang, Chuan Fei, et al.
(författare)
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Diluted Organic Semiconductors in Photovoltaics
- 2020
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Ingår i: Solar RRL. - : WILEY-V C H VERLAG GMBH. - 2367-198X. ; 4:9
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Tidskriftsartikel (refereegranskat)abstract
- Incorporation of insulating polymers or molecules into organic semiconductor films, creating so-called diluted organic semiconductors, has been successfully used both in organic field-effect transistors and organic light-emitting diodes to reduce sensitivity to charge traps. However, application of this strategy in organic photovoltaics is challenging due to the complex requirements on the light-absorbing blend layer. Herein, diluted donor-acceptor-insulator ternary organic solar cells are developed to improve mobility and decrease radiative and nonradiative recombination in the active layer. In addition, both thermal and environmental stability of the diluted ternary solar cells are enhanced. Finally, the diluted semiconductor approach enables large-area solar cells to be fabricated where the loss in power density upon cell area upscaling is five times lower than for the equivalent binary cells.
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| 2. |
- Xiong, Shaobing, et al.
(författare)
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Defect-Passivation Using Organic Dyes for Enhanced Efficiency and Stability of Perovskite Solar Cells
- 2020
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Ingår i: Solar RRL. - : WILEY-V C H VERLAG GMBH. - 2367-198X. ; 4:5
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Tidskriftsartikel (refereegranskat)abstract
- Perovskite solar cells are a highly competitive candidate for next-generation photovoltaic technology. Defects in the perovskite grain boundaries and on the film surfaces however have significant impacts on both the device efficiency and environmental stability. Herein, a strategy using organic dyes as additives to passivate the defect states and produce more n-type perovskite films, thereby improving charge transport and decreasing charge recombination, is reported. Based on this strategy, the power conversion efficiency of the perovskite solar cell is significantly increased from 18.13% to 20.18% with a negligible hysteresis. Furthermore, the rich hydrogen bonds and carbonyl structures in the organic dye can significantly enhance device stability both in terms of humidity and thermal stress. The results present a promising pathway using abundant and colorful organic dyes as additives to achieve high-performance perovskite solar cells.
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