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Träfflista för sökning "WFRF:(Anderlund Magnus F.) srt2:(2011)"

Sökning: WFRF:(Anderlund Magnus F.) > (2011)

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1.
  • Berggren, Gustav, et al. (författare)
  • Mechanistic Studies on the Water-Oxidizing Reaction of Homogeneous Manganese-Based Catalysts : Isolation and Characterization of a Suggested Catalytic Intermediate
  • 2011
  • Ingår i: Inorganic Chemistry. - : American Chemical Society (ACS). - 0020-1669 .- 1520-510X. ; 50:8, s. 3425-3430
  • Tidskriftsartikel (refereegranskat)abstract
    • The synthesis, isolation, and characterization of two high-valent manganese dimers with isomeric ligands are reported. The complexes are synthesized and crystallized from solutions of low-valent precursors exposed to tert-butyl hydroperoxide. The crystal structures display centrosymmetric complexesconsisting of Mn2 IV,IV(μ-O)2 cores, with one ligand coordinating to each manganese. The ligands coordinate with the diaminoethane backbone, the carboxylate, and one of the two pyridines, while the second pyridine is noncoordinating. The activity of these complexes, under water oxidation conditions, is discussed in light of a proposed mechanism for water oxidation, in which this type of complexes have been suggested as a key intermediate.
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2.
  • Shevchenko, Denys, et al. (författare)
  • Photochemical water oxidation with visible light using a cobalt containing catalyst
  • 2011
  • Ingår i: Energy and Environmental Science. - : RSC Publishing. - 1754-5692 .- 1754-5706. ; 4:4, s. 1284-1287
  • Tidskriftsartikel (refereegranskat)abstract
    • Artificial photosynthesis aims at using solar light energy to oxidatively split water to oxygen, protons and electrons and store the energy in a chemical fuel. Here we present a cobalt phosphonate material that can split water catalytically, driven by visible light in aqueous solutions of pH 7.
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