| 1. |
- Kirillova, Elena N., et al.
(författare)
-
C-13- and C-14-based study of sources and atmospheric processing of water-soluble organic carbon (WSOC) in South Asian aerosols
- 2013
-
Ingår i: Journal of Geophysical Research - Atmospheres. - : American Geophysical Union (AGU). - 2169-897X .- 2169-8996. ; 118:2, s. 614-626
-
Tidskriftsartikel (refereegranskat)abstract
- Water-soluble organic carbon (WSOC) is typically a large component of carbonaceous aerosols with a high propensity for inducing cloud formation. The sources of WSOC, which may be both of primary and secondary origins, are in general poorly constrained. This study assesses the concentrations and dual-carbon isotope (14C and 13C) signatures of South Asian WSOC during a 15-month continuous campaign in 2008-2009. Total suspended particulate matter samples were collected at Sinhagad (SINH) India and at the Maldives Climate Observatory at Hanimaadhoo (MCOH). Monsoon-driven meteorology yields significant WSOC concentration differences between the dry winter season (0.94±0.43 μg m-3 MCOH and 3.6±2.3 μg m-3 SINH) and the summer monsoon season (0.10±0.04 μg m-3 MCOH and 0.35±0.21 μg m-3 SINH). Radiocarbon-based source apportionment of WSOC shows the dominance of biogenic/biomass combustion sources but also a substantial anthropogenic fossil-fuel contribution (17±4% MCOH and 23±4% SINH). Aerosols reaching MCOH after long-range over-ocean transport were enriched by 3-4‰ in δ13C-WSOC relative to SINH. This is consistent with particle-phase aging processes influencing the δ13C-WSOC signal in the South Asian regional receptor atmosphere.
|
|
| 2. |
- Sheesley, Rebecca J., et al.
(författare)
-
Year round radiocarbon based source apportionment of carbonaceous aerosols at two background sites in south asia
- 2012
-
Ingår i: Journal of Geophysical Research. - 0148-0227 .- 2156-2202. ; 117, s. D10202-
-
Tidskriftsartikel (refereegranskat)abstract
- Atmospheric Brown Clouds (ABC), regional-scale haze events, are a significant concern for both human cardiopulmonary health and regional climate impacts. In order to effectively mitigate this pollution-based phenomenon, it is imperative to understand the magnitude, scope and source of ABC in regions such as South Asia. Two sites in S. Asia were chosen for a 15-month field campaign focused on isotope-based source apportionment of carbonaceous aerosols in 2008-2009. Both the Maldives Climate Observatory in Hanimaadhoo (MCOH) and a mountaintop site in Sinhagad, India (SINH) act as regionally mixed receptor sites. Annual radiocarbon-based source apportionment for soot elemental carbon (SEC) at MCOH and SINH revealed 73 +/- 6% and 59 +/- 5% contribution from biomass combustion, respectively (remainder from fossil fuel). The contributions from biogenic/biomass combustion to total organic carbon were similar between MCOH and SINH (69 +/- 5% and 64 +/- 5, respectively). The biomass combustion contribution for SEC in the current study, especially the results from MCOH, shows good agreement with published black carbon emissions inventories for India. Geographic source assessment, including clustered back trajectory analysis and carbon contribution by source region, indicated that the highest SEC/TOC loads originated from the W. Indian coastal margin, including the coastal city of Mumbai, India. The winter dry season C-14-based source apportionment of the BC-tracing SEC fraction for 2006, 2008, 2009 were not statistically different (p = 0.7) and point to a near-constant two-thirds contribution from biomass combustion practices, including wood and other biofuels as well as burning of agricultural crop residues.
|
|
| 3. |
- Alling, Vanja, et al.
(författare)
-
Degradation of terrestrial organic carbon, primary production and out-gassing of CO2 in the Laptev and East Siberian Seas as inferred from delta C-13 values of DIC
- 2012
-
Ingår i: Geochimica Et Cosmochimica Acta. - : Elsevier BV. - 0016-7037 .- 1872-9533. ; 95, s. 143-159
-
Tidskriftsartikel (refereegranskat)abstract
- The cycling of carbon on the Arctic shelves, including outgassing of CO2 to the atmosphere, is not clearly understood. Degradation of terrestrial organic carbon (OCter) has recently been shown to be pronounced over the East Siberian Arctic Shelf (ESAS), i.e. the Laptev and East Siberian Seas, producing dissolved inorganic carbon (DIC). To further explore the processes affecting DIC, an extensive suite of shelf water samples were collected during the summer of 2008, and assessed for the stable carbon isotopic composition of DIC (delta C-13(DIC)). The delta C-13(DIC) values varied between -7.2 parts per thousand to +1.6 parts per thousand and strongly deviated from the compositions expected from only mixing between river water and seawater. Model calculations suggest that the major processes causing these deviations from conservative mixing were addition of (DIC) by degradation of OCter, removal of DIC during primary production, and outgassing of CO2. All waters below the halocline in the ESAS had delta C-13(DIC) values that appear to reflect mixing of river water and seawater combined with additions of on average 70 +/- 20 mu M of DIC, originating from degradation of OCter in the coastal water column. This is of the same magnitude as the recently reported deficits of DOCter and POCter for the same waters. The surface waters in the East Siberian Sea had higher delta C-13(DIC) values and lower DIC concentrations than expected from conservative mixing, consistent with additions of DIC from degradation of OCter and outgassing of CO2. The outgassing of CO2 was equal to loss of 123 +/- 50 mu M DIC. Depleted delta C-13(POC) values of -29 parts per thousand to -32 parts per thousand in the mid to outer shelf regions are consistent with POC from phytoplankton production. The low delta C-13(POC) values are likely due to low delta C-13(DIC) of precursor DIC, which is due to degradation of OCter, rather than reflecting terrestrial input compositions. Overall, the delta C-13(DIC) values confirm recent suggestions of substantial degradation of OCter over the ESAS, and further show that a large part of the CO2 produced from degradation has been outgassed to the atmosphere. (C) 2012 Elsevier Ltd. All rights reserved.
|
|
| 4. |
- Bosch, Carme, et al.
(författare)
-
Source-diagnostic dual-isotope composition and optical properties of water-soluble organic carbon and elemental carbon in the South Asian outflow intercepted over the Indian Ocean
- 2014
-
Ingår i: Journal of Geophysical Research - Atmospheres. - 2169-897X .- 2169-8996. ; 119:20, s. 11743-11759
-
Tidskriftsartikel (refereegranskat)abstract
- The dual carbon isotope signatures and optical properties of carbonaceous aerosols have been investigated simultaneously for the first time in the South Asian outflow during an intensive campaign at the Maldives Climate Observatory on Hanimaadhoo (MCOH) (February and March 2012). As one component of the Cloud Aerosol Radiative Forcing Dynamics Experiment, this paper reports on the sources and the atmospheric processing of elemental carbon (EC) and water-soluble organic carbon (WSOC) as examined by a dual carbon isotope approach. The radiocarbon (C-14) data show that WSOC has a significantly higher biomass/biogenic contribution (865%) compared to EC (594%). The more C-13-enriched signature of MCOH-WSOC (-20.80.7) compared to MCOH-EC (-25.8 +/- 0.3 parts per thousand) and megacity Delhi WSOC (-24.1 +/- 0.9 parts per thousand) suggests that WSOC is significantly more affected by aging during long-range transport than EC. The C-13-C-14 signal suggests that the wintertime WSOC intercepted over the Indian Ocean largely represents aged primary biomass burning aerosols. Since light-absorbing organic carbon aerosols (Brown Carbon (BrC)) have recently been identified as potential contributors to positive radiative forcing, optical properties of WSOC were also investigated. The mass absorption cross section of WSOC (MAC(365)) was 0.5 +/- 0.2 m(2)g(-1) which is lower than what has been observed at near-source sites, indicating a net decrease of WSOC light-absorption character during long-range transport. Near-surface WSOC at MCOH accounted for similar to 1% of the total direct solar absorbance relative to EC, which is lower than the BrC absorption inferred from solar spectral observations of ambient aerosols, suggesting that a significant portion of BrC might be included in the water-insoluble portion of organic aerosols.
|
|
| 5. |
- Delmonte, B., et al.
(författare)
-
Geographic provenance of aeolian dust in East Antarctica during Pleistocene glaciations : preliminary results from Talos Dome and comparison with East Antarctic and new Andean ice core data
- 2010
-
Ingår i: Quaternary Science Reviews. - : Elsevier BV. - 0277-3791 .- 1873-457X. ; 29:02-jan, s. 256-264
-
Tidskriftsartikel (refereegranskat)abstract
- The strontium and neodymium isotopic signature of aeolian mineral particles archived in polar ice cores provides constraints on the geographic provenance of dust and paleo-atmospheric circulation patterns. Data from different ice cores drilled in the centre of the East Antarctic plateau such as EPICA-Dome C (EDC, 75 degrees 06'S: 123 degrees 21'E) and Vostok (78 degrees 28'S, 106 degrees 48'E) suggested a uniform geographic provenance for dust during Pleistocene glacial ages, likely from southern South America (SSA). In this work the existing dust isotopic data from EDC have been integrated with new data from Marine Isotopic Stage (MIS) 14 (about 536 ka before 1950AD) and in parallel some first results are shown for the new TALDICE ice core which was drilled on the edge of the East Antarctic Plateau (Talos Dome, 72 degrees 48'S, 159 degrees 06'E) on the opposite side with respect to SSA. Interestingly, the isotopic composition of TALDICE glacial dust is remarkably similar to that obtained from glacial dust from sites located in the East Antarctic interior. Overall, the glacial dust isotopic field obtained from six East Antarctic ice cores matches well South American data obtained from target areas. In this respect, it was recently suggested that dust exported long-range from South America originates from Patagonia and from the Puna-Altiplano plateau. To test this hypothesis, we analysed the isotopic composition of dust from an ice core drilled on the Illimani glacier (Bolivia, 16 degrees 37'S, 67 degrees 46'W; 6350 m a.s.l.) in order to obtain information on the isotopic composition of regional mineral aerosol uplifted from the Altiplano area and likely transported over a long distance. Altogether, ice core and source data strongly suggest that the westerly circulation pattern allowed efficient transfer of dust from South America to the East Antarctic plateau under cold Quaternary climates. Isotopic data support the hypothesis of a possible mixing of dust from Patagonia and from the Puna-Altiplano plateau. Interestingly, high glacial dust inputs to Antarctica are characterized by less radiogenic Nd values, an issue suggesting that enhanced dust production in Patagonia was associated with the activation of a secondary source. Still, Patagonia was the most important supplier for dust to central East Antarctica during Quaternary glaciations.
|
|
| 6. |
- Feroci, M., et al.
(författare)
-
LOFT - The large observatory for x-ray timing
- 2012
-
Ingår i: Proceedings of SPIE - The International Society for Optical Engineering. - : SPIE - International Society for Optical Engineering. - 9780819491442 ; , s. 84432D-
-
Konferensbidrag (refereegranskat)abstract
- The LOFT mission concept is one of four candidates selected by ESA for the M3 launch opportunity as Medium Size missions of the Cosmic Vision programme. The launch window is currently planned for between 2022 and 2024. LOFT is designed to exploit the diagnostics of rapid X-ray flux and spectral variability that directly probe the motion of matter down to distances very close to black holes and neutron stars, as well as the physical state of ultradense matter. These primary science goals will be addressed by a payload composed of a Large Area Detector (LAD) and a Wide Field Monitor (WFM). The LAD is a collimated (<1 degree field of view) experiment operating in the energy range 2-50 keV, with a 10 m2 peak effective area and an energy resolution of 260 eV at 6 keV. The WFM will operate in the same energy range as the LAD, enabling simultaneous monitoring of a few-steradian wide field of view, with an angular resolution of <5 arcmin. The LAD and WFM experiments will allow us to investigate variability from submillisecond QPO's to yearlong transient outbursts. In this paper we report the current status of the project.
|
|
| 7. |
- Feroci, M., et al.
(författare)
-
The large observatory for x-ray timing
- 2014
-
Ingår i: Proceedings of SPIE - The International Society for Optical Engineering. - : SPIE. - 9780819496126
-
Konferensbidrag (refereegranskat)abstract
- The Large Observatory For x-ray Timing (LOFT) was studied within ESA M3 Cosmic Vision framework and participated in the final downselection for a launch slot in 2022-2024. Thanks to the unprecedented combination of effective area and spectral resolution of its main instrument, LOFT will study the behaviour of matter under extreme conditions, such as the strong gravitational field in the innermost regions of accretion flows close to black holes and neutron stars, and the supranuclear densities in the interior of neutron stars. The science payload is based on a Large Area Detector (LAD, 10 m2 effective area, 2-30 keV, 240 eV spectral resolution, 1° collimated field of view) and a Wide Field Monitor (WFM, 2-50 keV, 4 steradian field of view, 1 arcmin source location accuracy, 300 eV spectral resolution). The WFM is equipped with an on-board system for bright events (e.g. GRB) localization. The trigger time and position of these events are broadcast to the ground within 30 s from discovery. In this paper we present the status of the mission at the end of its Phase A study.
|
|
| 8. |
- Widerlund, Anders, et al.
(författare)
-
Late Holocene freshening of the Baltic Sea derived from high-resolution strontium isotope analyses of mollusk shells
- 2011
-
Ingår i: Geology. - 0091-7613 .- 1943-2682. ; 39:2, s. 187-190
-
Tidskriftsartikel (refereegranskat)abstract
- Strontium isotopic composition (87Sr/86Sr) data from subfossil 14C-dated mollusk shells in raised beach sediments are used as a paleosalinity proxy in the brackish Baltic Sea, the precision (±5%) and accuracy (±0.7‰) of the method being judged from replicate analyses of modern shells. Paleosalinity data with an average time resolution of ~200 yr for the period 7130-2775 calibrated 14C yr B.P. indicate maximum surface salinities of 10‰-11‰, 11‰-12‰, and 12‰-13‰ for the Bothnian Bay, Bothnian Sea, and Baltic Proper (the three major Baltic subbasins). The relative salinity differences between the basins were small (≤30%) compared to the as much as eightfold present-day relative salinity differences (Bothnian Bay 1‰-3‰; Bothnian Sea 4‰-5‰; Baltic Proper 6‰-8‰). Late Holocene freshening (ca. 3000 calibrated 14C yr B.P. to present) is most pronounced in the northernmost subbasin, the Bothnian Bay, consistent with the absence of a permanent halocline, sequestering of phosphorus in well-oxygenated bottom sediments, and phosphorus limitation of primary production in the present-day Bothnian Bay. This study suggests that paleosalinity data may be crucial to improving our understanding of the possible effects of any future, climate-induced freshening of the Baltic Sea
|
|
