| 1. |
- Andersson, Viktor, 1983, et al.
(författare)
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Alkali desorption from ilmenite oxygen carrier particles used in biomass combustion
- 2024
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Ingår i: Fuel. - 0016-2361 .- 1873-7153. ; 359
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Tidskriftsartikel (refereegranskat)abstract
- Oxygen-carrying fluidized bed materials are increasingly used in novel technologies for carbon capture and storage, and to improve the efficiency of fuel conversion processes. Potassium- and sodium-containing compounds are released during biomass combustion and may have both negative and positive effects on conversion processes. Ilmenite is an important oxygen carrier material with the ability to capture alkali in the form of titanates. This is a desirable property since it may reduce detrimental alkali effects including fouling, corrosion, and fluidized bed agglomeration. This study investigates the interactions of alkali-containing compounds with ilmenite particles previously used in an industrial scale (115 MWth) oxygen carrier aided combustion system. The ilmenite samples were exposed to temperatures up to 1000 °C under inert and oxidizing conditions while the alkali release kinetics were characterized using online alkali monitoring. Alkali desorption occurs between 630 and 800 °C, which is attributed to loosely bound alkali at or near the surface of the particles. Extensive alkali release is observed above 900 °C and proceeds during extended time periods at 1000 °C. The release above 900 °C is more pronounced under oxidizing conditions and approximately 9.1 and 3.2 wt% of the alkali content is emitted from the ilmenite samples in high and low oxygen activity, respectively. Detailed material analyses using scanning electron microscopy with energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy were conducted before and after temperature treatment, which revealed that the concentrations of potassium, sodium and chlorine decrease at the outermost surface of the ilmenite particles during temperature treatment, and Cl is depleted to a deeper level in oxidizing conditions compared to inert. The implications for ilmenite-ash interactions, oxygen carrier aided combustion and chemical looping systems are discussed.
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| 2. |
- Andersson, Viktor, 1983, et al.
(författare)
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Alkali interactions with a calcium manganite oxygen carrier used in chemical looping combustion
- 2022
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Ingår i: Fuel Processing Technology. - : Elsevier BV. - 0378-3820 .- 1873-7188. ; 227
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Tidskriftsartikel (refereegranskat)abstract
- Chemical-Looping Combustion (CLC) of biofuels is a promising technology for cost-efficient CO2 separation and can lead to negative CO2 emissions when combined with carbon capture and storage. A potential challenge in developing CLC technology is the effects of alkali metal-containing compounds released during fuel conversion. This study investigates the interactions between alkali and an oxygen carrier (OC), CaMn0.775Ti0.125Mg0.1O3-δ, to better understand the fate of alkali in CLC. A laboratory-scale fluidized bed reactor is operated at 800–900 °C in oxidizing, reducing and inert atmospheres to mimic CLC conditions. Alkali is fed to the reactor as aerosol KCl particles, and alkali in the exhaust is measured online with a surface ionization detector. The alkali concentration changes with gas environment, temperature, and alkali loading, and the concentration profile has excellent reproducibility over repeated redox cycles. Alkali-OC interactions are dominated by alkali uptake under most conditions, except for a release during OC reduction. Uptake is significant during stable reducing conditions, and is limited under oxidizing conditions. The total uptake during a redox cycle is favored by a high alkali loading, while the influence of temperature is weak. The implications for the understanding of alkali behavior in CLC and further development are discussed.
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| 3. |
- Andersson, Viktor, 1983, et al.
(författare)
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Alkali-wall interactions in a laboratory-scale reactor for chemical looping combustion studies
- 2021
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Ingår i: Fuel Processing Technology. - : Elsevier BV. - 0378-3820 .- 1873-7188. ; 217
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Tidskriftsartikel (refereegranskat)abstract
- Alkali metal-containing compounds are readily released during thermal conversion of solid fuels, and may have both detrimental and beneficial effects on chemical looping combustion. Here, we characterize alkali interactions with the inner walls of a laboratory-scale reactor under oxidizing, reducing and inert conditions at temperatures up to 900 °C. KCl aerosol particles are continuously introduced to the stainless steel reactor and the alkali concentration is measured on-line with a surface ionization detector. Aerosol particles evaporate at temperatures above 500 °C and KCl molecules rapidly diffuse to the reactor wall. Up to 92% of the alkali reaching the wall below 700 °C remains adsorbed, while re-evaporation is important at higher temperatures, where up to 74% remains adsorbed. Transient changes in alkali concentration are observed during repeated redox cycles, which are associated with changes in chemical composition of the wall material. Metal oxides on the reactor wall are partially depleted under reducing conditions, which allow for the formation of a new potassium-rich phase that is stable in a reducing atmosphere, but not under inert conditions. The observed wall effects are concluded to be extensive and include major transient effects depending on gas composition, and the implications for laboratory studies and improved experimental methodology are discussed.
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| 4. |
- Andersson, Viktor, 1983, et al.
(författare)
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Design and first application of a novel laboratory reactor for alkali studies in chemical looping applications
- 2023
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Ingår i: Fuel Processing Technology. - 0378-3820. ; 252
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Tidskriftsartikel (refereegranskat)abstract
- Alkali compounds are readily released during biomass conversion and their complex interactions with reactor walls and sampling equipment makes detailed investigations challenging. This study evaluates a novel laboratory-scale fluidized bed reactor for chemical looping combustion (CLC) studies. The reactor design is based on detailed consideration of the behavior of alkali-containing molecules and aerosol particles and is guided by computational fluid dynamic simulations. The design allows for interactions between gaseous alkali and a fluidized bed, while minimizing alkali interactions with walls before and after the fluidized bed. The function of the laboratory reactor is demonstrated in experiments using online gas and alkali analysis. Alkali is continuously fed to the reactor as KOH or KCl aerosol with and without a fluidized bed of the oxygen carrier CaMn0.775Ti0.125Mg0.1O3-δ present in inert, reducing and oxidizing conditions at temperatures up to 900 °C. Alkali uptake by the OC is characterized in all conditions, and observed to sensitively depend on gas composition, reactor temperature and type of alkali compound. The experimental setup is concluded to have a significantly improved functionality compared to a previously used reactor, which opens up for detailed studies of interactions between alkali compounds and oxygen carriers used in CLC.
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| 5. |
- Andersson, Viktor, 1983, et al.
(författare)
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Gaseous alkali interactions with ilmenite, manganese oxide and calcium manganite under chemical looping combustion conditions
- 2024
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Ingår i: Fuel Processing Technology. - 0378-3820 .- 1873-7188. ; 254
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Tidskriftsartikel (refereegranskat)abstract
- Alkali species present in biomass pose significant challenges in chemical looping combustion (CLC) processes and other thermal conversion applications. The interactions between different alkali species and three common oxygen carrier (OC) materials that are considered to be state of the art in CLC applications have been investigated. A dedicated fluidized bed laboratory reactor was used to study interactions of KCl, NaCl, KOH, NaOH, K2SO4 and Na2SO4 with manganese oxide, calcium manganite and ilmenite. Alkali vapor was generated by injecting alkali salts under reducing, oxidizing and inert conditions at 900 °C. Gaseous species were measured online downstream of the reactor, and the efficiency of alkali uptake was determined under different conditions. The result show significant alkali uptake by all OCs under the studied conditions. Ilmenite shows near complete alkali uptake in reducing conditions, while manganese oxide and calcium manganite exhibited less effective alkali uptake, but have advantages in terms of fuel conversion and oxidizing efficiency. Alkali chlorides, sulfates and hydroxides show distinctly different behavior, with alkali hydroxides being efficiently captured all three investigate OC materials. The findings contribute to a deeper understanding of alkali behavior and offer valuable guidance for the design and optimization of CLC with biomass.
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| 6. |
- Andersson, Viktor, 1983, et al.
(författare)
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Integration of algae-based biofuel production with an oil refinery: Energy and carbon footprint assessment
- 2020
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Ingår i: International Journal of Energy Research. - : Hindawi Limited. - 1099-114X .- 0363-907X. ; 44:13, s. 10860-10877
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Tidskriftsartikel (refereegranskat)abstract
- Biofuel production from algae feedstock has become a topic of interest in the recent decades since algae biomass cultivation is feasible in aquaculture and does therefore not compete with use of arable land. In the present work, hydrothermal liquefaction of both microalgae and macroalgae is evaluated for biofuel production and compared with transesterifying lipids extracted from microalgae as a benchmark process. The focus of the evaluation is on both the energy and carbon footprint performance of the processes. In addition, integration of the processes with an oil refinery has been assessed with regard to heat and material integration. It is shown that there are several potential benefits of co-locating an algae-based biorefinery at an oil refinery site and that the use of macroalgae as feedstock is more beneficial than the use of microalgae from a system energy performance perspective. Macroalgae-based hydrothermal liquefaction achieves the highest system energy efficiency of 38.6%, but has the lowest yield of liquid fuel (22.5 MJ per 100 MJalgae) with a substantial amount of solid biochar produced (28.0 MJ per 100 MJalgae). Microalgae-based hydrothermal liquefaction achieves the highest liquid biofuel yield (54.1 MJ per 100 MJalgae), achieving a system efficiency of 30.6%. Macro-algae-based hydrothermal liquefaction achieves the highest CO2 reduction potential, leading to savings of 24.5 resp 92 kt CO2eq/year for the two future energy market scenarios considered, assuming a constant feedstock supply rate of 100 MW algae, generating 184.5, 177.1 and 229.6 GWhbiochar/year, respectively. Heat integration with the oil refinery is only possible to a limited extent for the hydrothermal liquefaction process routes, whereas the lipid extraction process can benefit to a larger extent from heat integration due to the lower temperature level of the process heat demand.
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| 7. |
- Dods, Robert, 1989, et al.
(författare)
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Ultrafast structural changes within a photosynthetic reaction centre.
- 2021
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Ingår i: Nature. - : Springer Science and Business Media LLC. - 1476-4687 .- 0028-0836. ; 589:7841, s. 310-314
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Tidskriftsartikel (refereegranskat)abstract
- Photosynthetic reaction centres harvest the energy content of sunlight by transporting electrons across an energy-transducing biological membrane. Here we use time-resolved serial femtosecond crystallography1 using an X-ray free-electron laser2 to observe light-induced structural changes in the photosynthetic reaction centre of Blastochloris viridis on a timescale of picoseconds. Structural perturbations first occur at the special pair of chlorophyll molecules of the photosynthetic reaction centre that are photo-oxidized by light. Electron transfer to the menaquinone acceptor on the opposite side of the membrane induces a movement of this cofactor together with lower amplitude protein rearrangements. These observations reveal how proteins use conformational dynamics to stabilize the charge-separation steps of electron-transfer reactions.
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| 8. |
- Sköld Gustafsson, Viktor
(författare)
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Decision Support for Emergency Response to Multiple Natural Hazards : CHALLENGES AND NEEDS
- 2022
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Licentiatavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Global warming exceeding 1.5°C above pre-industrial levels will very likely lead to unavoidable increases of several climate hazards in the coming decades. Climate change phenomena can increase the risk of several extreme weather events, leading to risks of what is commonly considered as natural hazards, for instance landslides and forest fires. These chains or networks of events are termed natural multi-hazards or compound natural events, referring to a primary event or a driver that directly triggers or increases the probability of one or more secondary events by changing the environment. The very likely increase of single and compound natural hazards due to climate change require increased attention since it may imply new challenges to emergency response systems and new threats to society. Especially, how emergency response systems can prepare for and respond to these hazards by using knowledge of the interactions between different natural events. The purpose of this thesis is to increase the knowledge on interactions between natural hazards, investigate how multiple natural hazards lead to challenges for emergency response systems, and how these challenges can be addressed. The purpose can be further divided into three objectives: (i) to identify relevant multiple natural hazards in a Swedish context, (ii) to identify planning and decision-making challenges these hazards may imply for emergency response systems, and (iii) to develop a decision support tool addressing one of these challenges. The objectives have been addressed in three sub-studies, one for each of the objectives, leading to the production of four papers. The first sub-study focused on the first objective and resulted in the construction of a national natural hazard interaction framework for Sweden, which is presented in Paper 1. The second sub-study focused on the second objective, leading to the identification of needs for information, planning, and decision support systems in the Swedish emergency response system. The results from this study are presented in Paper 2 and 3. The third and last sub-study focused on the development of a decision support tool addressing one of the needs identified in the second sub-study. The sub-study led to the development of an optimization model for resource preparedness location planning, presented in Paper 4. This thesis contributes to the emergency management field, both scientifically and practically. The scientific contributions are the development of a national natural hazard interactions framework and a resource preparedness location model for wildfires, both filling gaps in the current knowledge. Also, the thesis contributes scientifically through the alternative applications of theory, which can inform the research community in future studies. The natural hazard interaction framework and the resource preparedness location model for wildfires are also considered practical contributions. The former can support the extension of regional and local risk and vulnerability analyses to also include multiple natural hazards, while the latter sheds light on the potential of optimization-based decision support tools to increase preparedness to natural hazards.
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| 9. |
- Sköld Gustafsson, Viktor, et al.
(författare)
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Identifying decision support needs for emergency response to multiple natural hazards: an activity theory approach
- 2023
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Ingår i: Natural Hazards. - : Springer. - 0921-030X .- 1573-0840.
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Tidskriftsartikel (refereegranskat)abstract
- Planning and decision making in emergency response systems face new challenges due to climate changes and the increased risk of multiple or compound natural hazards. This is especially the case in areas with inexperience of such events. The aim of this paper is to identify important activities concerning planning and decision-making during responses to natural hazards, and their potential need for decision support. The knowledge base of the study consists of interviews with 12 representatives from the Swedish emergency response system, supplemented by documents covering policies, operations, and responsibility. Thematic coding was applied to the interview data for identification of important planning and decision activities. Needs of decision support were identified by applying activity theory to the identified activities. We found needs of decision support connected to eight identified key activities concerning consequence analysis, national reinforcements, and resource management. The results illuminate a lack of technology to support response activities during both single and multiple natural hazards. The findings can inform policy makers of emergency response of where to concentrate the development of tools for collaborative preparedness and response work to cope with future challenges from natural hazards.
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| 10. |
- Sköld Gustafsson, Viktor, et al.
(författare)
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Managing Natural Hazards in Sweden – Needs for Improved Information and Decision Support Systems
- 2022
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Ingår i: ISCRAM 2022 Conference Proceedings – 19th International Conference on Information Systems for Crisis Response and Management. - 9788284270999 ; , s. 376-384
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Konferensbidrag (refereegranskat)abstract
- This paper explores opportunities for information systems to support emergency response to multiple natural hazards. Interviews were conducted with 12 representatives from actors of the Swedish emergency response system about response to multiple natural hazards. Challenges and needs connected to five themes influencing the response effort were identified: Cooperation, Resource management, Command and control, Common operational picture, and Risk management. The results illuminate a lack of technology to support decisions and analyses during emergency response to both single and multiple natural hazards. Based on this, the paper suggests and discusses information systems and decision support tools to assist in satisfying the identified needs. The findings can inform policy makers in emergency response of where to concentrate the development of collaborative preparedness and response work, and the scientific community of future research directions.
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