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On the relationship...
On the relationship between unit cells and channel systems in high silica zeolites with the butterfly projection
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- Guo, Peng (författare)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
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- Wan, Wei (författare)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
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- McCusker, Lynne (författare)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK),Laboratory of Crystallography, ETH Zurich, Switzerland
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Baerlocher, Christian (författare)
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- Zou, Xiaodong (författare)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
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(creator_code:org_t)
- 2015-03-28
- 2015
- Engelska.
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Ingår i: Zeitschrift für Kristallographie - Crystalline Materials. - : Walter de Gruyter GmbH. - 2194-4946 .- 2196-7105. ; 230:5, s. 301-309
- Relaterad länk:
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https://www.research...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Zeolites are crystalline aluminosilicate framework materials with corner sharing TO 4 (T = Al, Si) tetrahedra forming well-defined pores and channels. Many zeolites are built from similar building units (i.e., isolated units, chains or layers), which are connected in different ways to form a variety of topologies. We have identified ten zeolite frameworks that share the same two-dimensional butterfly net containing 5-, 6- and 10-rings: (MRE)-M-star, FER, MEL, SZR, MFS, MFI, TUN, IMF, BOG and TON. Different orientations of the TO4 tetrahedra within the layer lead to different connectivities between neighboring layers. Some layers are corrugated and some are flat, resulting in different channel systems parallel to the layer. We found some interesting relationships between the unit cell parameters and this channel system that allow the size of the channels and their directions to be deduced from the unit cell dimensions. This may facilitate the prediction of new members of this zeolite family. In addition, other zeolites containing the butterfly layers are also discussed.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Nyckelord
- structure prediction
- structure relationship
- structure solution
- zeolites
- Inorganic Chemistry
- oorganisk kemi
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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