| 1. |
- Ardo, Shane, et al.
(author)
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Pathways to electrochemical solar-hydrogen technologies
- 2018
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In: Energy & Environmental Science. - : Royal Society of Chemistry. - 1754-5692 .- 1754-5706. ; 11:10, s. 2768-2783
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Research review (peer-reviewed)abstract
- Solar-powered electrochemical production of hydrogen through water electrolysis is an active and important research endeavor. However, technologies and roadmaps for implementation of this process do not exist. In this perspective paper, we describe potential pathways for solar-hydrogen technologies into the marketplace in the form of photoelectrochemical or photovoltaic-driven electrolysis devices and systems. We detail technical approaches for device and system architectures, economic drivers, societal perceptions, political impacts, technological challenges, and research opportunities. Implementation scenarios are broken down into short-term and long-term markets, and a specific technology roadmap is defined. In the short term, the only plausible economical option will be photovoltaic-driven electrolysis systems for niche applications. In the long term, electrochemical solar-hydrogen technologies could be deployed more broadly in energy markets but will require advances in the technology, significant cost reductions, and/ or policy changes. Ultimately, a transition to a society that significantly relies on solar-hydrogen technologies will benefit from continued creativity and influence from the scientific community.
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| 2. |
- Freier, Christian, et al.
(author)
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Mobile quantum gravity sensor with unprecedented stability
- 2016
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In: Journal of Physics: Conference Series. - : IOP Publishing. - 1742-6588 .- 1742-6596. ; 723:1, s. Art. no. 012050-
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Conference paper (peer-reviewed)abstract
- Changes of surface gravity on Earth are of great interest in geodesy, earth sciencesand natural resource exploration. They are indicative of Earth system's mass redistributions andvertical surface motion, and are usually measured with falling corner-cube- and superconductinggravimeters (FCCG and SCG). Here we report on absolute gravity measurements with amobile quantum gravimeter based on atom interferometry. The measurements were conductedin Germany and Sweden over periods of several days with simultaneous SCG and FCCGcomparisons. They show the best-reported performance of mobile atomic gravimeters todate with an accuracy of 39 nm/s^2, long-term stability of 0,5 nm/s^2 and short-term noise of 96 nm/s^2/(Hz)^1/2. These measurements highlight the unique properties of atomic sensors. Theachieved level of performance in a transportable instrument enables new applications in geodesyand related Fields, such as continuous absolute gravity monitoring with a single instrument underrough environmental conditions.
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| 3. |
- Hans, Marcus, et al.
(author)
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Stress-Dependent Elasticity of TiAlN Coatings
- 2019
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In: Coatings. - : MDPI. - 2079-6412. ; 9:1
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Journal article (peer-reviewed)abstract
- We investigate the effect of continuous vs. periodically interrupted plasma exposure during cathodic arc evaporation on the elastic modulus as well as the residual stress state of metastable cubic TiAlN coatings. Nanoindentation reveals that the elastic modulus of TiAlN grown at floating potential with continuous plasma exposure is 7%-11% larger than for coatings grown with periodically interrupted plasma exposure due to substrate rotation. In combination with X-ray stress analysis, it is evident that the elastic modulus is governed by the residual stress state. The experimental dependence of the elastic modulus on the stress state is in excellent agreement with ab initio predictions. The macroparticle surface coverage exhibits a strong angular dependence as both density and size of incorporated macroparticles are significantly lower during continuous plasma exposure. Scanning transmission electron microscopy in combination with energy dispersive X-ray spectroscopy reveals the formation of underdense boundary regions between the matrix and TiN-rich macroparticles. The estimated porosity is on the order of 1% and a porosity-induced elastic modulus reduction of 5%-9% may be expected based on effective medium theory. It appears reasonable to assume that these underdense boundary regions enable stress relaxation causing the experimentally determined reduction in elastic modulus as the population of macroparticles is increased.
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| 4. |
- Moshontz, Hannah, et al.
(author)
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The Psychological Science Accelerator: Advancing Psychology Through a Distributed Collaborative Network
- 2018
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In: Advances in Methods and Practices in Psychological Science. - : SAGE Publications. - 2515-2459 .- 2515-2467. ; 1:4, s. 501-515
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Journal article (peer-reviewed)abstract
- Concerns about the veracity of psychological research have been growing. Many findings in psychological science are based on studies with insufficient statistical power and nonrepresentative samples, or may otherwise be limited to specific, ungeneralizable settings or populations. Crowdsourced research, a type of large-scale collaboration in which one or more research projects are conducted across multiple lab sites, offers a pragmatic solution to these and other current methodological challenges. The Psychological Science Accelerator (PSA) is a distributed network of laboratories designed to enable and support crowdsourced research projects. These projects can focus on novel research questions or replicate prior research in large, diverse samples. The PSA’s mission is to accelerate the accumulation of reliable and generalizable evidence in psychological science. Here, we describe the background, structure, principles, procedures, benefits, and challenges of the PSA. In contrast to other crowdsourced research networks, the PSA is ongoing (as opposed to time limited), efficient (in that structures and principles are reused for different projects), decentralized, diverse (in both subjects and researchers), and inclusive (of proposals, contributions, and other relevant input from anyone inside or outside the network). The PSA and other approaches to crowdsourced psychological science will advance understanding of mental processes and behaviors by enabling rigorous research and systematic examination of its generalizability.
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| 5. |
- Stelzer, Bastian, et al.
(author)
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Remote Tracking of Phase Changes in Cr2AlC Thin Films by In-situ Resistivity Measurements
- 2019
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In: Scientific Reports. - : NATURE PUBLISHING GROUP. - 2045-2322. ; 9
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Journal article (peer-reviewed)abstract
- Resistivity changes of magnetron sputtered, amorphous Cr2AlC thin films were measured during heating in vacuum. Based on correlative X-ray diffraction, in-situ and ex-situ selected area electron diffraction measurements and differential scanning calorimetry data from literature it is evident that the resistivity changes at 552 +/- 4 and 585 +/- 13 degrees C indicate the phase transitions from amorphous to a hexagonal disordered solid solution structure and from the latter to MAX phase, respectively. We have shown that phase changes in Cr2AlC thin films can be revealed by in-situ measurements of thermally induced resistivity changes.
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