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- Wills, J. M., et al.
(författare)
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A novel electronic configuration of the 5f states in delta-plutonium as revealed by the photo-electron spectra
- 2004
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Ingår i: Journal of Electron Spectroscopy and Related Phenomena. - : Elsevier BV. - 0368-2048 .- 1873-2526. ; 135:2-3, s. 163-166
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Tidskriftsartikel (refereegranskat)abstract
- We present a theoretical model, the mixed-level model, aiming at describing metals with very complex, strongly correlated, electronic structures. As a demonstration, it is applied to the electronic structure of delta-Pu. The model reproduces the electronic-structure related properties of this complex metal; in particular, the theory is capable of reproducing the valence band photoemission spectrum of delta-Pu. We also report new experimental photoemission spectra at several photon energies. Taken together, our results provide strong evidence that the electronic structure of delta-Pu involves a 5f shell with four electrons in a localized multiplet hybridizing with valence states, and approximately one 5f electron forming a completely delocalized band state.
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| 2. |
- Wahlin, Karl, et al.
(författare)
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Reduced Models of the Retention of Nitrogen in Catchments
- 2004
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Ingår i: Proceedings of the International Environmental Modelling and Software Society Conference (iEMSs), 14-17 June, Osnabrück, Germany. ; , s. 1081-1086
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Konferensbidrag (refereegranskat)abstract
- Process-oriented models of the retention of nitrogen in catchments are by necessity rather complex. We introduced several types of ensemble runs that can provide informative summaries of meteorologically normalised model outputs and also clarify the extent to which such outputs are related to various model parameters. Thereafter we employed this technique to examine policy-relevant outputs of the catchment model INCA-N. In particular, we examined how long it will take for changes in the application of fertilisers on cultivated land to affect the predicted riverine loads of nitrogen. The results showed that the magnitude of the total intervention effect was influenced mainly by the parameters governing the turnover of nitrogen in soil, whereas the temporal distribution of the water quality response was determined primarily by the hydromechanical model parameters. This raises the question of whether the soil nitrogen processes included in the model are elaborate enough to correctly explain the widespread observations of slow water quality responses to changes in agricultural practices.
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