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Sökning: WFRF:(Carbajal R.) > (2020-2023)

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  • Kereszturi, Gabor, et al. (författare)
  • Porosity, strength, and alteration - Towards a new volcano stability assessment tool using VNIR-SWIR reflectance spectroscopy
  • 2023
  • Ingår i: Earth and Planetary Science Letters. - : Elsevier. - 0012-821X .- 1385-013X. ; 602
  • Tidskriftsartikel (refereegranskat)abstract
    • Volcano slope stability analysis is a critical component of volcanic hazard assessments and monitoring. However, traditional methods for assessing rock strength require physical samples of rock which may be difficult to obtain or characterize in bulk. Here, visible to shortwave infrared (350-2500 nm; VNIR-SWIR) reflected light spectroscopy on laboratory-tested rock samples from Ruapehu, Ohakuri, Whakaari, and Banks Peninsula (New Zealand), Merapi (Indonesia), Chaos Crags (USA), Styrian Basin (Austria) and La Soufriere de Guadeloupe (Eastern Caribbean) volcanoes was used to design a novel rapid chemometric-based method to estimate uniaxial compressive strength (UCS) and porosity. Our Partial Least Squares Regression models return moderate accuracies for both UCS and porosity, with R2 of 0.43-0.49 and Mean Absolute Percentage Error (MAPE) of 0.2-0.4. When laboratory-measured porosity is included with spectral data, UCS prediction reaches an R2 of 0.82 and MAPE of 0.11. Our models highlight that the observed changes in the UCS are coupled with subtle mineralogical changes due to hydrothermal alteration at wavelengths of 360-438, 532-597, 1405-1455, 2179-2272, 2332-2386, and 2460-2490 nm. These mineralogical changes include mineral replacement, precipitation hydrothermal alteration processes which impact the strength of volcanic rocks, such as mineral replacement, precipitation, and/or silicification. Our approach highlights that spectroscopy can provide a first order assessment of rock strength and/or porosity or be used to complement laboratory porosity-based predictive models. VNIR-SWIR spectroscopy therefore provides an accurate non-destructive way of assessing rock strength and alteration mineralogy, even from remote sensing platforms. (c) 2022 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
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  • Heap, Michael J., et al. (författare)
  • The tensile strength of hydrothermally altered volcanic rocks
  • 2022
  • Ingår i: Journal of Volcanology and Geothermal Research. - : Elsevier. - 0377-0273 .- 1872-6097. ; 428
  • Tidskriftsartikel (refereegranskat)abstract
    • The tensile strength of volcanic rocks is an important parameter for understanding and modelling a wide range of volcanic processes, and in the development of strategies designed to optimise energy production in volcanic geothermal reservoirs. However, despite the near-ubiquity of hydrothermal alteration at volcanic and geothermal systems, values of tensile strength for hydrothermally altered volcanic rocks are sparse. Here, we present an experimental study in which we measured the tensile strength of variably altered volcanic rocks. The alteration of these rocks, quantified as the weight percentage of secondary (alteration) minerals, varied from 6 to 62.8 wt%. Our data show that tensile strength decreases as a function of porosity, in agreement with previous studies, and as a function of alteration. We fit existing theoretical constitutive models to our data so that tensile strength can be estimated for a given porosity, and we provide a transformation of these models such that they are a function of alteration. However, because porosity and alteration influence each other, it is challenging to untangle their individual contributions to the measured reduction in tensile strength. Our new data and previously published data suggest that porosity exerts a first-order role on the tensile strength of volcanic rocks. Based on our data and observations, we also suggest that (1) alteration likely decreases tensile strength if associated with mineral dissolution, weak secondary minerals (such as clays), and an increase in microstructural heterogeneity and (2) alteration likely increases tensile strength if associated with pore- and crack-filling mineral precipitation. Therefore, we conclude that both alteration intensity and alteration type likely influence tensile strength. To highlight the implications of our findings, we provide discrete element method modelling which shows that, following the pressurisation of a dyke, the damage within weak hydrothermally altered host-rock is greater and more widespread than for strong hydrothermally altered host-rock. Because the rocks in volcanic and geothermal settings are likely to be altered, our results suggest that future modelling should consider the tensile strength of hydrothermally altered volcanic rocks.
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  • Heap, Michael J., et al. (författare)
  • Whole-rock oxygen isotope ratios as a proxy for the strength and stiffness of hydrothermally altered volcanic rocks
  • 2022
  • Ingår i: Bulletin of Volcanology. - : Springer Nature. - 0258-8900 .- 1432-0819. ; 84:8
  • Tidskriftsartikel (refereegranskat)abstract
    • Hydrothermal alteration is considered to increase the likelihood of dome or flank collapse by compromising stability. Understanding how such alteration influences rock properties, and providing independent metrics for alteration that can be used to estimate these parameters, is therefore important to better assess volcanic hazards and mitigate risk. We explore the possibility of using whole-rock delta O-18 and delta D values and water contents, metrics that can potentially track alteration, to estimate the strength (compressive and tensile) and Young's modulus (i.e. "stiffness") of altered (acid-sulphate) volcanic rocks from La Soufriere de Guadeloupe (Eastern Caribbean). The delta O-18 values range from 5.8 to 13.2 parts per thousand, delta D values from - 151 to - 44 parts per thousand, and water content from 0.3 to 5.1 wt%. We find that there is a good correlation between delta O-18 values and laboratory-measured strength and Young's modulus, but that these parameters do not vary systematically with delta D or water content (likely due to their pre-treatment at 200 degrees C). Empirical linear relationships that allow strength and Young's modulus to be estimated using delta O-18 values are provided using our new data and published data for Merapi volcano (Indonesia). Our study highlights that delta O-18 values can be used to estimate the strength and Young's modulus of volcanic rocks, and could therefore be used to provide parameters for volcano stability modelling. One advantage of this technique is that delta O-18 only requires a small amount of material, and can therefore provide rock property estimates in scenarios where material is limited, such as borehole cuttings or when sampling large blocks is impracticable.
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