| 1. |
- Cui, Yanxia, et al.
(författare)
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Exciting multiple plasmonic resonances by a double-layered metallic nanostructure
- 2011
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Ingår i: Journal of the Optical Society of America. B, Optical physics. - 0740-3224 .- 1520-8540. ; 28:11, s. 2827-2832
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Tidskriftsartikel (refereegranskat)abstract
- By placing a metallic layer of a periodic nanostrip array above a metallic layer of a periodic nanogroove array with a separation of 120nm, we obtain a triple-band thin film absorber with all its resonant wavelengths displaying absorptivity greater than 90%. Through a systematic study of the current compound structure, we find these three absorption peaks mainly depend on some simple resonances, i.e., the modes supported by the nanostrip array in the top layer, the nanogroove array in the bottom layer, and the horizontal cavity between the two layers. In addition, we show that this kind of absorber is quite robust and fairly insusceptible to the parallel shift between the two different layers. This study should contribute to the design of thin film absorbers/ emitters.
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| 2. |
- Cui, Yanxia, et al.
(författare)
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Plasmon-Assisted Optical Curtains
- 2010
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Ingår i: PLASMONICS. - : Springer Nature. - 1557-1955 .- 1557-1963. ; 5:4, s. 369-374
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Tidskriftsartikel (refereegranskat)abstract
- We predict an optical curtain effect, i.e., formation of a spatially invariant light field as light emerges from a set of periodic metallic nano-objects. The underlying physical mechanism of generation of this unique optical curtain can be explained in both the spatial domain and the wave-vector domain. In particular, in each period, we use one metallic nanostrip to equate the amplitudes of lights impinging on the openings of two metallic nanoslits and also shift their phases by pi difference. We elaborate the influence on the output effect from some geometrical parameters like the periodicity, the slit height, and so on. By controlling the light illuminated on metallic subwavelength apertures, it is practical to generate optical curtains of arbitrary forms, which may open new routes of plasmonic nanolithography.
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| 3. |
- Cui, Yanxia, et al.
(författare)
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Ultrabroadband Light Absorption by a Sawtooth Anisotropic Metamaterial Slab
- 2012
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Ingår i: Nano Letters. - : American Chemical Society (ACS). - 1530-6984 .- 1530-6992. ; 12:3, s. 1443-1447
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Tidskriftsartikel (refereegranskat)abstract
- We present an ultrabroadband thin-film infrared absorber made of sawtoothed anisotropic metamaterial. Absorptivity of higher than 95% at normal incidence is supported in a wide range of frequencies, where the full absorption width at half-maximum is about 86%. Such property is retained well at a very wide range of incident angles too. Light of shorter wavelengths are harvested at upper parts of the sawteeth of smaller widths, while light of longer wavelengths are trapped at lower parts of larger tooth widths. This phenomenon is explained by the slowlight modes in anisotropic metamaterial waveguide. Our study can be applied in the field of designing photovoltaic devices and thermal emitters.
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| 4. |
- Galand, Marina, et al.
(författare)
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Ionization sources in Titan's deep ionosphere
- 2010
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Ingår i: Journal of Geophysical Research. - 0148-0227 .- 2156-2202. ; 115, s. A07312-
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Tidskriftsartikel (refereegranskat)abstract
- We analyze a multi-instrumental data set from four Titan encounters by the Cassini spacecraft to investigate in detail the formation of the ionosphere. The data set includes observations of thermospheric and ionospheric species and suprathermal electrons. A model describing the solar and electron energy deposition is used as an organizing element of the Cassini data set. We first compare the calculated secondary electron production rates with the rates inferred from suprathermal electron intensity measurements. We then calculate an effective electron dissociative recombination coefficient, applying three different approaches to the Cassini data set. Our findings are threefold: (1) The effective recombination coefficient derived under sunlit conditions in the deep ionosphere (< 1200 km) is found to be independent of solar zenith angle and flyby. Its value ranges from 6.9 x 10(-7) cm(3) s(-1) at 1200 km to 5.9 x 10(-6) cm(3) s(-1) at 970 km at 500 K. (2) The presence of an additional, minor source of ionization is revealed when the solar contribution is weak enough. The contribution by this non-solar source-energetic electrons most probably of magnetospheric origin-becomes apparent for secondary electron production rates, due to solar illumination alone, close to or smaller than about 3 x 10(-1) cm(-3) s(-1). Such a threshold is reached near the solar terminator below the main solar-driven electron production peak (< 1050 km). (3) Our ability to model the electron density in the deep ionosphere is very limited. Our findings highlight the need for more laboratory measurements of electron dissociative recombination coefficients for heavy ion species at high electron temperatures (especially near 500 K).
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| 5. |
- Hu, Jiwen, et al.
(författare)
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A rhodamine-based fluorescent probe for Hg2+ and its application for biological visualization
- 2014
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Ingår i: Sensors and actuators. B, Chemical. - : Elsevier. - 0925-4005 .- 1873-3077. ; 203, s. 452-458
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Tidskriftsartikel (refereegranskat)abstract
- A new visible light excitable fluorescent probe (1) is synthesized by appending a hydroxymethyl-pyridine to rhodamine B hydrazide. The probe displays very specific Hg2+-induced colour change and fluorescent enhancement in the aqueous systems. The "turn-on" response of fluorescence is based on a binding-induced ring-opening process from the spirolactam (nonfluorescent) to acyclic xanthene (fluorescent) in rhodamine B. The coordinating atoms O-center dot-N-N-O-center dot from the hydroxymethyl-pyridine and rhodamine B hydrazide play dominant role in the formation of a complex with 1:1 stoichiometry of Hg2+ to 1. It exhibits a linear response in the range of 0.1-5 mu M with the limit of detection (LOD) of 15.7 nM (3 sigma/slope), while the calculated value of the association constant of Hg2+/1 is 0.70 x 10(5) M-1. Furthermore, confocal microscopy imaging experiment demonstrates the probe 1 can be applied as a fluorescent probe for visualization of Hg2+ in living HeLa cells.
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| 6. |
- Hu, Zhang-Jun, et al.
(författare)
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A facile "click" reaction to fabricate a FRET-based ratiometric fluorescent Cu2+ probe
- 2014
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Ingår i: Journal of materials chemistry. B. - : Royal Society of Chemistry. - 2050-750X .- 2050-7518. ; 2:28, s. 4467-4472
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Tidskriftsartikel (refereegranskat)abstract
- A facile one-step Cu(I)-catalyzed "click" reaction, between a dansyl-azide and a propargyl-substituted rhodamine B hydrazide, is employed to fabricate a novel FRET ratiometric "off-on" fluorescent probe. The sensitive emission of the donor, a dansyl group, overlaps perfectly with the absorption of the acceptor, xanthene in the open-ring rhodamine. The proposed probe shows high selectivity towards Cu2+. The ratio of emission intensities at 568 and 540 nm (I-568/I-540) exhibits a drastic 28-fold enhancement upon addition of Cu2+. The probe shows an excellent linear relationship between emission ratios and the concentrations of Cu2+ from 10 to 50 mu M, with a detection limit (S/N = 3) of 0.12 mu M. The preliminary cellular studies demonstrated that the probe is cell membrane permeable and could be applied for ratiometric fluorescence imaging of intracellular Cu2+ with almost no cytotoxicity. The ingenuity of the probe design is to construct a FRET donor-acceptor interconnector and a selective receptor simultaneously by "click" reaction. The strategy was verified to have great potential for developing novel FRET probes for Cu2+.
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| 7. |
- Hu, Zhang-Jun, et al.
(författare)
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Optimization of ethylenediamine-grafted multiwalled carbon nanotubes for solid-phase extraction of lead cations
- 2012
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Ingår i: Environmental Science and Pollution Research. - : Springer. - 0944-1344 .- 1614-7499. ; 19:4, s. 1237-1244
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Tidskriftsartikel (refereegranskat)abstract
- IntroductionEthylenediamine-grafted multiwalled carbon nanotubes (MWCNTs-EDA-I and MWCNTs-EDA-II) are optimized and employed to investigate the preconcentration of lead ions (Pb(II)) in trace level.ResultsThe results show that Pb(II) can be adsorbed quantitatively on the optimized MWCNTs in the range of pH 4–7 and MWCNTs-EDA-I has a higher maximum Pb(II) adsorption capacity (157.19 mg/g) than MWCNTs-EDA-II (89.16 mg/g). The adsorbed Pb(II) can be eluted completely using 5 mL of 1 mol/L HNO3.DiscussionA new approach using a microcolumn packed with the obtained MWCNTs-EDA-I has been developed for the preconcentration of trace amount of Pb(II). Parameters influencing the preconcentration of Pb(II), such as pH of the sample, sample volume, elution solution, and interfering ions, have been examined and optimized in detail. Under optimum experimental conditions, the limit of detection is 0.30 ng/mL with the enrichment factor of 60. The relative standard deviation (R.S.D) was 2.6% at the 20 ng/mL Pb(II) level.ConclusionThe method has been applied for the preconcentration of trace amount of Pb(II) in environmental water samples with satisfying results.
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| 8. |
- Okada, Yukinori, et al.
(författare)
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Genetics of rheumatoid arthritis contributes to biology and drug discovery
- 2014
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Ingår i: Nature. - : Nature Publishing Group. - 0028-0836 .- 1476-4687. ; 506:7488, s. 376-381
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Tidskriftsartikel (refereegranskat)abstract
- A major challenge in human genetics is to devise a systematic strategy to integrate disease-associated variants with diverse genomic and biological data sets to provide insight into disease pathogenesis and guide drug discovery for complex traits such as rheumatoid arthritis (RA)(1). Here we performed a genome-wide association study meta-analysis in a total of >100,000 subjects of European and Asian ancestries (29,880 RA cases and 73,758 controls), by evaluating similar to 10 million single-nucleotide polymorphisms. We discovered 42 novel RA risk loci at a genome-wide level of significance, bringing the total to 101 (refs 2-4). We devised an in silico pipeline using established bioinformatics methods based on functional annotation(5), cis-acting expression quantitative trait loci(6) and pathway analyses(7-9)-as well as novel methods based on genetic overlap with human primary immunodeficiency, haematological cancer somatic mutations and knockout mouse phenotypes-to identify 98 biological candidate genes at these 101 risk loci. We demonstrate that these genes are the targets of approved therapies for RA, and further suggest that drugs approved for other indications may be repurposed for the treatment of RA. Together, this comprehensive genetic study sheds light on fundamental genes, pathways and cell types that contribute to RA pathogenesis, and provides empirical evidence that the genetics of RA can provide important information for drug discovery.
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| 9. |
- Zhang, Guojie, et al.
(författare)
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Comparative genomics reveals insights into avian genome evolution and adaptation
- 2014
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Ingår i: Science. - : American Association for the Advancement of Science (AAAS). - 0036-8075 .- 1095-9203. ; 346:6215, s. 1311-1320
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Tidskriftsartikel (refereegranskat)abstract
- Birds are the most species-rich class of tetrapod vertebrates and have wide relevance across many research fields. We explored bird macroevolution using full genomes from 48 avian species representing all major extant clades. The avian genome is principally characterized by its constrained size, which predominantly arose because of lineage-specific erosion of repetitive elements, large segmental deletions, and gene loss. Avian genomes furthermore show a remarkably high degree of evolutionary stasis at the levels of nucleotide sequence, gene synteny, and chromosomal structure. Despite this pattern of conservation, we detected many non-neutral evolutionary changes in protein-coding genes and noncoding regions. These analyses reveal that pan-avian genomic diversity covaries with adaptations to different lifestyles and convergent evolution of traits.
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