| 1. |
- Anderson, Richard I., et al.
(författare)
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VELOcities of CEpheids (VELOCE) : I. High-precision radial velocities of Cepheids
- 2024
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Ingår i: Astronomy and Astrophysics. - 0004-6361. ; 686
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Tidskriftsartikel (refereegranskat)abstract
- We present the first data release of VELOcities of CEpheids (VELOCE), dedicated to measuring the high-precision radial velocities (RVs) of Galactic classical Cepheids (henceforth, Cepheids). The first data release (VELOCE DR1) comprises 18 225 RV measurements of 258 bona fide classical Cepheids on both hemispheres collected mainly between 2010 and 2022, along with 1161 observations of 164 stars, most of which had previously been misclassified as Cepheids. The median per-observation RV uncertainty for Cepheids is 0.037 km s-1 and reaches 2 m s-1 for the brightest stars observed with Coralie. Non-variable standard stars were used to characterize RV zero-point stability and to provide a base for future cross-calibrations. We determined zero-point differences between VELOCE and 31 literature data sets using template fitting, which we also used to investigate linear period changes of 146 Cepheids. In total, 76 spectroscopic binary Cepheids and 14 candidate binary Cepheids were identified using VELOCE data alone, which are investigated in detail in a companion Paper (VELOCE II). VELOCE DR1 provides a number of new insights into the pulsational variability of Cepheids, most importantly: a) the most detailed description of the Hertzsprung progression based on RVs to date; b) the identification of double-peaked bumps in the pulsation curve; and c) clear evidence that virtually all Cepheids feature spectroscopic variability signals that lead to modulated RV variability at the level of tens to hundreds of m s-1 and that cannot be satisfactorily modeled using single-periodic Fourier series. We identified 36 stars exhibiting such modulated variability, of which 4 also exhibit orbital motion. Linear radius variations depend strongly on pulsation period and a steep increase in slope of the ΔR/p vs. log P-relation is found near 10 days. This effect, combined with significant RV amplitude differences at fixed period, challenges the existence of a tight relation between Baade-Wesselink projection factors and pulsation periods. We investigated the accuracy of RV time series measurements, Uγ, and RV amplitudes published by Gaia's third data release (Gaia DR3) and determined an offset of 0.65 ± 0.11 km s-1 relative to VELOCE. Whenever possible, we recommend adopting a single set of template correlation parameters for distinct classes of large-amplitude variable stars to avoid systematic offsets in Uγ among stars belonging to the same class. The peak-to-peak amplitudes of Gaia RVs exhibit significant (16%) dispersion. Potential differences of RV amplitudes require further inspection, notably in the context of projection factor calibration.
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| 2. |
- Borne, Kurtis D., et al.
(författare)
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Ultrafast electronic relaxation pathways of the molecular photoswitch quadricyclane
- 2024
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Ingår i: NATURE CHEMISTRY. - : Springer Nature. - 1755-4330 .- 1755-4349. ; 16, s. 499-505
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Tidskriftsartikel (refereegranskat)abstract
- The light-induced ultrafast switching between molecular isomers norbornadiene and quadricyclane can reversibly store and release a substantial amount of chemical energy. Prior work observed signatures of ultrafast molecular dynamics in both isomers upon ultraviolet excitation but could not follow the electronic relaxation all the way back to the ground state experimentally. Here we study the electronic relaxation of quadricyclane after exciting in the ultraviolet (201 nanometres) using time-resolved gas-phase extreme ultraviolet photoelectron spectroscopy combined with non-adiabatic molecular dynamics simulations. We identify two competing pathways by which electronically excited quadricyclane molecules relax to the electronic ground state. The fast pathway (<100 femtoseconds) is distinguished by effective coupling to valence electronic states, while the slow pathway involves initial motions across Rydberg states and takes several hundred femtoseconds. Both pathways facilitate interconversion between the two isomers, albeit on different timescales, and we predict that the branching ratio of norbornadiene/quadricyclane products immediately after returning to the electronic ground state is approximately 3:2.
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| 3. |
- Lara-Gonzalez, Samuel, et al.
(författare)
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Substrate-induced dimerization of engineered monomeric variants of triosephosphate isomerase from trichomonas vaginalis
- 2015
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Ingår i: PLoS ONE. - : Public Library of Science (PLoS). - 1932-6203. ; 10
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Tidskriftsartikel (refereegranskat)abstract
- The dimeric nature of triosephosphate isomerases (TIMs) is maintained by an extensive surface area interface of more than 1600 Å2. TIMs from Trichomonas vaginalis (TvTIM) are held in their dimeric state by two mechanisms: A ball and socket interaction of residue 45 of one subunit that fits into the hydrophobic pocket of the complementary subunit and by swapping of loop 3 between subunits. TvTIMs differ from other TIMs in their unfolding energetics. In TvTIMs the energy necessary to unfold a monomer is greater than the energy necessary to dissociate the dimer. Herein we found that the character of residue I45 controls the dimer-monomer equilibrium in TvTIMs. Unfolding experiments employing monomeric and dimeric mutants led us to conclude that dimeric TvTIMs unfold following a four state model denaturation process whereas monomeric TvTIMs follow a three state model. In contrast to other monomeric TIMs, monomeric variants of TvTIM1 are stable and unexpectedly one of them (I45A) is only 29-fold less active than wild-type TvTIM1. The high enzymatic activity of monomeric TvTIMs contrast with the marginal catalytic activity of diverse monomeric TIMs variants. The stability of the monomeric variants of TvTIM1 and the use of cross-linking and analytical ultracentrifugation experiments permit us to understand the differences between the catalytic activities of TvTIMs and other marginally active monomeric TIMs. As TvTIMs do not unfold upon dimer dissociation, herein we found that the high enzymatic activity of monomeric TvTIM variants is explained by the formation of catalytic dimeric competent species assisted by substrate binding.
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| 4. |
- Sedaghati, Elyar, et al.
(författare)
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A spectral survey of WASP-19b with ESPRESSO
- 2021
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Ingår i: Monthly Notices of the Royal Astronomical Society. - : Oxford University Press (OUP). - 0035-8711 .- 1365-2966. ; 505:1, s. 435-458
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Forskningsöversikt (refereegranskat)abstract
- High-resolution precision spectroscopy provides a multitude of robust techniques for probing exoplanetary atmospheres. We present multiple VLT/ESPRESSO transit observations of the hot-Jupiter exoplanet WASP-19b with previously published but disputed atmospheric features from lowresolution studies. Through spectral synthesis and modelling of the Rossiter-McLaughlin (RM) effect we calculate stellar, orbital and physical parameters for the system. From narrow-band spectroscopy we do not detect any of HI, FeI, MgI, CaI, NaI, and KI neutral species, placing upper limits on their line contrasts. Through cross-correlation analyses with atmospheric models, we do not detect Fe I and place a 3σ upper limit of log (XFe/X⊙) ≈ -1.83 ± 0.11 on its mass fraction, from injection and retrieval. We show the inability to detect the presence of H2O for known abundances, owing to lack of strong absorption bands, as well as relatively low S/N ratio. We detect a barely significant peak (3.02±0.15 σ) in the cross-correlation map for TiO, consistent with the sub-solar abundance previously reported. This is merely a hint for the presence of TiO and does not constitute a confirmation. However, we do confirm the presence of previously observed enhanced scattering towards blue wavelengths, through chromatic RM measurements, pointing to a hazy atmosphere. We finally present a reanalysis of low-resolution transmission spectra of this exoplanet, concluding that unocculted starspots alone cannot explain previously detected features. Our reanalysis of the FORS2 spectra of WASP-19b finds a ~100× sub-solar TiO abundance, precisely constrained to log XTiO ≈ -7.52 ± 0.38, consistent with the TiO hint from ESPRESSO. We present plausible paths to reconciliation with other seemingly contradicting results.
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