Reversible Ionic Polarization in Metal Halide Perovskites

• Metal halide perovskites have emerged as promising photovoltaic materials with attractive photoelectronic properties. However, the fundamental mechanisms for their outstanding properties are still elusive. In this work, we reveal the reversible bulk ionic polarization property of perovskites through studying the photoelectric response on the controllable states by electrical poling from room temperature to low temperature (200 K). The overall increase in light absorption, photoconductance, and carrier recombination lifetime demonstrates that the bulk ionic polarization contributes to the excellent photoelectric properties of halide perovskites. Moreover, we also discuss the role of ionic polarization in the overshoot transient photocurrent relaxation phenomenon after the electrical poling. This work would promote deep understanding in the unique properties of perovskites and their excellent photovoltaic performance.

Ämnesord

NATURVETENSKAP  -- Fysik -- Den kondenserade materiens fysik (hsv//swe)

NATURAL SCIENCES  -- Physical Sciences -- Condensed Matter Physics (hsv//eng)

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