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- Ghazzali, Mohamed I D M, 1974, et al.
(författare)
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4,4'-(Azinodimethylene)dipyridinium bis(tetrafluoroborate) and 4-[(4-pyridylmethylene)hydrazonomethyl]pyridinium perchlorate: two different hydrogen-bonding motifs
- 2007
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Ingår i: Acta Crystallographica Section C: Crystal Structure Communications. - 0108-2701 .- 1600-5759. ; C63:5, s. o312-o314
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Tidskriftsartikel (refereegranskat)abstract
- In the crystal structures of the title compounds, C12H12N42+·2BF4-, (I), and C12H11N4+·ClO4-, (II), respectively, infinite two- and one-dimensional architectures are built up via N-H...F [in (I)] and conventional N-H...N [in (II)] hydrogen bonding. The N-N single bond in (I) lies on a crystallographic centre of symmetry; as a result, the two pyridinium rings are parallel. In (II), the pyridinium and pyridyl ring planes are inclined with a dihedral angle of 14.45(3)°.
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| 2. |
- Ghazzali, Mohamed I D M, 1974, et al.
(författare)
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catena-Poly[[chloro(pyridinium-3-carboxylato-κO)zinc(II)]-μ-nicotinato-κ2O:N]
- 2007
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Ingår i: Acta Crystallographica Section E: Structure Reports Online. - 1600-5368. ; E63:1, s. m114-m116
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Tidskriftsartikel (refereegranskat)abstract
- The title bis-nicotinate zinc chloride, [Zn(C6H4NO2)Cl(C6H5NO2)]n, has an infinite head-to-tail one-dimensional chain structure. The compound was synthesized under mild hydrothermal conditions. The ZnII atom exhibits a distorted tetrahedral coordination geometry. The structure is statistically disordered, with 0.5 site occupancy for the Zn atom and the H atom located on the pyridine N atom. As a result, Zn positions in the crystal structure alternate between two sites related by a crystallographic twofold axis and rows of molecules are formed, supported by strong N-H...O hydrogen bonds.
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| 3. |
- Ghazzali, Mohamed I D M, 1974, et al.
(författare)
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Syntheses, crystal structures, optical limiting properties, and DFT calculations of three thiophene-2-aldazine Schiff base derivatives
- 2007
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Ingår i: New Journal of Chemistry. - : Royal Society of Chemistry (RSC). - 1369-9261 .- 1144-0546. ; 31:10, s. 1777-1784
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Tidskriftsartikel (refereegranskat)abstract
- The syntheses, characterizations and structural determinations of N,N'-bis(thiophenyl-2-methylene)hydrazine 1, N,N'-bis(4-bromothiophenyl-2-methylene)hydrazine 2 and N,N'-bis(5-bromothiophenyl-2-methylene)hydrazine 3 are presented. The materials show third-ordernonlinear behaviour with transmissions of 20, 22 and 18 μJ for an input energy of 150 μJ. The4- and 5-bromothiophenic structures show Br...Br interactions of 3.562 and 3.626 Å, respectively.Analysis of bromine containing aromatic compounds in the Cambridge CrystallographicDatabase (CSD) showed the expected angle dependences of the Br...Br interactions dividing theseinto ‘‘type I’’ and ‘‘type II’’. A semi-quantitative agreement was found between the CSD data anda model derived form calculated electrostatic potentials.
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