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Träfflista för sökning "WFRF:(Gustafsson Torbjörn 1949 ) srt2:(2011)"

Sökning: WFRF:(Gustafsson Torbjörn 1949 ) > (2011)

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1.
  • Dahbi, Mohammed, et al. (författare)
  • Effect of manganese on the structural and thermal stability of Li 0.3Ni0.7 - yCo0.3−yMn2yO2 electrode materials (y =0 and 0.05)
  • 2011
  • Ingår i: Solid State Ionics. - : Elsevier. - 0167-2738 .- 1872-7689. ; 203:1, s. 37-41
  • Tidskriftsartikel (refereegranskat)abstract
    • Thermal and structural stabilities of Li(0.3)Ni(0.7)Co(0.3)O(2) and Li(0.3)Ni(0.65)Co(0.25)Mn(0.10)O(2) chemically delithiated cathode materials were studied by X-ray diffraction, thermogravimetric analysis and differential scanning calorimetry. The structure of the Li(0.3)Ni(0.7)Co(0.3)O(2) layered material (S.C. R-3 m) transforms first to the spinel-type structure (S.C. Fd3m) and then to the completely disordered Ni0-type structure (S.C. Fm3m). These structural transitions were accompanied by 10.2% oxygen loss and leads to an exothermic reaction, activated by the electrolyte, more energetic than that of Li(0.3)Ni(0.65)Mn(0.10)O(2) manganese substituted electrode. Furthermore, no structural changes were observed during the thermal treatment of Li(0.3)Ni(0.65)Co(0.25)Mn(0.10)O(2) and relatively lower oxygen loss was recorded. The obtained results prove the positive effect of manganese substitution on the electrochemical features of Li(0.3)Ni(0.7)Co(0.3)O(2).
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2.
  • Maher, Kenza, et al. (författare)
  • The electrochemical behaviour of the carbon-coated Ni0.5TiOPO4 electrode material
  • 2011
  • Ingår i: Journal of Power Sources. - : Elsevier BV. - 0378-7753 .- 1873-2755. ; 196:5, s. 2819-2825
  • Tidskriftsartikel (refereegranskat)abstract
    • Ni0.5TiOPO4 oxyphosphate exhibits good electrochemical properties as an anode material in lithium ion batteries but suffers from its low conductivity. We present here the electrochemical performances of the synthesized Ni0.5TiOPO4/carbon composite by using sucrose as the carbon source. X-ray diffraction study confirms that this phosphate crystallizes in the monoclinic system (S.G. P21/c). The use of the Ni0.5TiOPO4/C composite in lithium batteries shows enhanced electrochemical performances compared with the uncoated material. Capacities up to 200 mAh g−1 could be reached during cycling of this electrode. Furthermore, an acceptable rate capability was obtained with very low capacity fading even at 0.5C rate. Nevertheless, a considerable irreversible capacity was evidenced during the first discharge. In situ synchrotron X-ray radiation was utilized to study the structural change during the first discharge in order to evidence the origin of this irreversible capacity. Lithium insertion during the first discharge induces an amorphization of the crystal structure of the parent material accompanied by an irreversible formation of a new phase.
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  • Resultat 1-2 av 2
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tidskriftsartikel (2)
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refereegranskat (2)
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Edström, Kristina, 1 ... (2)
Saadoune, Ismael (2)
Gustafsson, Torbjörn ... (2)
Dahbi, Mohammed (1)
Mansori, Mohammed (1)
Maher, Kenza (1)
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Uppsala universitet (2)
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Engelska (2)
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Naturvetenskap (2)
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