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Sökning: WFRF:(Hamad Y) > (2015-2019)

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1.
  • Thomas, HS, et al. (författare)
  • 2019
  • swepub:Mat__t
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  • Hamieh, A., et al. (författare)
  • Single site silica supported tetramethyl niobium by the SOMC strategy: synthesis, characterization and structure-activity relationship in the ethylene oligomerization reaction
  • 2017
  • Ingår i: Chemical Communications. - : Royal Society of Chemistry (RSC). - 1359-7345 .- 1364-548X. ; 53:52, s. 7068-7071
  • Tidskriftsartikel (refereegranskat)abstract
    • A silica supported tetramethyl niobium complex [( SiO) NbMe4] 2 has been isolated by the surface alkylation of [( SiO-) NbCl3Me] 1 with dimethyl zinc in pentane. 1 can be easily synthesized by grafting NbCl3Me2 onto the surface of partially dehydroxylated silica by the SOMC strategy. Precise structural analysis was carried out using FTIR, advanced solid state NMR, elemental analysis and mass balance techniques (gas quantification after treating 2 with degassed water). Complex 1 was found to be active in the ethylene oligomerization reaction, producing up to C30, whereas to our surprise complex 2 selectively dimerized ethylene into 1-butene in the absence of a co-catalyst at the same conversion level.
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6.
  • Mahfouz, R., et al. (författare)
  • Properties of K,Rb-intercalated C60 encapsulated inside carbon nanotubes called peapods derived from nuclear magnetic resonance
  • 2015
  • Ingår i: Journal of Applied Physics. - : AIP Publishing. - 0021-8979 .- 1089-7550. ; 118:11
  • Tidskriftsartikel (refereegranskat)abstract
    • We present a detailed experimental study on how magnetic and electronic properties of Rb, K-intercalated C-60 encapsulated inside carbon nanotubes called peapods can be derived from C-13 nuclear magnetic resonance investigations. Ring currents do play a basic role in those systems; in particular, the inner cavities of nanotubes offer an ideal environment to investigate the magnetism at the nanoscale. We report the largest diamagnetic shifts down to -68.3 ppm ever observed in carbon allotropes, which is connected to the enhancement of the aromaticity of the nanotube envelope upon intercalation. The metallization of intercalated peapods is evidenced from the chemical shift anisotropy and spin-lattice relaxation (T-1) measurements. The observed relaxation curves signal a three-component model with two slow and one fast relaxing components. We assigned the fast component to the unpaired electrons charged C-60 that show a phase transition near 100 K. The two slow components can be rationalized by the two types of charged C-60 at two different positions with a linear regime following Korringa behavior, which is typical for metallic system and allow us to estimate the density of sate at Fermi level n(E-F).
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  • Resultat 1-6 av 6

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