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Träfflista för sökning "WFRF:(Hauksson Jón) srt2:(2000-2004)"

Search: WFRF:(Hauksson Jón) > (2000-2004)

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1.
  • Hauksson, Jón B, et al. (author)
  • NMR processing techniques based on multivariate data analysis and orthogonal signal correction. 13C CP/MAS NMR spectroscopic characterization of softwood kraft pulp
  • 2001
  • In: Magnetic Resonance in Chemistry. - : Wiley. - 0749-1581 .- 1097-458X. ; 39:5, s. 267-75
  • Journal article (peer-reviewed)abstract
    • This paper presents a novel way of extracting information from a series of severely overlapped NMR spectra using multivariate data analysis techniques. A number of softwood pulps were prepared from wood chips that were subjected to kraft cooking conditions in laboratory digesters. In addition to measurements of traditional physical parameters, the pulps were characterized using standard 13C CP/MAS NMR spectroscopy. The relationship between the kappa number and both the NMR time domain and frequency domain data was modeled using multivariate data analysis techniques. The variation in the NMR spectra that was not correlated with the kappa number was removed using a new preprocessing tool, orthogonal signal correction (OSC). The resulting OSC-treated NMR spectra were used as descriptors to generate partial least-squares projections to latent structures (PLS) models for the variation of the kappa number. PLS weights were used to generate NMR sub-spectra which correspond to changes in the pulps that occur as the pulping process proceeds from high to low values of the kappa number. The sub-spectra were used to gain insight into the changes in the pulps occurring at the molecular level. Concomitant changes in cellulose crystallinity and the amounts of hemicellulose and lignin were observed in these sub-spectra. Copyright © 2001 John Wiley & Sons, Ltd.
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2.
  • Hauksson, Jón B, et al. (author)
  • Prediction of basic wood properties for Norway spruce. Interpretation of Near Infrared Spectroscopy data using partial least squares regression
  • 2001
  • In: Wood Science and Technology. - : Springer Science and Business Media LLC. - 0043-7719 .- 1432-5225. ; 35:6, s. 475-85
  • Journal article (peer-reviewed)abstract
    • This work was undertaken to investigate the feasibility of using near infrared spectroscopy (NIR) and partial least squares regression (PLS) as a tool to characterize the basic wood properties of Norway Spruce (Picea abies (L.) Karst.). The wood samples originated from a trial located in the province of Västerbotten in Sweden. In this trial, the effects of birch shelterwoods (Betula pendula Roth) of different densities on growth and yield in Norway spruce understorey were examined. All Norway spruce trees in each shelterwood treatment were divided into three growth rate classes based on diameter at breast height (1.3 m) over bark. Five discs were cut from each tree (i.e. from the root stem, and at 20%, 40%, 60%, and 80% of the total height). The discs from 40% tree height were used (i.e., where the largest variations in annual ring widths and wood density were found). A total of 27 discs were selected. The discs were used for measuring annual ring widths, wood density, average fiber length and the fiber length distributions. Milled wood samples prepared from the discs were used for recording NIR spectra. PLS regression was used to generate prediction models for the wood properties (Y-matrix) and NIR spectra (X-matrix) as well as between the wood properties (Y-matrix) and the fiber length distributions (X-matrix). One set of models was generated using untreated spectra and fiber length distributions. For a second set of models the structure in the X-matrix, which was orthogonal to the matrix described by the wood properties, was eliminated using a soft target rotation technique called orthogonal signal correction (OSC). The PLS model obtained using "raw" untreated NIR spectra and fiber length distributions had a poor modeling power as evidenced by the cumulative Q2 values. For the PLS models based on untreated NIR spectra the cumulative Q2 values ranged from a minimum of 16% (wood density) to a maximum of 46% (no. of annual rings). Orthogonal signal correction of the X-matrix (NIR spectra or fiber length distributions) gave PLS models with a modeling power corresponding to cumulative Q2 values well in excess of 70%. The improvement in predictive ability accomplished by the OSC procedure was verified by placing four of the 27 observations in an external test set and comparing RMSEP values for the test set observations without OSC and with OSC.
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  • Result 1-2 of 2
Type of publication
journal article (2)
Type of content
peer-reviewed (2)
Author/Editor
Edlund, Ulf (2)
Hauksson, Jón B (2)
Trygg, Johan (1)
Bergqvist, Göran (1)
Sjöström, Michael (1)
Bergsten, Urban (1)
University
Umeå University (2)
Language
English (2)
Research subject (UKÄ/SCB)
Natural sciences (2)
Year

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