| 1. |
- Carrizo, Daniel, et al.
(författare)
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Compound-specific bromine isotope compositions of one natural and six = dustrially synthesised organobromine substances
- 2011
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Ingår i: Environmental Chemistry. - 1448-2517 .- 1449-8979. ; 8:2, s. 127-132
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Tidskriftsartikel (refereegranskat)abstract
- AB The stable bromine isotopic composition (delta(81)Br) was determined for six industrially synthesised brominated organic compounds (BOCs) and one natural BOC by gas-chromatography multi-collector inductively coupled plasma mass spectrometry (GC-mcICP-MS). The delta(81)Br compositions of brominated benzenes, phenols (both natural and industrial), anisoles, and naphthalenes were constrained with the standard differential measurement approach using as reference a monobromobenzene sample with an independently determined delta(81)Br value (-0.39 parts per thousand v. Standard Mean Ocean Bromide, SMOB). The delta(81)Br values for the industrial BOCs ranged from -4.3 to -0.4 parts per thousand. The average delta(81)Br value for the natural compound (2,4-dibromophenol) was 0.2 +/- 1.6% (1 s.d.), and for the identical industrial compound (2,4-dibromophenol) -1.1 +/- 0.9 parts per thousand (1 s.d.), with a statistically significant difference of similar to 1.4 (P<0.05). The delta(81)Br of four out of six industrial compounds was found to be significantly different from that of the natural sample. These novel results establish the bromine isotopic variability among the industrially produced BOCs in relation to a natural sample.
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| 2. |
- Horst, Axel, et al.
(författare)
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Stable bromine isotopic composition of atmospheric CH3Br
- 2013
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Ingår i: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 65, s. 21040-
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Tidskriftsartikel (refereegranskat)abstract
- Tropospheric methyl bromide (CH3Br) is the largest source of bromine to the stratosphere and plays an important role in ozone depletion. Here, the first stable bromine isotope composition (delta Br-81) of atmospheric CH3Br is presented. The delta Br-81 of higher concentration Stockholm samples and free air subarctic Abisko samples suggest a source/background value of -0.04 +/- 0.28 parts per thousand ranging up to +1.75 +/- 0.12 parts per thousand. The Stockholm delta Br-81 versus concentration relationship corresponds to an apparent isotope enrichment factor of -4.7 +/- 3.7 parts per thousand, representing the combined reaction sink. This study demonstrates the scientific potential of atmospheric delta Br-81 measurements, which in the future may be combined with other isotope systems in a top-down inverse approach to further understand key source and sink processes of methyl bromide.
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| 3. |
- Norström, Elin, et al.
(författare)
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Late Quaternary vegetation dynamics and hydro-climate in the Drakensberg, South Africa
- 2014
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Ingår i: Quaternary Science Reviews. - : Elsevier BV. - 0277-3791 .- 1873-457X. ; 105, s. 48-65
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Tidskriftsartikel (refereegranskat)abstract
- Abstract A multi-proxy study of a sediment sequence from Braamhoek wetland, covering the last c. 16,000 years, reveals a record of regional climate and vegetation dynamics in the Drakensberg region, South Africa, including signals from both the organic sediment fraction (fossil pollen, charcoal, n-alkane abundance, n-alkane δ13C, TOC) and the inorganic fraction (mineral magnetic properties). The reconstruction, supported by a robust chronology, indicates two major periods of increased regional wetness during the late Pleistocene to early Holocene phase (c. 13,800–12,600 cal yr BP; c. 10,200–8500 cal yr BP) and one during the late Holocene (c. 2000 cal yr BP to present). Drier conditions are recorded during the Younger Dryas (c. 12,600–11,300 cal yr BP) and mid-Holocene (c. 7000–2000 cal yr BP). A major decline in fynbos vegetation during the early Holocene suggests a shift towards warmer temperatures and possibly towards less pronounced winter rains in eastern South Africa from c. 8500 cal yr BP. Comparison with records from interior of South Africa show relatively high inter-site variability, however, the Braamhoek moisture proxies do co-vary with the speleothem isotope records from Makapansgat, suggesting a similar hydro-climate evolution in eastern and interior parts of the summer rainfall region during the studied period. On multi-millennial time scales, an inverse hydro-climatological pattern is evident between these two South African records and reconstructions from tropical locations in southeast Africa. Such a rainfall dipole between eastern tropical and southern Africa, has previously been identified on shorter time scales, i.e. on inter-annual to millennial scales. The Braamhoek study suggests that a similar dipole pattern is acting also on a multi-millennial perspective. These long-term precipitation anomalies are tentatively coupled to teleconnections from multi-millennial changes in the dynamics of the Indian Ocean Dipole (IOD) and El Niño-Southern Oscillation (ENSO).
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| 4. |
- Thornton, Brett F., et al.
(författare)
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A High-Volume Cryosampler and Sample Purification System for Bromine Isotope Studies of Methyl Bromide
- 2013
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Ingår i: Journal of Atmospheric and Oceanic Technology. - 0739-0572 .- 1520-0426. ; 30:9, s. 2095-2107
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Tidskriftsartikel (refereegranskat)abstract
- A system was developed for collecting from the ambient atmosphere the methyl halides CH3Cl and CH3Br in quantities sufficient for chlorine and bromine isotope analysis. The construction and operation of the novel cryogenic collection system (cryosampler) and sample purification system developed for this task are described. This study demonstrates the capability of the cryosampler by quantifying the CH3Cl and CH3Br collected from atmospheric samples and the nonfractionating bromine isotope fingerprint of CH3Br from synthetic air samples of controlled composition. An optimized cryosampler operation time of 4 h at a flow rate of 15 L min(-1) is applied to yield the nearly 40 ng required for subsequent Br-81-CH3Br analyses. The sample purification system is designed around a packed column gas chromatography-quadropole-mass spectrometry (GCqMS) system with three additional cryotraps and backflushing capacity. The system's suitability was tested by observing both the mass recovery and the lack of Br-81 isotope fractionation induced during sample purification under varying flow rates and loading scenarios. To demonstrate that the entire system samples and dependably delivers CH3Br to the isotope analysis system without inducing isotope fractionation, diluted synthetic air mixtures prepared from standard gases were processed through the entire system, yielding a Br-81-CH3Br of +0.03 parts per thousand +/- 0.10 parts per thousand relative to their starting composition. Finally, the combined cryosampler-purification and analysis system was applied to demonstrate the first-ever Br-81-CH3Br in the ambient atmosphere with two samples collected in the autumn of 2011, yielding -0.08 parts per thousand +/- 0.43 parts per thousand and +1.75 parts per thousand +/- 0.13 parts per thousand versus standard mean ocean bromide for samples collected at a suburban Stockholm, Sweden, site.
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