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| 2. |
- Albinsson, I., et al.
(författare)
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Ion association effects and ionic conduction in polyalkalene modified polydimethylsiloxanes
- 1992
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Ingår i: Solid State Ionics. - : Elsevier. - 0167-2738 .- 1872-7689. ; 53-56:Part 2, s. 1044-1053
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Tidskriftsartikel (refereegranskat)abstract
- Poly (ethylene oxide) and poly (propylene oxide) modified poly (dimethyl siloxane) (PDMS) have been complexed with LiCF3SO3, NaCF3SO3 and KCF3SO3. In order to study ion association in these systems, the nondegenerate symmetric stretch (A1, SO3) Raman modes have been studied as a function of temperature at several different salt concentrations. Ionic conductivity has also been measured. For the poly (ethylene oxide) modified PDMS (PEO-PDMS), ether oxygen to metal ratios ranged from 12500:1 to 9:1. Changing the cation from Li+ to Na+ to K+ increases the conductivity of the complex. Plots of the molar conductivity versus salt concentration show that the characteristic shape and the region of increase in the molar conductivity is influenced most by the fraction of “free” ions which increases with increasing salt concentration. Charged triplets and contact ion-pairs are also present at the higher salt concentrations; the number of triplets increases with concentration and temperature. Non-VTF behaviour is observed. For the poly (propylene oxide) modified PDMS (PPO-PDMS) (with excess PPO), phase separation is observed when these triflate salts are complexed in. These solutions above and below the boundary layer have been studied by Raman spectroscopy revealing that the upper region is siloxane rich. The formation of the boundary layer is attributed to an increasing difference in surface tension between the PPO/salt/PPO-PDMS complexes and the separate PPO, PPO-PDMS components. The boundary layer moves up with increase in salt concentration. There is evidence of “free” ions, contact-ion pairs, triplets and aggregates. Values of conductivity of 2.2×10−6 and 1.6×10−5 S/cm are quoted for 293 K and 8 mol% LiCF3SO3 in respectively PPO-PDMS/PPO and PEO-PDMS/PEO. Both are better conductors than the corresponding 8 mol% PPG4000/LiCF3SO3 complex.
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| 4. |
- Jacobsson, Per, et al.
(författare)
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Ion association effects and phase separation in poly(propylene oxide) modified poly(dimethylsiloxane) complexed with triflate salts
- 1992
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Ingår i: Polymer. - : Elsevier. - 0032-3861 .- 1873-2291. ; 33:13, s. 2778-2783
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Tidskriftsartikel (refereegranskat)abstract
- Phase separation is observed in poly(propylene oxide) modified poly(dimethylsiloxane) (PPO-PDMS) with excess poly(propylene oxide) (PPO) when salts of MCF3SO3 (M = Li, Na) are added. The same behaviour is inferred for KCF3SO3. The solutions above and below the boundary layer have been studied by Raman spectroscopy and in particular by examining the non-degenerate, symmetric stretch (A1, SO3) Raman mode of the CF3SO3− anion. The upper part is siloxane rich; salt is present on both sides of the boundary layer with a much lower concentration in the upper part. The formation of the boundary layer is attributed to an increasing difference in surface tension between the PPO/salt/PPO-PDMS complexes and the separate PPO, PPO-PDMS components. The boundary layer moves up with increase in concentration. The number of ‘free’ ions decreases and ion association increases with increase in temperature. There is evidence of contact ion pairs, triplets and aggregates. Values of conductivity are quoted for 293 K.
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| 5. |
- Stevens, James R., et al.
(författare)
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A comparison of acetone and poly(propylene glycol) as solvents for lithium triflate and lithium perchlorate
- 1991
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Ingår i: Canadian journal of chemistry (Print). - : Canadian Science Publishing. - 0008-4042 .- 1480-3291. ; 69:12, s. 1980-1984
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Tidskriftsartikel (refereegranskat)abstract
- Solutions of LiCF3SO3 and LiClO4 in acetone and in poly(propylene glycol) (PPG 400 and PPG 4000) have been compared by studying the nondegenerate, symmetric stretch (A1,SO3) and (A1,ClO4) Raman modes. The Raman spectra contain bands due to the symmetric stretching motion of the "free" anion and due to the symmetric stretching motion of anions in ion aggregates. It is concluded that "free" ions, ion pairs, triplets, and aggregates are present. Although PPG has a much lower dielectric constant, it is a better solvent for these salts than the dipolar aprotic acetone. These findings have ramifications on the current controversy of whether "free" ions are present at all in polyether–salt complexes such as PPG 4000/LiCF3SO3.
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