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- Aad, G., et al.
(författare)
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- 2010
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swepub:Mat__t
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- Aad, G., et al.
(författare)
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- 2010
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swepub:Mat__t
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- Kuznetsova, T. V., et al.
(författare)
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A photoelectron spectroscopy study of the electronic structure evolution in CuInSe2-related compounds at changing copper content
- 2012
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Ingår i: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 101:11, s. 111607-
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Tidskriftsartikel (refereegranskat)abstract
- Evolution of the valence-band structure at gradually increasing copper content has been analysed by x-ray photoelectron spectroscopy (XPS) in In2Se3, CuIn5Se8, CuIn3Se5, and CuInSe2 single crystals. A comparison of these spectra with calculated total and angular-momentum resolved density-of-states (DOS) revealed the main trends of this evolution. The formation of the theoretically predicted gap between the bonding and non-bonding states has been observed in both experimental XPS spectra and theoretical DOS.
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- Chinga-Carrasco, Gary, et al.
(författare)
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Bleached and unbleached MFC nanobarriers: : Properties and hydrophobisation with hexamethyldisilazane
- 2012
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Ingår i: Journal of nanoparticle research. - : Springer Science and Business Media LLC. - 1388-0764 .- 1572-896X. ; 14:12
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Tidskriftsartikel (refereegranskat)abstract
- This study explores the production and surface modification of microfibrillated cellulose (MFC), based on unbleached and bleached Pinus radiata pulp fibres. Unbleached Pinus radiata pulp fibres tend to fibrillate easier by homogenisation without pre-treatment, compared to the corresponding bleached MFC. The resulting unbleached MFC films have higher barrier against oxygen, lower water wettability and higher tensile strength than the corresponding bleached MFC qualities. In addition, it is demonstrated that carboxymethylation can also be applied for production of highly fibrillated unbleached MFC. The nanofibril size distribution of the carboxymethylated MFC is narrow with diameters less than 20 nm, as quantified on high-resolution field-emission scanning electron microscopy images. The carboxymetylation had a larger fibrillation effect on the bleached pulp fibres than on the unbleached one. Importantly, the suitability of hexamethyldisilazane (HMDS) as a new alternative for rendering MFC films hydrophobic was demonstrated. TheHMDS-modifiedfilmsmade of carboxymethylated MFC had oxygen permeability levels better than 0.06 mL mm m-2 day-1 atm-1,which is a good property for some packaging applications.
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