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- Hussmann, G.A., et al.
(författare)
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Characterization of solution structure near the surface of a growing crystal by Raman spectroscopy
- 1984
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Ingår i: Industrial crystallization 84. - Amsterdam : Elsevier. - 0444424067 ; , s. 21-26
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Konferensbidrag (refereegranskat)abstract
- In situ structure analyses of the supersaturated aqueous NaNO//3 solution near a growing NaNO//3 crystal have been performed using micro Raman spectroscopy. It was observed that the relative concentrations of higher ordered species (contact-ion pairs, and ion aggregates) are diminished near the growing crystal, indicating that these species are dominant in the diffusion process when compared to free aquated ions or solvent-separated ions. There were no detectable differences between the spectra obtained for saturated and supersaturated solutions.
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