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| 2. |
- Palmgren, Pål, et al.
(författare)
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Ordered phthalocyanine superstructures on Ag(110)
- 2008
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Ingår i: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 128:6, s. 064702-
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Tidskriftsartikel (refereegranskat)abstract
- Organic-metal interfaces, in particular, self-assembling systems, are interesting in the field of molecular electronics. In this study, we have investigated the formation of the Ag(110)-iron phthalocyanine (FePc) interface in a coverage range of less than 1 and up to 2 ML using synchrotron based photoelectron spectroscopy and low energy electron diffraction. As-deposited FePc forms a densely packed first layer exhibiting a 3x2/c(6x2) symmetry. Upon thermal treatment the order at the interface is modified depending on the initial FePc coverage, resulting in less densely packed but still ordered superstructures. The first monolayer is relatively strongly bound to the substrate, leading to the formation of an interface state just below the Fermi level. The highest occupied molecular orbital of FePc in the second layer is found at 1 eV higher binding energy compared to the interface state.
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| 3. |
- Palmgren, Pål, et al.
(författare)
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Strong interactions in dye-sensitized interfaces
- 2008
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Ingår i: The Journal of Physical Chemistry C. - : American Chemical Society (ACS). - 1932-7447 .- 1932-7455. ; 112:15, s. 5972-5977
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Tidskriftsartikel (refereegranskat)abstract
- Phthalocyanines (Pcs) are capable of converting sunlight into electric energy when adsorbed on TiO2 in a dye-sensitized solar cell. Of special interest in this type of cell is the energy level alignment as well as how molecules adsorb on the surface as it determines the output of the cell. We investigated the FePc-TiO2(110) interface using scanning tunneling microscopy, synchrotron-based photoelectron spectroscopy, and X-ray absorption spectroscopy. We found a strong coupling of the first-layer FePc to the substrate resulting in an alteration of the electronic structure and charge transfer from the molecules. The FePc in the second layer is not severely affected by the bonding to the surface and has bulk-like electronic properties. The growth of FePc thin films proceeds in a layer plus island mode, and the molecular plane is parallel to the surface. The energy level alignment at the interface is determined, and the lowest unoccupied molecular orbital is found above the conduction band minimum of the oxide substrate.
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| 4. |
- Salomon, E., et al.
(författare)
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Etching of silicon nanowires on Ag(110) by atomic hydrogen
- 2009
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Ingår i: Surface Science. - : Elsevier BV. - 0039-6028 .- 1879-2758. ; 603:23, s. 3350-3354
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Tidskriftsartikel (refereegranskat)abstract
- Scanning Tunnelling Microscopy, High Resolution Electron Energy Loss Spectroscopy and High Resolution X-Ray Photoelectron Spectroscopy have been used to study the adsorption of atomic hydrogen onto Si nanowires grown on Ag(1 1 0). We demonstrate that the hydrogen strongly interacts with the Si nanowires modifying their structural and electronic properties. Hydrogen atoms etch the Si nanowires and eventually lead to their complete removal from the Ag(1 1 0) surface.
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