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The impact of the s...
The impact of the structure of graphene-based materials on the removal of organophosphorus pesticides from water
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- Lazarevic-Pasti, Tamara (författare)
- Univ Belgrade, Vinca Inst Nucl Sci, Dept Phys Chem, Mike Petrovica Alasa 12-14,POB 522, Belgrade 11001, Serbia.
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- Anicijevic, Vladan (författare)
- Univ Belgrade, Fac Phys Chem, Studentski Trg 12-16, Belgrade 11158, Serbia.
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- Baljozovic, Milos (författare)
- Paul Scherrer Inst, Lab Micro & Nanotechnol, Villigen, Switzerland.
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- Anicijevic, Dragana Vasic (författare)
- Univ Belgrade, Vinca Inst Nucl Sci, Dept Phys Chem, Mike Petrovica Alasa 12-14,POB 522, Belgrade 11001, Serbia.
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- Gutic, Sanjin (författare)
- Univ Sarajevo, Dept Chem, Fac Sci, Zmaja Bosne 33-35, Sarajevo, Bosnia & Herceg.
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- Skorodumova, Natalia V. (författare)
- KTH,Uppsala universitet,Materialteori,Uppsala Univ, Dept Phys & Astron, Box 516, S-75120 Uppsala, Sweden.;KTH Royal Inst Technol, Sch Ind Engn & Management, Dept Mat Sci & Engn, Brinellvagen 23, S-10044 Stockholm, Sweden.,Univ Belgrade, Vinca Inst Nucl Sci, Dept Phys Chem, Mike Petrovica Alasa 12-14,POB 522, Belgrade 11001, Serbia.
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- Skorodumova, Natalia V. (författare)
- KTH,Uppsala Univ, Dept Phys & Astron, Box 516, S-75120 Uppsala, Sweden.;KTH Royal Inst Technol, Sch Ind Engn & Management, Dept Mat Sci & Engn, Brinellvagen 23, S-10044 Stockholm, Sweden.
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- Pašti, Igor (författare)
- KTH,Materialvetenskap,Univ Belgrade, Fac Phys Chem, Studentski Trg 12-16, Belgrade 11158, Serbia;KTH Royal Inst Technol, Sch Ind Engn & Management, Dept Mat Sci & Engn, Brinellvagen 23, S-10044 Stockholm, Sweden
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Univ Belgrade, Vinca Inst Nucl Sci, Dept Phys Chem, Mike Petrovica Alasa 12-14,POB 522, Belgrade 11001, Serbia Univ Belgrade, Fac Phys Chem, Studentski Trg 12-16, Belgrade 11158, Serbia. (creator_code:org_t)
- 2018
- 2018
- Engelska.
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Ingår i: ENVIRONMENTAL SCIENCE-NANO. - : ROYAL SOC CHEMISTRY. - 2051-8153 .- 2051-8161. ; 5:6, s. 1482-1494
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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https://urn.kb.se/re...
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Abstract
Ämnesord
Stäng
- The wide use of pesticides in modern agriculture and other areas results in an urgent need for their efficient removal from the environment. Adsorption of pesticides is one of the most commonly used strategies for this task. Here we analyze the adsorption of two organophosphorus pesticides, dimethoate (DMT) and chlorpyrifos (CPF), on graphene-based materials. The adsorption was found to be very sensitive to the structure of the adsorbents used. In particular, aliphatic DMT was found to prefer hydrophilic oxidized graphene surfaces. The CPF molecule, which contains an aromatic moiety, prefers adsorption on the surface of a graphene basal plane with high structural order and preserved electron system. The toxicity of pesticide solutions is reduced after adsorption, suggesting that there is no oxidation of DMT and CPF to more toxic oxo forms. We emphasize that the combination of structural properties of adsorbents and adsorbates defines the adsorption of organophosphorus pesticides on graphene-based materials, while the specific surface area of adsorbents is not the major factor.
Ämnesord
- NATURVETENSKAP -- Kemi -- Annan kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Other Chemistry Topics (hsv//eng)
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
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