| 1. |
- Acevedo Gomez, Yasna
(författare)
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On Gas Contaminants, and Bipolar Plates in Proton Exchange Membrane Fuel Cells
- 2019
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- The proton exchange membrane (PEM) fuel cell is an electrochemical device that converts chemical energy into electrical energy through two electrocatalytic reactions. The most common catalyst used is platinum on carbon (Pt/C), which has shown the best performance in the fuel cell until now. However, the drawback of this catalyst is that it does not tolerate impurities, and both hydrogen and oxygen may carry small amounts of impurities depending on the production sources. The purpose of this thesis is to understand the effect of two impurities that are less investigated, i.e., ammonia, which may accompany the hydrogen rich reformates from renewable sources, and nitrogen dioxide, which may come from air pollution. The mechanism of contamination and an adequate recovery method for the respective contaminant are studied. Additionally, electroplated bipolar plates with Ni-Mo and Ni-Mo-P coatings were tested as alternatives to stainless steel and carbon materials.The results show that ammonia not only provokes changes in the polymer membrane but also in the oxygen reduction reaction (ORR), hydrogen oxidation reaction (HOR) and catalyst ionomer in both electrodes. The extent of performance recovery after the contamination depends on the concentration used and the exposure time. In contrast, nitrogen dioxide affects the catalyst in the electrode directly; the contamination is related to side reactions that are produced on the catalyst’s surface. However, NO2 is not attached strongly to the catalyst and it is possible to restore the performance by using clean air. The time the recovery process takes depends on the potential applied and the air flow.Finally, the evaluation of electroplated Ni-Mo and Ni-Mo-P on stainless steel by ex situ and in situ studies shows that these coatings reduce the internal contact resistance (ICR) and the corrosion rate of the stainless steel considerably. However, the in situ experiments show that phosphorus addition to the coating does not improve the fuel cell performance; thus, the Ni-Mo alloy is found to be a promising choice for electroplating stainless steel bipolar plates.
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| 2. |
- Ajpi, Cesario, et al.
(författare)
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Crystal structure and Hirshfeld surface analysis of poly[tris(mu(4)-benzene-1,4-dicarboxylato)tetrakis(di-methylformamide)tr inickel(II)] : a two-dimensional coordination network
- 2019
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Ingår i: Acta Crystallographica Section E: Crystallographic Communications. - : International Union of Crystallography. - 2056-9890. ; 75, s. 1839-1843
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Tidskriftsartikel (refereegranskat)abstract
- The crystal structure of the title compound, [Ni-3(C8H4O4)(3)(C3H7NO)(4)], is a two-dimensional coordination network formed by trinuclear linear Ni-3(tp)(3)(DMF)(4) units (tp = terephthalate = benzene-1,4-dicarboxylate and DMF = dimethyl-formamide) displaying a characteristic coordination mode of acetate groups in polynuclear metal-organic compounds. Individual trinuclear units are connected through tp anions in a triangular network that forms layers. One of the DMF ligands points outwards and provides interactions with equivalent planes above and below, leaving the second ligand in a structural void much larger than the DMF molecule, which shows positional disorder. Parallel planes are connected mainly through weak C-H center dot center dot center dot O, H center dot center dot center dot H and H center dot center dot center dot C interactions between DMF molecules, as shown by Hirshfeld surface analysis.
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| 3. |
- Ajpi, Cesario, et al.
(författare)
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Crystal structure and Hirshfeld surface analysis of poly[tris-(μ4-benzene-1,4-di-carboxyl-ato)tetra-kis-(di-methyl-formamide)-trinickel(II)] : a two-dimensional coordination network.
- 2019
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Ingår i: Acta crystallographica. Section E, Crystallographic communications. - 2056-9890. ; 75:Pt 12, s. 1839-1843
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Tidskriftsartikel (refereegranskat)abstract
- The crystal structure of the title compound, [Ni3(C8H4O4)3(C3H7NO)4], is a two-dimensional coordination network formed by trinuclear linear Ni3(tp)3(DMF)4 units (tp = terephthalate = benzene-1,4-di-carboxyl-ate and DMF = di-methyl-formamide) displaying a characteristic coordination mode of acetate groups in polynuclear metal-organic compounds. Individual trinuclear units are connected through tp anions in a triangular network that forms layers. One of the DMF ligands points outwards and provides inter-actions with equivalent planes above and below, leaving the second ligand in a structural void much larger than the DMF mol-ecule, which shows positional disorder. Parallel planes are connected mainly through weak C-H⋯O, H⋯H and H⋯C inter-actions between DMF mol-ecules, as shown by Hirshfeld surface analysis.
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| 4. |
- Asp, Leif E, et al.
(författare)
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Carbon Fibre Composite Structural Batteries: A Review
- 2019
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Ingår i: Functional Composites and Structures. - : Institute of Physics (IOP). - 2631-6331.
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Tidskriftsartikel (refereegranskat)abstract
- This paper presents a comprehensive review of the state-of-the-art in structural battery composites research. Structural battery composites are a class of structural power composites aimed to provide mass-less energy storage for electrically powered structural systems. Structural battery composites are made from carbon fibres in a structural electrolyte matrix material. Neat carbon fibres are used as a structural negative electrode, exploiting their high mechanical properties, excellent lithium insertion capacity and high electrical conductivity. Lithium iron phosphate coated carbon fibres are used as the structural positive electrode. Here, the lithium iron phosphate is the electrochemically active substance and the fibres carry mechanical loads and conduct electrons. The surrounding structural electrolyte is lithium ion conductive and transfers mechanical loads between fibres. With these constituents, structural battery half-cells and full-cells are realised with a variety in device architecture. The paper also presents an overview of material modelling and characterisation performed to date. Particular reference is given to work performed in national and European research projects under the leadership of the authors, who are able to provide a unique insight into this emerging and exciting field of research.
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| 5. |
- Asp, Leif, 1966, et al.
(författare)
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Realisation of structural battery composite materials
- 2015
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Ingår i: ICCM International Conferences on Composite Materials. - : International Committee on Composite Materials.
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Konferensbidrag (refereegranskat)abstract
- This paper introduces the concept of structural battery composite materials and their possible devices and the rationale for developing them. The paper presents an overview of the research performed in Sweden on a novel structural battery composite material. The research areas addressed include: carbon fibre electrodes, structural separators, multifunctional matrix materials, device architectures and material functionalization. Material characterization, fabrication and validation are also discussed. The paper focuses on a patented battery composite material technology. Here, carbon fibres are employed as combined negative battery electrodes and reinforcement, coated with a solid polymer electrolyte working simultaneously as electrolyte and separator with ability to transfer mechanical loads. The coated fibres are distributed in a conductive positive cathode material on an aluminium electron collector film. Efficient Li-ion transport between the electrodes is achieved by the solid polymer electrolyte coating being only a few hundred nanometres thick. Finally some outstanding scientific and engineering challenges are discussed. Such challenges, calling for further research are related to manufacture, development of new solid polymer electrolytes for improved multifunctionality and the lack of material models.
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| 6. |
- Asp, Leif, 1966, et al.
(författare)
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Structural Battery Composites: A Review, Functional Composites and Structures
- 2019
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Ingår i: Functional Composites and Structures. - : IOP Publishing. - 2631-6331. ; 1
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Forskningsöversikt (refereegranskat)abstract
- This paper presents a comprehensive review of the state-of-the-art in structural battery composites research. Structural battery composites are a class of structural power composites aimed to provide mass-less energy storage for electrically powered structural systems. Structural battery composites are made from carbon fibres in a structural electrolyte matrix material. Neat carbon fibres are used as a structural negative electrode, exploiting their high mechanical properties, excellent lithium insertion capacity and high electrical conductivity. Lithium iron phosphate coated carbon fibres are used as the structural positive electrode. Here, the lithium iron phosphate is the electrochemically active substance and the fibres carry mechanical loads and conduct electrons. The surrounding structural electrolyte is lithium ion conductive and transfers mechanical loads between fibres. With these constituents, structural battery half-cells and full-cells are realised with a variety in device architecture. The paper also presents an overview of material modelling and characterisation performed to date. Particular reference is given to work performed in national and European research projects under the leadership of the authors, who are able to provide a unique insight into this emerging and exciting field of research.
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| 7. |
- Benavente Araoz, Fabian Andres, et al.
(författare)
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Photovoltaic/battery system sizing for rural electrification in Bolivia : Considering the suppressed demand effect
- 2019
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Ingår i: Applied Energy. - : Elsevier BV. - 0306-2619 .- 1872-9118. ; 235, s. 519-528
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Tidskriftsartikel (refereegranskat)abstract
- Rural electrification programs usually do not consider the impact that the increment of demand has on the reliability of off-grid photovoltaic (PV)/battery systems. Based on meteorological data and electricity consumption profiles from the highlands of Bolivian Altiplano, this paper presents a modelling and simulation framework for analysing the performance and reliability of such systems. Reliability, as loss of power supply probability (LPSP), and cost were calculated using simulated PV power output and battery state of charge profiles. The effect of increasing the suppressed demand (SD) by 20% and 50% was studied to determine how reliable and resilient the system designs are. Simulations were performed for three rural application scenarios: a household, a school, and a health centre. Results for the household and school scenarios indicate that, to overcome the SD effect, it is more cost-effective to increase the PV power rather than to increase the battery capacity. However, with an increased PV-size, the battery ageing rate would be higher since the cycles are performed at high state of charge (SOC). For the health centre application, on the other hand, an increase in battery capacity prevents the risk of electricity blackouts while increasing the energy reliability of the system. These results provide important insights for the application design of off-grid PV-battery systems in rural electrification projects, enabling a more efficient and reliable source of electricity.
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| 8. |
- Benavente-Araoz, Fabian, et al.
(författare)
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Loss-of-load probability analysis for optimization of small off-grid PV-battery systems in Bolivia
- 2017
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Ingår i: Proceedings of the 9th International Conference on Applied Energy. - : Elsevier. ; 142, s. 3715-3720
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Konferensbidrag (refereegranskat)abstract
- This study evaluates the use of energy storage technologies coupled to renewable energy sources in rural electrification as a way to address the energy access challenge. Characteristic energy demanding applications will differently affect the operating conditions for off-grid renewable energy systems. This paper discusses and evaluates simulated photovoltaic power output and battery state of charge profiles, using estimated climate data and electricity load profiles for the Altiplanic highland location of Patacamaya in Bolivia to determine the loss of load probability as optimization parameter. Simulations are performed for three rural applications: household, school, and health center. Increase in battery size prevents risk of electricity blackouts while increasing the energy reliability of the system. Moreover, increase of PV module size leads to energy excess conditions for the system reducing its efficiency. The results obtained here are important for the application of off-grid PV-battery systems design in rural electrification projects, as an efficient and reliable source of electricity.
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| 9. |
- Bessman, Alexander, et al.
(författare)
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Aging effects of AC harmonics on lithium-ion cells
- 2019
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Ingår i: Journal of Energy Storage. - : Elsevier. - 2352-152X .- 2352-1538. ; 21, s. 741-749
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Tidskriftsartikel (refereegranskat)abstract
- With the vehicle industry poised to take the step into the era of electric vehicles, concerns have been raised that AC harmonics arising from switching of power electronics and harmonics in electric machinery may damage the battery. In light of this, we have studied the effect of several different frequencies on the aging of 28 Ah commercial NMC/graphite prismatic lithium-ion battery cells. The tested frequencies are 1 Hz, 100 Hz, and 1 kHz, all with a peak amplitude of 21 A. Both the effect on cycled cells and calendar aged cells is tested. The cycled cells are cycled at a rate of 1C:1C, i.e., 28 A during both charging and discharging, with the exception of a period of constant voltage at the end of every charge. After running for one year, the cycled cells have completed approximately 2000 cycles. The cells are characterized periodically to follow how their capacities and power capabilities evolve. After completion of the test about 80% of the initial capacity remained and no increase in resistance was observed. No negative effect on either capacity fade or power fade is observed in this study, and no difference in aging mechanism is detected when using non-invasive electrochemical methods of post mortem investigation.
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| 10. |
- Bessman, Alexander, 1989-, et al.
(författare)
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Challenging Sinusoidal Ripple-Current Charging of Lithium-Ion Batteries
- 2018
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Ingår i: IEEE Transactions on Industrial Electronics. - : IEEE Press. - 0278-0046 .- 1557-9948. ; 65:6, s. 4750-4757
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Tidskriftsartikel (refereegranskat)abstract
- Sinusoidal ripple-current charging has previously been reported to increase both charging efficiency and energy efficiency and decrease charging time when used to charge lithium-ion battery cells. In this paper, we show that no such effect exists in lithium-ion battery cells, based on an experimental study of large-size prismatic cells. Additionally, we use a physics-based model to show that no such effect should exist, based on the underlying electrochemical principles.
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