| 1. |
- Bertolino, Mattias, et al.
(författare)
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Thomas-Reiche-Kuhn correction for truncated configuration-interaction spaces : Case of laser-assisted dynamical interference
- 2022
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Ingår i: Physical Review A: covering atomic, molecular, and optical physics and quantum information. - 2469-9926 .- 2469-9934. ; 106:4
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Tidskriftsartikel (refereegranskat)abstract
- The Thomas-Reiche-Kuhn sum rule is used to form an effective potential that is added to the time-dependent configuration-interaction singles (TDCIS) equations of motion in velocity gauge. The purpose of the effective potential is to include virtual coupling from singles to doubles, which is required for size-consistent velocity-gauge TDCIS results. The proposed method is compared to length-gauge TDCIS results for laser-assisted photoionization. Finally, a dynamical interference effect controlled by two-color fields is predicted for atomic targets.
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| 2. |
- Lindroth, Katrin, et al.
(författare)
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Differential Defecation of Solid and Liquid Phases in Horses-A Descriptive Survey
- 2020
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Ingår i: Animals. - : MDPI AG. - 2076-2615. ; 10
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Tidskriftsartikel (refereegranskat)abstract
- Simple Summary Free faecal liquid is a condition in horses where faeces are voided in one solid and one liquid phase. The presence of free faecal liquid may cause management problems in equine husbandry and is potentially contributing to impaired equine welfare. Causes of free faecal liquid are not known, but nutritional factors such as the feeding of specific forages have been suggested to be of importance. Characterization of horses showing free faecal liquid and their feeding and management was, therefore, performed via an internet-based survey in order to map the condition further. Results showed that horses with free faecal liquid included a large variety of different breeds, ages, disciplines, coat colours, housing systems and feeding strategies, meaning that almost any type of horse could be affected. Horses that were reported to show free faecal liquid did so with all types of feeding strategies, but changes from wrapped forage to hay, to pasture, or to another batch of wrapped forage often resulted in diminished signs of free faecal liquid. Horses were also reported to have a comparably high incidence of colic in relation to published data for other horse populations. The results indicated that more detailed studies are required for a further understanding of the underlying cause of free faecal liquid.Abstract Free faecal liquid (FFL) is a condition in horses where faeces are voided in one solid and one liquid phase. The liquid phase contaminates the tail, hindlegs and area around the anus of the horse, resulting in management problems and potentially contributing to impaired equine welfare. The underlying causes are not known, but anecdotal suggestions include feeding wrapped forages or other feed- or management-related factors. Individual horse factors may also be associated with the presence of FFL. This study, therefore, aimed to characterize horses showing FFL particularly when fed wrapped forages, and to map the management and feeding strategies of these horses. Data were retrieved by a web-based survey, including 339 horses with FFL. A large variety of different breeds, ages, disciplines, coat colours, housing systems and feeding strategies were represented among the horses in the study, meaning that any type of horse could be affected. Respondents were asked to indicate if their horse had diminished signs of FFL with different changes in forage feeding. Fifty-eight percent (n = 197) of the horse owners reported diminished signs of FFL in their horses when changing from wrapped forages to hay; 46 (n = 156) of the horse owners reported diminished signs of FFL in their horses when changing from wrapped forages to pasture; 17% (n = 58) reported diminished signs of FFL when changing from any type of forage batch to any other forage. This indicated that feeding strategy may be of importance, but cannot solely explain the presence of FFL. The results also showed that the horses in this study had a comparably high incidence of previous colic (23%, n = 78) compared to published data from other horse populations. In conclusion, the results showed that FFL may affect a large variety of horse types and that further studies should include detailed data on individual horse factors including gastrointestinal diseases as well as feeding strategies, in order to increase the chance of finding causes of FFL.
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| 3. |
- Lindroth, Katrin, et al.
(författare)
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Feeding and Management of Horses with and without Free Faecal Liquid: A Case-Control Study
- 2021
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Ingår i: Animals. - : MDPI AG. - 2076-2615. ; 11
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Tidskriftsartikel (refereegranskat)abstract
- Simple Summary Horses with free faecal liquid defecate in one solid and one liquid phase, and the liquid phase can be a concern for the horse owner and veterinarians. The causes of free faecal liquid are unknown, but previous studies have indicated that feed ration composition may play an important role in the occurrence of the condition. A study comparing feed rations, feeding practices and management factors for horses with and without free faecal liquid was performed. Horses without free faecal liquid were reported to have a lower daily intake of starch and sugar and a higher daily intake of protein and fibre compared to horses with free faecal liquid. Horses with and without free faecal liquid were fed similar amounts of wrapped forages and were subject to the same management practices. The reported differences may be of importance for the condition, but further studies are required to establish if its occurrence is due to specific feeding regimens. Free faecal liquid (FFL) in horses is characterised by the excretion of faeces in two phases (one solid and one liquid), which may cause dermatitis on the hindlegs. The causes of FFL are not known. Results from previous studies have indicated that feed ration composition and management factors may play important roles in the occurrence of FFL. A case-control study was therefore performed in which data on feed rations, feeding practices and management factors were compared between horses with (case) and without (control) FFL on 50 private farms in Sweden and Norway. The comparisons show that case and control horses were reported to be fed similar average amounts of wrapped forage (p = 0.97) and to be subject to similar management practices, but case horses were fed higher proportions of concentrates in their diet (p < 0.001) and lower average amounts of straw and lucerne (p < 0.05) compared to control horses. Case horses were reported to be fed twice as much concentrate per 100 kg BW and day as control horses and a higher daily intake of starch and water-soluble carbohydrates (p < 0.05). Case horses also had a lower daily intake of digestible crude protein and neutral detergent fibre compared to control horses (p < 0.05). These differences were small but are of interest for further studies of factors causing FFL.
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| 4. |
- Peschel, Jasper, et al.
(författare)
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Attosecond dynamics of multi-channel single photon ionization
- 2022
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Ingår i: Nature Communications. - : Springer Science and Business Media LLC. - 2041-1723. ; 13:1
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Tidskriftsartikel (refereegranskat)abstract
- Photoionization of atoms and molecules is one of the fastest processes in nature. The understanding of the ultrafast temporal dynamics of this process often requires the characterization of the different angular momentum channels over a broad energy range. Using a two-photon interferometry technique based on extreme ultraviolet and infrared ultrashort pulses, we measure the phase and amplitude of the individual angular momentum channels as a function of kinetic energy in the outer-shell photoionization of neon. This allows us to unravel the influence of channel interference as well as the effect of the short-range, Coulomb and centrifugal potentials, on the dynamics of the photoionization process.
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| 5. |
- Sörngård, Johanna, 1993-
(författare)
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Attosecond information encoded in the photoemission angle
- 2024
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Electrons that break free during photoionization acquire a phase shift induced by the many-body potential of the parent ion. This phase shift can be interpreted as a delay in the photoionization process. This delay is very brief—on the order of attoseconds—and the time-scale of the process is short enough to, until recently, have been approximated as instantaneous. Recent developments in experimental methods have enabled the generation of light pulses of attosecond duration, allowing these phenomena to be probed in experiments. The photoionization delay can be measured in short-pulse pump-probe experiments that utilizes methods like RABBIT or streaking. Originally these experimental protocols used linearly polarized light and non-angularly resolved measurements.When the capability to use circularly polarized pulses in experiments grow, the numerical methods used to simulate such experiments must follow, and be made capable of accounting for pulses with non-linear polarization. As more experiments collect angularly resolved data it is important to develop tools to analyse these more complex results.This thesis summarizes the work I have done to extend two numerical simulation methods to circular polarization, as well as the extension of a theoretical tool to angularly resolved delays. By decoupling the angular and radial parts through the implementation of coupled two-photon operators, I have enabled the calculation of two-photon matrix elements for any detection angle and combination of photon polarizations.I have computed general formulas for so-called asymmetry parameters that can be used to effectively describe and analyze the angular dependence of cross sections and delays. I have further worked on extending a program suite that simulates the interaction of atoms with light in the time-dependent regime so that it can simulate light of arbitrary polarization.Through these efforts we have found ways to either simplify experiments, or to make them directly sensitive to only the effects of the probe pulse, which is the physically interesting part of the experimental signal.
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| 6. |
- Vinbladh, Jimmy, et al.
(författare)
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Relativistic Two-Photon Matrix Elements for Attosecond Delays
- 2022
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Ingår i: Atoms. - : MDPI AG. - 2218-2004. ; 10:3
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Tidskriftsartikel (refereegranskat)abstract
- The theory of one-photon ionization and two-photon above-threshold ionization is formulated for applications to heavy atoms in attosecond science by using Dirac–Fock formalism. A direct comparison of Wigner–Smith–Eisenbud delays for photoionization is made with delays from the Reconstruction of Attosecond Beating By Interference of Two-photon Transitions (RABBIT) method. Photoionization by an attosecond pulse train, consisting of monochromatic fields in the extreme ultraviolet range, is computed with many-body effects at the level of the relativistic random phase approximation (RRPA). Subsequent absorption and emission processes of infrared laser photons in RABBIT are evaluated by using static ionic potentials as well as asymptotic properties of relativistic Coulomb functions. As expected, light elements, such as argon, show negligible relativistic effects, whereas heavier elements, such a krypton and xenon, exhibit delays that depend on the fine-structure of the ionic target. The relativistic effects are notably close to ionization thresholds and Cooper minima with differences in fine-structure delays predicted to be as large as tens of attoseconds. The separability of relativistic RABBIT delays into a Wigner–Smith–Eisenbud delay and a universal continuum–continuum delay is studied with reasonable separability found for photoelectrons emitted along the laser polarization axis in agreement with prior non-relativistic results.
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| 7. |
- Zapata, Felipe, et al.
(författare)
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Implementation and validation of the relativistic transient absorption theory within the dipole approximation
- 2021
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Ingår i: Electronic Structure. - : IOP Publishing. - 2516-1075. ; 3:1
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Tidskriftsartikel (refereegranskat)abstract
- A relativistic transient absorption theory is derived, implemented and validated within the dipole approximation based on the time-dependent Dirac equation. In the non-relativistic limit, it is found that the absorption agrees with the well established non-relativistic theory based on the time-dependent Schrodringer equation. Time-dependent simulations have been performed using the Dirac equation and the Schrodinger equation for the hydrogen atom in two different attosecond transient absorption scenarios. These simulations validate the present relativistic theory. The presented work can be seen as a first step in the development of a more general relativistic attosecond transient absorption spectroscopy method for studying heavy atoms, but it also suggests the possibility of studying relativistic effects, such as Zitterbewegung, in the time domain.
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| 8. |
- Zapata, Felipe, et al.
(författare)
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Relativistic time-dependent configuration-interaction singles method
- 2022
-
Ingår i: Physical Review A: covering atomic, molecular, and optical physics and quantum information. - 2469-9926 .- 2469-9934. ; 105:1
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Tidskriftsartikel (refereegranskat)abstract
- In this work, a derivation and implementation of the relativistic time-dependent configuration-interaction singles (RTDCIS) method is presented. Various observables for krypton and xenon atoms obtained by RTDCIS are compared with experimental data and alternative relativistic calculations. This includes energies of occupied orbitals in the Dirac-Fock ground state, Rydberg state energies, Fano resonances, and photoionization cross sections. Diagrammatic many-body perturbation theory, based on the relativistic random phase approximation, is used as a benchmark with excellent agreement between RTDCIS reported at the Tamm-Dancoff level. Results from RTDCIS are computed in the length gauge, where the negative energy states can be omitted with acceptable loss of accuracy. A complex absorbing potential, that is used to remove photoelectrons far from the ion, is implemented as a scalar potential and validated for RTDCIS. The RTDCIS methodology presented here opens for future studies of strong-field processes, such as attosecond transient absorption and high-order harmonic generation, with electron and hole spin dynamics and other relativistic effects described by first principles via the Dirac equation.
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| 9. |
- Zhong, Shiyang, et al.
(författare)
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Attosecond electron–spin dynamics in Xe 4d photoionization
- 2020
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Ingår i: Nature Communications. - : Springer Science and Business Media LLC. - 2041-1723 .- 2041-1723. ; 11:1
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Tidskriftsartikel (refereegranskat)abstract
- The photoionization of xenon atoms in the 70–100 eV range reveals several fascinating physical phenomena such as a giant resonance induced by the dynamic rearrangement of the electron cloud after photon absorption, an anomalous branching ratio between intermediate Xe+ states separated by the spin-orbit interaction and multiple Auger decay processes. These phenomena have been studied in the past, using in particular synchrotron radiation, but without access to real-time dynamics. Here, we study the dynamics of Xe 4d photoionization on its natural time scale combining attosecond interferometry and coincidence spectroscopy. A time-frequency analysis of the involved transitions allows us to identify two interfering ionization mechanisms: the broad giant dipole resonance with a fast decay time less than 50 as, and a narrow resonance at threshold induced by spin-flip transitions, with much longer decay times of several hundred as. Our results provide insight into the complex electron-spin dynamics of photo-induced phenomena.
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