| 1. |
- Aasmundtveit, K.E., et al.
(author)
-
Structural ordering in phenyl-substituted polythiophenes
- 2000
-
In: Macromolecules. - : American Chemical Society (ACS). - 0024-9297 .- 1520-5835. ; 33:15, s. 5481-5489
-
Journal article (peer-reviewed)abstract
- Various substituted poly(phenylthiophene)s have been studied by X-ray diffraction. They are semicrystalline, with very different degrees of crystallinity. Those with para-substituted phenyl groups have a low degree of crystallinity, whereas those with ortho-substituted phenyl groups are more crystalline. The most crystalline materials in this study have two equally long substituents on the phenyl ring, one at the ortho position and the other at the ortho or meta position on the opposite side of the phenyl ring. Poly(3-(2,5-dioctylphenyl)thiophene) (PDOPT) was most thoroughly studied, and a structural model is proposed. The structure of PDOPT is quite different from previously studied substituted polythiophenes in that the octyl side chains are directed normal to the thiophene planes. In this way, the conjugated polymer chains are kept separated from each other. Solution-cast and spin-cast PDOPT films are anisotropic, with the octyl side chains oriented normal to the film surface in both cases. This is contrary to the situation for poly(3-alkylthiophene)s, where solution-cast and spin-cast films orient in different ways.
|
|
| 2. |
- Johansson, Tomas, et al.
(author)
-
Electrochemical bandgaps of substituted polythiophenes
- 2003
-
In: Journal of Materials Chemistry. - : Royal Society of Chemistry (RSC). - 0959-9428 .- 1364-5501. ; 13:6, s. 1316-1323
-
Journal article (peer-reviewed)abstract
- The electrochemical bandgaps for different soluble substituted polythiophenes have been measured by cyclic voltammetry. The effect of substituents on the oxidation/reduction potentials is discussed. Bandgaps obtained by cyclic voltammetry have been found to be in general higher than optical bandgaps. Among regioregular polymers substituted with a phenyl group at position 3 of the thiophene ring, examples are found that give very symmetric voltammograms. Rationalization for this behaviour is discussed from a conformational point of view.
|
|
| 3. |
- Theander, M., et al.
(author)
-
Photoluminescence quenching at a polythiophene/C-60 heterojunction
- 2000
-
In: Physical Review B (Condensed Matter and Materials Physics). - 1098-0121 .- 1550-235X. ; 61:19, s. 12957-12963
-
Journal article (peer-reviewed)abstract
- Quenching of photoluminescence in a substituted polythiophene in the presence of a deposited C-60 layer is studied by steady-state and time-resolved photoluminescence (PL). The steady-state PL is evaluated by con -sidering the interference of the absorbed and emitted electro-optical field in the thin film coupled to exciton diffusion in the conjugated polymer. PL quenching occurs for excitons generated within 5 nm from the heterojunction. A blueshift of the polymer emission spectrum is observed when C-60 is deposited on top of a polymer thin film. The blueshift is shown to be caused by PL quenching before the excitation is transferred to the lowest-energy sites.
|
|
