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Sökning: WFRF:(Moia R) > (2015)

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1.
  • Alorda, B., et al. (författare)
  • Collaborative distributed sun-tracking control system for building integration with minimal plant area and maximum energy-conversion efficiency
  • 2015
  • Ingår i: International Journal of Electrical Power & Energy Systems. - : Elsevier BV. - 0142-0615 .- 1879-3517. ; 70, s. 52-60
  • Tidskriftsartikel (refereegranskat)abstract
    • This paper presents a collaborative distributed sun-tracking control system for a novel Fixed Mirror Solar Concentrator (FMSC) structure, which increases the energy-conversion efficiency of the FMSC and reduces the space between solar collectors units, a positive aspect for in-building integration. The improved FMSC uses solar concentration collectors suited for mid-range thermal applications (90-200 °C) and is designed for easy installation in buildings because of its relatively small extension. The proposed solar orientation system (ORSYS) relies on a two-step algorithm to increase the energy captured by the receiver, which provides tolerance to common logical and mechanical errors in the estimation of the receiver position. ORSYS is implemented as a CAN-based distributed system, extended with web-interface features for supervision and configuration of the overall system. ORSYS also includes a coordination algorithm that allows adjacent collectors to share the physical space between them, thus reducing the total plant area. Experimental evaluation has been performed using an industrial-scale solar collector prototype, showing its feasibility and efficiency in terms of energy conversion in real environments.
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2.
  • Moia, Davide, et al. (författare)
  • The Role of Hole Transport between Dyes in Solid-State Dye-Sensitized Solar Cells
  • 2015
  • Ingår i: The Journal of Physical Chemistry C. - : AMER CHEMICAL SOC. - 1932-7447 .- 1932-7455. ; 119:33, s. 18975-18985
  • Tidskriftsartikel (refereegranskat)abstract
    • In dye-sensitized solar cells (DSSCs) photo-generated positive charges are normally considered to be carried away from the dyes by a separate phase of hole-transporting material (HTM). We show that there can also be significant transport within the dye monolayer itself before the hole reaches the HTM. We quantify the fraction of dye regeneration in solid-state DSSCs that can be attributed to this process. By using cyclic voltammetry and transient anisotropy spectroscopy, we demonstrate that the rate of interdye hole transport is prevented both on micrometer and nanometer length scales by reducing the dye loading on the TiO2 surface. The dye regeneration yield is quantified for films with high and low dye loadings (with and without hole percolation in the dye monolayer) infiltrated with varying levels of HTM. Interdye hole transport can account for >50% of the overall dye regeneration with low HTM pore filling. This is reduced to about 5% when the infiltration of the HTM in the pores is optimized in 2 mu m thick films. Finally, we use hole transport in the dye monolayer to characterize the spatial distribution of the HTM phase in the pores of the dyed mesoporous TiO2.
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