| 1. |
- Nyberg, Harald, et al.
(författare)
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Extreme friction reductions during inital running-in of W-S-C-Ti low-friction coatings
- 2013
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Ingår i: Wear. - : Elsevier. - 0043-1648 .- 1873-2577. ; 302:1-2 SI, s. 987-997
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Tidskriftsartikel (refereegranskat)abstract
- The disulphides of tungsten and molybdenum are known for their low friction properties when used as solid lubricants. Due to their low hardness, their load bearing capacity when used as thin films is poor. When carbon is added to a WS2 coating, both of these shortcomings are improved, and a structure consisting of nanocrystals of WS2, and possibly tungsten carbide, in a matrix of amorphous carbon is formed. In this study, an attempt is made for further increasing the hardness of such coatings, by addition of Ti, a strong carbide former. A number of W–S–C(–Ti) coatings were deposited using magnetron co-sputtering, and characterised with regard to chemical composition, structure and tribological properties. It was seen that addition of Ti significantly increased the hardness of the coatings, while maintaining their excellent low friction properties in dry atmosphere. However, the coatings with Ti showed extremely high initial friction, a feature not seen for the coatings without Ti. The mechanisms behind this running-in behaviour were investigated by studying surfaces at early stages of wear. It was observed that tribofilms formed during sliding for the coatings containing Ti consisted mainly of TiO2, with platelets of WS2 appearing in the contact only after prolonged sliding. For the pure W–S–C coatings, WS2 was observed in the sliding interface almost instantly at the onset of sliding.
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| 2. |
- Sundberg, Jill, et al.
(författare)
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Influence of Ti addition on the structure and properties of low-friction W–S–C coatings
- 2013
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Ingår i: Surface & Coatings Technology. - : Elsevier. - 0257-8972 .- 1879-3347. ; 232, s. 340-348
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Tidskriftsartikel (refereegranskat)abstract
- Transition metal dichalcogenides, such as WS2 and MoS2, are known for their layered structure and lubricating properties. When deposited as thin coatings, however, their use as solid lubricants is limited by their low hardness and load-bearing capacity. The addition of another element, such as carbon, can improve the mechanical properties, although the hardness of for example W-S-C coatings is still rather low. In this work, Ti has been added to W-S-C coatings in order to further increase the hardness by carbide formation. W-S-C and W-S-C-Ti coatings were deposited by non-reactive magnetron sputtering, and characterized with regard to composition, structure and mechanical and tribological properties. It was found that the addition of Ti leads to the formation of a new carbide phase, and a significant increase in hardness for coatings with moderate carbon contents. The friction properties of W-S-C-Ti coatings were found to be comparable to that of W-S-C coatings, with friction coefficients down to mu approximate to 0.02 and similar wear rates against steel in a dry atmosphere. Formation of WS2 in the wear track of W-S-C-Ti was confirmed by transmission electron microscopy. It has thus been shown that the addition of Ti to W-S-C coatings can increase the hardness, while still maintaining WS2 lubrication.
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| 3. |
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| 4. |
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| 5. |
- Sundberg, Jill, et al.
(författare)
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Tribochemically Active Ti–C–S Nanocomposite Coatings
- 2013
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Ingår i: Materials Research Letters. - : Taylor & Francis. - 2166-3831. ; 1:3, s. 148-155
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Tidskriftsartikel (refereegranskat)abstract
- We demonstrate a new concept of self-adaptive materials, where sulphur is incorporated into TiC/a-C coatings and may be released in, for example, a tribological contact. By reactive sputtering with H2S, sulphur goes into the carbide to form a TiC x S y phase in an amorphous carbon matrix. The addition of sulphur lowers the friction against steel. Significantly lower friction is obtained against a tungsten counter-surface, as WS2 is generated in the contact. Annealing experiments and formation energy calculations confirm that sulphur can be released from TiC x S y . Ti–C–S coatings are thus chemically active in tribological contacts, creating possibilities of new low-friction systems.
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| 6. |
- Nyberg, Harald, et al.
(författare)
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Calculated Trajectories of Curling Stones Sliding Under Asymmetrical Friction : Validation of Published Models
- 2013
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Ingår i: Tribology letters. - : Springer Science and Business Media LLC. - 1023-8883 .- 1573-2711. ; 50:3, s. 379-385
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Tidskriftsartikel (refereegranskat)abstract
- In the sport of curling, stones are slid across an ice sheet, aimed towards a target area. A sliding stone does not move in a straight line, but follows a curled trajectory, deviating in a direction determined by its rotation. As yet, no satisfactory explanation for this motion has been presented, although many attempts have been made. In many of them, the curling motion has been attributed to an asymmetrical distribution of the friction force acting on the sliding stone, typically such that the friction on the rear of the stone (as seen in the direction of motion) is higher than that on the front. In this paper, the motion of a rotating curling stone sliding over ice is calculated, for different assumed distributions of the coefficient of friction in the contact between stone and ice, using a numerical method. It is shown that no redistribution of the friction, no matter how extreme, can explain the observed motion of a real curling stone.
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| 7. |
- Nyberg, Harald, et al.
(författare)
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Design of low-friction PVD coating systems with enhanced running-in performance - carbon overcoats on TaC/aC coatings
- 2013
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Ingår i: Surface & Coatings Technology. - : Elsevier BV. - 0257-8972 .- 1879-3347. ; 222, s. 48-54
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Tidskriftsartikel (refereegranskat)abstract
- The widespread use of low friction PVD coatings on machine elements is limited by the high costs associated with fulfilling the demands on the surface quality of both the supporting substrate and the counter surface. In this work, an attempt is made at lowering these demands, by adding a sacrificial carbon overcoat to a TaC/aC low friction coating. Both coatings were deposited by planar magnetron DC sputtering, as separate steps in a single PVD-process. Coatings were deposited on substrates of two different surface roughnesses, in order to test the ability of this coating system to function on rougher substrates. Reciprocating ball on disc tests was performed, using balls with two different surface roughnesses. The worn surfaces were investigated using 3-D profilometry and SEM. The ability of the different overcoats to initially reduce the roughness of both the coated surface and the counter surface and to produce stable, low-friction conditions was examined for the different initial roughnesses. The implications for design of efficient run-in coatings for various systems are discussed.
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| 8. |
- Nyberg, Harald, 1985-, et al.
(författare)
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The asymmetrical friction mechanism that puts the curl in the curling stone
- 2013
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Ingår i: Wear. - : Elsevier. - 0043-1648 .- 1873-2577. ; 301:1-2, s. 583-589
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Tidskriftsartikel (refereegranskat)abstract
- Curling is an Olympic winter sport in which two teams slide stones across a sheet of ice towards a target area, some 28 m away from the release line. The sport has its name from the fact that the trajectory of a rotating stone becomes slightly curled, a fact used to reach open spots or take out opponent stones behind hindering “guarding” stones, etc. By slowly turning the stone clockwise when it is released, it will curl to the right, and vice versa. The resulting sideward deviation is typically slightly more than a metre. This intriguing tribological phenomenon has so far lacked a satisfactory explanation, although many attempts have been presented. In many of them, the curling motion has been attributed to an asymmetrical distribution of the friction force acting on the sliding stone, such that the friction on the rear of the stone (as seen in the direction of motion) is higher than that on the front. In a recent paper, we could show that no such redistribution of the friction, no matter how extreme, can explain the magnitude of the observed motion of a real curling stone. The present work presents an alternative asymmetrical mechanism that actually is strong enough to account for the observed motion. Further, in contrast to previous models, it satisfies other observed phenomena, including the independence of rotational speed of the stone and the strong dependence of the roughness of the stone. The model is backed up by experimental evidence and is based on the specific tribological conditions presented by the contact between a scratched curling stone and a pebbled ice sheet.
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