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- Quinet, Pascal, et al.
(author)
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Laser-induced-fluorescence lifetime measurements and relativistic Hartree-Fock oscillator strength calculations in singly ionized platinum
- 2008
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In: Physical Review A. Atomic, Molecular, and Optical Physics. - : American Physical Society. - 1050-2947 .- 1094-1622. ; 77:2
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Journal article (peer-reviewed)abstract
- Radiative lifetimes of eight odd-parity states of Pt II, in the energy range from 51 408 to 64 388 cm−1, have been measured by means of the time-resolved laser-induced-fluorescence technique. Free, singly ionized platinum ions were obtained in a laser-produced plasma and a tunable laser with 1.5 ns duration pulse was used to selectively excite the Pt+ ions. The comparison of the experimental results with relativistic Hartree-Fock calculations emphasizes the importance of valence-valence correlation and of core-polarization effects in this complex ion. A new and extensive set of calculated oscillator strengths and transition probabilities is reported in the present paper.
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