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Recent Advances in Enantioselective Pd-Catalyzed Allylic Substitution : From Design to Applications
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- Pàmies, O. (författare)
- Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43007, Spain.
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- Margalef, J. (författare)
- Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43007, Spain.
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- Cañellas, S. (författare)
- Janssen Cilag, Janssen Res & Dev, Discovery Sci, Toledo 45007, Spain.
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- James, J. (författare)
- Univ Coll Dublin, Ctr Synth & Chem Biol, Sch Chem, Dublin 4, Ireland.
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- Judge, E. (författare)
- Univ Coll Dublin, Ctr Synth & Chem Biol, Sch Chem, Dublin 4, Ireland.
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Guiry, P. J. (författare)
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- Moberg, Christina, 1947- (författare)
- KTH,Organisk kemi
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- Bäckvall, Jan-Erling (författare)
- Stockholms universitet,Institutionen för organisk kemi
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- Pfaltz, A. (författare)
- Univ Basel, Dept Chem, CH-4056 Basel, Switzerland.
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- Pericàs, M. A. (författare)
- Barcelona Inst Sci & Technol, Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain.;Univ Barcelona, Dept Quim Inorgan & Organ, Barcelona 08028, Spain.
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- Diéguez, M. (författare)
- Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43007, Spain.
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Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43007, Spain Janssen Cilag, Janssen Res & Dev, Discovery Sci, Toledo 45007, Spain. (creator_code:org_t)
- 2021-03-19
- 2021
- Engelska.
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Ingår i: Chemical Reviews. - : American Chemical Society. - 0009-2665 .- 1520-6890. ; 121:8, s. 4373-4505
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Abstract
Ämnesord
Stäng
- This Review compiles the evolution, mechanistic understanding, and more recent advances in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic substitutions. For each reaction, the catalytic data, as well as examples of their application to the synthesis of more complex molecules, are collected. Sections in which we discuss key mechanistic aspects for high selectivity and a comparison with other metals (with advantages and disadvantages) are also included. For Pd-catalyzed asymmetric allylic substitution, the catalytic data are grouped according to the type of nucleophile employed. Because of the prominent position of the use of stabilized carbon nucleophiles and heteronucleophiles, many chiral ligands have been developed. To better compare the results, they are presented grouped by ligand types. Pd-catalyzed asymmetric decarboxylative reactions are mainly promoted by PHOX or Trost ligands, which justifies organizing this section in chronological order. For asymmetric oxidative allylic substitution the results are grouped according to the type of nucleophile used. © 2021 American Chemical Society.
Ämnesord
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Nyckelord
- Allylation
- Catalysis
- Enantioselectivity
- Nucleophiles
- Stereochemistry
- Substitution reactions
- Synthesis (chemical)
- Allylic substitution
- Carbon nucleophiles
- Chronological order
- Complex molecules
- Enantioselective
- Heteronucleophiles
- High selectivity
- Mechanistic aspects
- Ligands
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Till lärosätets databas
- Av författaren/redakt...
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Pàmies, O.
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Margalef, J.
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Cañellas, S.
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James, J.
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Judge, E.
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Guiry, P. J.
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visa fler...
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Moberg, Christin ...
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Bäckvall, Jan-Er ...
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Pfaltz, A.
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Pericàs, M. A.
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Diéguez, M.
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visa färre...
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