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| 2. |
- Awasthi, Mukesh Kumar, et al.
(författare)
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Biochemical engineering for elemental sulfur from flue gases through multi-enzymatic based approaches – A review
- 2024
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Ingår i: Science of the Total Environment. - 0048-9697 .- 1879-1026. ; 914
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Forskningsöversikt (refereegranskat)abstract
- Flue gases are the gases which are produced from industries related to chemical manufacturing, petrol refineries, power plants and ore processing plants. Along with other pollutants, sulfur present in the flue gas is detrimental to the environment. Therefore, environmentalists are concerned about its removal and recovery of resources from flue gases due to its activation ability in the atmosphere to transform into toxic substances. This review is aimed at a critical assessment of the techniques developed for resource recovery from flue gases. The manuscript discusses various bioreactors used in resource recovery such as hollow fibre membrane reactor, rotating biological contractor, sequential batch reactor, fluidized bed reactor, entrapped cell bioreactor and hybrid reactors. In conclusion, this manuscript provides a comprehensive analysis of the potential of thermotolerant and thermophilic microbes in sulfur removal. Additionally, it evaluates the efficacy of a multi-enzyme engineered bioreactor in this process. Furthermore, the study introduces a groundbreaking sustainable model for elemental sulfur recovery, offering promising prospects for environmentally-friendly and economically viable sulfur removal techniques in various industrial applications.
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| 3. |
- Barney, Andrew, et al.
(författare)
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Transition towards decarbonisation for islands : Development of an integrated energy planning platform and application
- 2021
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Ingår i: Sustainable Energy Technologies and Assessments. - : Elsevier BV. - 2213-1388 .- 2213-1396. ; 47
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Tidskriftsartikel (refereegranskat)abstract
- This paper presents REACT-DECARB, an energy planning decarbonisation platform employing renewable energy sources coupled with storage for islands. The paper implements the energy scenario creation and economic evaluation steps of the platform on eight geographic islands in seven countries within the EU. Twenty-one technologically feasible energy scenarios, applicable to the specific conditions of each island, are specified and their economic assessment via a levelized cost of energy (LCOE) calculation is then performed. The main aim of this application is to verify the noted steps of the platform as well as to test its flexibility across geographically, socially and dimensionally disparate islands with various scenario generation methods. The results of the economic analysis show a wide variation of LCOE depending primarily on whether full island autonomy is assumed. In some cases the islands’ scenarios’ costs approach current market prices but are never below them; some scenarios are, however, below the current price of the island’s thermal generation. The sensitivity and uncertainty of the economic performance results’ and the variables used to calculate them are evaluated and discussed for two of the islands. The overall analysis and application has shown that the REACT-DECARB platform is suitable for different islands, regardless of location and size and can be useful for island energy planners.
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| 4. |
- Beatrez, William, et al.
(författare)
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Critical prethermal discrete time crystal created by two-frequency driving
- 2023
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Ingår i: Nature Physics. - : Springer Nature. - 1745-2473 .- 1745-2481. ; 19:3, s. 407-413
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Tidskriftsartikel (refereegranskat)abstract
- Discrete time crystals are non-equilibrium many-body phases of matter characterized by spontaneously broken discrete time-translation symmetry under periodic driving. At sufficiently high driving frequencies, the system enters the Floquet prethermalization regime, in which the periodically driven many-body state has a lifetime vastly exceeding the intrinsic decay time of the system. Here, we report the observation of long-lived prethermal discrete time-crystalline order in a three-dimensional (3D) lattice of 13C nuclei in diamond at room temperature. We demonstrate a two-frequency driving protocol, involving an interleaved application of slow and fast drives that simultaneously prethermalize the spins with an emergent quasi-conserved magnetization along the x̂ axis. This enables continuous and highly resolved observation of their dynamic evolution. We obtain videos of the time-crystalline response with a clarity and throughput orders of magnitude greater than previous experiments. Parametric control over the drive frequencies allows us to reach time-crystal lifetimes of up to 396 Floquet cycles, which we measure in a single-shot experiment. Such rapid measurement enables detailed characterization of the entire phase diagram, highlighting the role of prethermalization in stabilizing the time-crystal response. The two-frequency drive approach expands the toolkit for investigating non-equilibrium phases of matter stabilized by emergent quasi-conservation laws.
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| 5. |
- Butler, Eadaoin M., et al.
(författare)
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A prediction model for childhood obesity in New Zealand
- 2021
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Ingår i: Scientific Reports. - : Springer Nature. - 2045-2322. ; 11
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Tidskriftsartikel (refereegranskat)abstract
- Several early childhood obesity prediction models have been developed, but none for New Zealand's diverse population. We aimed to develop and validate a model for predicting obesity in 4-5-year-old New Zealand children, using parental and infant data from the Growing Up in New Zealand (GUiNZ) cohort. Obesity was defined as body mass index (BMI) for age and sex >= 95th percentile. Data on GUiNZ children were used for derivation (n=1731) and internal validation (n=713). External validation was performed using data from the Prevention of Overweight in Infancy Study (POI, n=383) and Pacific Islands Families Study (PIF, n=135) cohorts. The final model included: birth weight, maternal smoking during pregnancy, maternal pre-pregnancy BMI, paternal BMI, and infant weight gain. Discrimination accuracy was adequate [AUROC=0.74 (0.71-0.77)], remained so when validated internally [AUROC=0.73 (0.68-0.78)] and externally on PIF [AUROC=0.74 [0.66-0.82)] and POI [AUROC=0.80 (0.71-0.90)]. Positive predictive values were variable but low across the risk threshold range (GUiNZ derivation 19-54%; GUiNZ validation 19-48%; and POI 8-24%), although more consistent in the PIF cohort (52-61%), all indicating high rates of false positives. Although this early childhood obesity prediction model could inform early obesity prevention, high rates of false positives might create unwarranted anxiety for families.
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| 7. |
- Cao, Di, et al.
(författare)
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Concurrent measurement of perfusion parameters related to small blood vessels and cerebrospinal fluid circulation in the human brain using dynamic dual-spin-echo perfusion MRI
- 2023
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Ingår i: NMR in Biomedicine. - 0952-3480. ; 36:10
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Tidskriftsartikel (refereegranskat)abstract
- Accumulating evidence from recent studies has indicated the importance of studying the interaction between the microvascular and lymphatic systems in the brain. To date, most imaging methods can only measure blood or lymphatic vessels separately, such as dynamic susceptibility contrast (DSC) MRI for blood vessels and DSC MRI-in-the-cerebrospinal fluid (CSF) (cDSC MRI) for lymphatic vessels. An approach that can measure both blood and lymphatic vessels in a single scan offers advantages such as a halved scan time and contrast dosage. This study attempts to develop one such approach by optimizing a dual-echo turbo-spin-echo sequence, termed "dynamic dual-spin-echo perfusion (DDSEP) MRI". Bloch simulations were performed to optimize the dual-echo sequence for the measurement of gadolinium (Gd)-induced blood and CSF signal changes using a short and a long echo time, respectively. The proposed method furnishes a T1-dominant contrast in CSF and a T2-dominant contrast in blood. MRI experiments were performed in healthy subjects to evaluate the dual-echo approach by comparing it with existing separate methods. Based on simulations, the short and long echo time were chosen around the time when blood signals show maximum difference between post- and pre-Gd scans, and the time when blood signals are completely suppressed, respectively. The proposed method showed consistent results in human brains as previous studies using separate methods. Signal changes from small blood vessels occurred faster than from lymphatic vessels after intravenous Gd injection. In conclusion, Gd-induced signal changes in blood and CSF can be detected simultaneously in healthy subjects with the proposed sequence. The temporal difference in Gd-induced signal changes from small blood and lymphatic vessels after intravenous Gd injection was confirmed using the proposed approach in the same human subjects. Results from this proof-of-concept study will be used to further optimize DDSEP MRI in subsequent studies.
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| 8. |
- Chettiyam Thodi, Muhamed Fasil, et al.
(författare)
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Using RS and GIS Techniques to Assess and Monitor Coastal Changes of Coastal Islands in the Marine Environment of a Humid Tropical Region
- 2023
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Ingår i: Water. - : MDPI. - 2073-4441. ; 15:21
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Tidskriftsartikel (refereegranskat)abstract
- Vypin, Vallarpadam, and Bolgatty are significant tropical coastal islands situated in the humid tropical Kerala region of India, notable for their environmental sensitivity. This study conducted a comprehensive assessment of shoreline alterations on these islands by integrating Remote Sensing (RS) and Geographic Information Systems (GIS) techniques. Utilizing satellite imagery from the LANDSAT series with a spatial resolution of 30 m, the analysis spanned the years from 1973 to 2019. The Digital Shoreline Analysis System (DSAS) tool, integrated into the ArcGIS software, was employed to monitor and analyze shoreline shifts, encompassing erosion and accretion. Various statistical parameters, including Net Shoreline Movement (NSM), End Point Rate (EPR), and Linear Regression Rate (LRR), were utilized to evaluate these changes. Additionally, the study aimed to discern the root causes of shoreline modifications in the study area, encompassing disturbances and the construction of new structures on these islands. The results conclusively demonstrated the substantial impact endured by these coastal islands, with accretion on both sides leading to the creation of new landmasses. This manuscript effectively illustrates that these islands have experienced marine transgression, notably evidenced by accretion. Anthropogenic activities were identified as the primary drivers behind the observed shoreline changes, underscoring the need for careful management and sustainable practices in these fragile coastal ecosystems.
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| 9. |
- Fijoł, Natalia, et al.
(författare)
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3D-printed monolithic biofilters based on a polylactic acid (PLA) - hydroxyapatite (HAp) composite for heavy metal removal from an aqueous medium
- 2021
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Ingår i: RSC Advances. - : Royal Society of Chemistry (RSC). - 2046-2069. ; 11:51, s. 32408-32418
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Tidskriftsartikel (refereegranskat)abstract
- High flux, monolithic water purification filters based on polylactic acid (PLA) functionalised with fish scale extracted hydroxyapatite (HAp) were prepared by solvent-assisted blending and thermally induced phase separation (TIPS), followed by twin-screw extrusion into filaments and processed via three-dimensional (3D) printing. The printed filters with consistent pore geometry and channel interconnectivity as well as homogenous distribution of HAp in the PLA matrix showed adsorption capabilities towards heavy metals i.e. cadmium (Cd) and lead (Pb) with maximum adsorption capacity of 112.1 mg gHAp−1 and 360.5 mg gHAp−1 for the metal salt of Pb and Cd, respectively. The adsorption was found to be driven by a combination of ion exchange, dissolution and precipitation on HAp and surface complexation.
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