| 1. |
- Khan, Sharjeel Ahmed, et al.
(författare)
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A comparative study in the tribological behaviour of different DLC coatings sliding against titanium alloys
- 2024
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Ingår i: Wear. - : Elsevier. - 0043-1648 .- 1873-2577. ; 554-555
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Tidskriftsartikel (refereegranskat)abstract
- In this study, the tribological behaviour of different Diamond-like-Carbon (DLC) coatings sliding against titanium alloy (Ti6Al4V) was analysed in a pin-on-disc tribometer at different applied loads to study effectiveness of tool coatings in titanium alloys machining. Three different DLC coatings were deposited on cemented carbide substrate using HiPIMS (DLC-Ar, DLC-Ne) and arc (DLC-Bn) deposition techniques. A detailed analysis of the wear track and titanium countersurfaces were performed following the tribotest to develop understanding about the wear mechanism and associated variation in the friction response. The results indicated that DLC-Ar presents low friction and reduced wear of coating and respective titanium countersurface at lowest load, seemingly due to its inherent tendency to spontaneously form graphitic transfer-layer at the interface. With an increase in the applied load, the tendency to retain tribofilm decreases as shearing ensue quickly exposing the underneath substrate material. The wear performance of DLC-Ne coatings is better than DLC-Ar under highest load and friction behaviour relatively close to DLC-Ar coatings. In comparison, under increased applied loads, DLC-Bn coatings offered better wear resistance and low friction compared with DLC-Ne and DLC-Ar coatings, which would offer improved performance in machining of titanium alloys.
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| 2. |
- Khan, Sharjeel Ahmed, et al.
(författare)
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Custom-tailored cross-cylinder tribotest to emulate wear mechanism in drilling of CFRP-Ti stacks
- 2023
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Ingår i: Tribology International. - : Elsevier. - 0301-679X .- 1879-2464. ; 186
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Tidskriftsartikel (refereegranskat)abstract
- While drilling of CFRP-Ti stacks, tool experiences complex tribomechanical interaction due to dissimilar workpiece constituents. For emulating tool wear behavior, the typical tribotest configuration such as reciprocating and pin-on-disc test are not representative for imitating contact scenario underwent during the drilling operation. Cross-cylinder tribotest is an effective test configuration to emulate contact in different manufacturing processes by providing fresh contact surface during sliding. In this work, for the first-time, tool wear of WC-Co cylinders was analyzed in cross-cylinder configuration against multi-material stack arrangement. Moreover, cross-cylinder testing against multi-material [CFRP-Ti]n workpiece showed cyclic variation in coefficient of friction against different workpiece constituents and wear mechanism is a combination of adhesive and abrasive wear on WC-Co tool, comparable to actual drilling operation.
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| 3. |
- Khan, Sharjeel Ahmed, et al.
(författare)
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Surface Roughness Influence on Tribological Behavior of HiPIMS DLC Coatings
- 2023
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Ingår i: Tribology Transactions. - : Taylor & Francis. - 1040-2004 .- 1547-397X. ; 66:3, s. 565-575
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Tidskriftsartikel (refereegranskat)abstract
- The application of diamond-like carbon (DLC) coatings in dry machining of difficult-to-machine materials has been gaining popularity due to high inertness, low coefficient of friction (COF), and high hardness of these coatings. Although the effect of surface roughness on the tribological properties of DLC coatings is of paramount importance, usually it is overlooked and coatings performance analysis was accomplished generally on highly polished substrates. The generation of polished surfaces is a time-consuming, labor-intensive process and, in most cases, not feasible for the industry due to its high cost. This article focuses on determining the effect of substrate (cemented carbide, WC-Co) surface roughness on the load-bearing capacity and tribological properties of DLC coatings deposited by High Power Impulse Magnetron Sputtering (HiPIMS) in Ne–Ar gas plasma. The DLC films were deposited onto WC-Co substrates with three different surface roughness profiles and their tribological performance were evaluated using a reciprocating tribotest. The high surface roughness resulted in increased wear rate due to high levels of asperities and increased potential for premature delamination of the coatings, while also causing severe damage to the counterbody due to inhibition of transfer film formation.
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| 4. |
- Khan, Sharjeel Ahmed
(författare)
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Sustainable and Environmentally Friendly Drilling of CFRP-Ti Stacks by DLC Coated Drills – A Tribomechanics Approach
- 2024
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Composite-metal stacks like Carbon Fiber Reinforced Plastic – Titanium alloy (CFRP-Ti) stacks are in high demand for various structural components of modern aircraft due to their high strength to weight ratio, good corrosion resistance, high thermal stability and other superior characteristics. Furthermore, CFRP-Ti stack is an eco-friendly material choice due to the growing emphasis towards sustainability and energy efficiency, to minimise fuel consumption. Mechanical drilling of CFRP-Ti stacks is inevitable and frequently employed operation for the purpose of rivets and bolts connections needed for component assembly in the aerospace sector. However, exceptional material endurance of CFRP-Ti stacks poses unmatched difficulty during the hole making process, as both CFRP and Ti6Al4V are characterised as difficult-to-machine materials. The distinct nature of stack materials causes rapid tool wear due to synergistic action of abrasive and adhesive wear, yielding poor hole quality, meanwhile compromising the structural integrity of CFRP-Ti stacks. Amidst growing productivity demands and environmentally friendly measures, prioritizing sustainability restrict the machining solutions viable for drilling of CFRP-Ti stacks. Dry machining emerges as the best option to abate the ecological hazards of metal-working fluids and their detrimental effect to CFRP matrix. Consequently, excessive cutting forces and temperatures were generated causing accelerated tool wear during the dry drilling process of CFRP-Ti stacks. The tool life is a decisive factor determining the hole quality during the mechanical drilling operation. The tool wear is aggravated from simultaneous wear action from distinct materials, as hard, brittle and heterogenous nature of CFRP fibers causes abrasive wear, whereas Ti6Al4V alloys are responsible for adhesive wear. The complex tribological interaction experienced by the cutting tool with distinct workpiece material entails for fundamental understanding into the tool wear mechanism. Cemented carbide (WC-Co) tools primarily employed in drilling of CFRP-Ti stacks undergo rapid tool wear. As tool material is the sole barrier towards the mechanical/thermal stresses in dry drilling process. The cutting tools are coated with wear resistance coatings such as Diamond-like Carbon (DLC) to transform the tribological contact and improve the tool life.The main objective of this thesis is to perform detailed tool wear analysis in drilling of CFRP-Ti stacks and emulate the tool wear mechanism by custom-tailored cross-cylinder tribotest using uncoated and DLCs coated tools. Non-hydrogenated DLC coatings were deposited by High Power Impulse Magnetron sputtering (HiPIMS) and arc deposition technology on cemented carbide substrate of different geometries (disc, cylinders & drills). The doctoral dissertation comprises of three parts (covered in 5 articles). The Part-1 (PAPER A&B) covers the preliminary characterisation of as-deposited DLC coatings to understand the effect of substrate surface roughness on the adhesion and tribological performance of DLC coatings. Secondly, the tribological behaviour of different DLC coatings against Ti6Al4V counterbody in pin-on-disc tribotest was analysed at different applied loads, to correlate with titanium machining. As well known, traditional tribometer does not involve renewing of the countersurface as movement occurs in the same track. Such tribotest are not effective to mimic the complex contact situation experienced during the drilling of CFRP-Ti stacks. As, no simple yet effective tribotest technique is available to replicate contact situation of complex multi-material stack sequence. Therefore, in Part-2 (PAPER C&D), development and exploitation of a cross-cylinder tribotest technique against multi-material stack of CFRP-Ti workpiece and its individual constituents was performed to emulate wear mechanism of the uncoated and DLCs coated tools during machining of CFRP-Ti stacks. Lastly, in Part-3 (PAPER E), in-depth tool wear analysis of uncoated and DLCs coated drills were analysed in dry drilling of CFRP-Ti stack by successively analysing the tool wear growth after set number of drilled holes.The results showed that cross-cylinder tribotest is an effective and simple appraisal technique to emulate the complex tool wear mechanism against multi-material of CFRP-Ti stacks. Despite showing difference from actual drilling experiment and need for improvement, cross-cylinder test replicates the contact situation satisfactorily well. The customised cross-cylinder test would guide in tool material selection, optimization of cutting parameters and tribological understanding of new coatings solutions in a facile, economical, and effective way.
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| 5. |
- Nikonovich, Maksim, et al.
(författare)
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Effect of cryogenic aging and test-environment on the tribological and mechanical properties of PEEK composites
- 2024
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Ingår i: Tribology International. - : Elsevier Ltd. - 0301-679X .- 1879-2464. ; 194
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Tidskriftsartikel (refereegranskat)abstract
- This study investigated mechanical and tribological properties of polyetheretherketone (PEEK) and PEEK composites, before and after aging in liquid nitrogen for 5 months. Tribological tests conducted at 25 °C and at − 100 °C in air and in high vacuum (10−5 Pa) environment revealed the effect of matrix modification, fillers, environment, temperature, and cryogenic aging on their performances. Cryogenic aging of the polymers resulted in cryogenic embrittlement and decrease of the fracture toughness by around 10% and increase of wear rate by at least 20%. Very low coefficient of friction (0.02) was achieved in cryogenic vacuum environment for carbon fiber, graphite, and PTFE reinforced PEEK. The results indicate the significant impact of aging, temperature and environment on PEEK and its composites.
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| 6. |
- Nikonovich, Maksim, et al.
(författare)
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Structural, thermal, and mechanical characterisation of PEEK-based composites in cryogenic temperature
- 2023
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Ingår i: Polymer testing. - : Elsevier. - 0142-9418 .- 1873-2348. ; 125
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Tidskriftsartikel (refereegranskat)abstract
- Thermal, thermo-mechanical and mechanical properties of four different commercially available polyetheretherketones (PEEK) based materials were investigated. PEEK matrix was either modified and/or reinforced with carbon fibres, graphite and/or PTFE. Impact strength was measured at three different temperatures: 25 °C, −100 °C, and −195 °C. At 25 °C, thermal stability and mechanical properties, including the elastic modulus, compression, and impact strength, were enhanced with the addition of carbon fibres. Matrix modification had a minor impact on thermal stability, while the mechanical properties decreased, except for impact strength. At −100 °C, the mechanical properties of the neat polymers were improved, including increased impact strength by 20% compared to values at 25 °C. Addition of fillers hindered the rise of impact strength due to complex mechanisms caused by different coefficients of thermal expansion of reinforcements and matrix. At −195 °C, the significant increase of impact strength was revealed for unmodified PEEK reaching 30 times higher values than at 25 °C, while matrix modification suppressed the rise of impact strength. The scratch test indicated the superior behaviour of unfilled PEEK during the tested load range (up to 15 N), while the effect of the fillers was observed at much lower load threshold of 7 N.
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| 7. |
- Nikonovich, Maksim
(författare)
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Tribological and Mechanical Performance of Thermoplastic Composites : Effect of Cryogenic Aging and Testing-Environment
- 2024
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Recent advancements in energy, space, medicine, and transportation sectors have raised the demand for high-performing materials capable of functioning under demanding conditions such as low temperatures, vacuum, and cryogenic liquids like liquid nitrogen, natural gas, and hydrogen. Besides exposure to cryogenic environments, materials must withstand extensive loads and temperature gradients, inevitably leading to decreases in material properties, premature wear, reduced service life, and early failure due to aging. The performance of various components, including valves, bearings, seals, and gaskets, often determines the overall system performance.High-performance thermoplastic polymers, particularly polyetheretherketone (PEEK) and polyimide (PI), are favourable candidates for demanding tribological applications due to their exceptional mechanical, chemical, and thermal properties. Although PEEK and PI-based materials have been utilised for cryogenic applications, they still do not fully meet all the requirements. To improve their mechanical properties and tribological performance, various modifications and fillers, including carbon fibres and solid lubricants such as graphite, molybdenum disulphide (MoS2), and polytetrafluoroethylene (PTFE), are introduced. While most studies focus on their behaviour in ambient conditions, ambiguities remain regarding their performance and failure mechanisms in demanding environments. Moreover, there has been limited investigation on the impact of long-term or cyclic exposure to cryogenic temperatures and liquids on the properties of polymers and polymer composites. This thesis investigates thermal, thermo-mechanical, and mechanical properties, as well as the tribological performance, of selected commercially available high-performance thermoplastic composites based on PEEK and PI matrices under varying test conditions. Friction behaviour and wear mechanisms of the materials were studied in detail in air and vacuum at 25 °C, as well as in vacuum at –100 °C. Thermo-mechanical and mechanical properties, as well as failure mechanisms, were examined in a temperature range from –195 °C to 25 °C. Furthermore, the thermal, mechanical, and tribological performance of PEEK and PIbased materials were further evaluated at 25 °C after the materials underwent two types of cryogenic aging: 1) long-term cryogenic aging in liquid nitrogen at –196 °C for 5 months, and 2) cyclic-aging for 12 weeks; each cycle was 7 days and included two steps: 6 days in liquid nitrogen at –196 °C and 1 day in an oven at 40 °C.The results show that material performance and wear mechanisms are significantly influenced by the test environment, temperature, and cryogenic aging, depending on polymer structure and composition. Variations in polymer structure and the addition of fillers improved mechanical properties at room and low temperatures without significantly affecting thermal properties. Polymer matrix physical shrinkage at low temperatures enhanced the filler/matrix interface, resulting in fracture toughness improvements of up to 40% for PEEK and 150% for PI. However, thermal stresses at the interface with carbon fibres and graphite competed with matrix toughening.In vacuum environment, PEEK exhibited a lower coefficient of friction, but a higher wear rate compared to its performance in air, mainly due to desorption of water molecules. The tribological performance of PEEK improved with the addition of carbon fibres, graphite, and PTFE. PI1 maintained consistent performance across all environments, while PI5 displayed notable variations, including a very low coefficient of friction in vacuum. The addition of MoS2 or graphite to PI1 reduced the coefficient of friction and wear rate enhancing transfer film formation, and PTFE mitigated significant changes.At low temperature in vacuum, improved toughness allowed PEEK to withstand increased contact pressure, reducing the wear rate. PEEK composites with carbon fibres, graphite, and PTFE showed a very low coefficient of friction (0.02). In contrast, PI experienced increased coefficient of friction and wear rate due to high contact stresses and abrasive wear. The formation of a thin, homogeneous transfer film on the countersurface and polymer disk was advantageous in reducing friction and wear.Cryogenic aging caused embrittlement in PEEK-based materials and neat PI due to incomplete chain relaxation, but it improved the filler/matrix interface in PI composites, enhancing fracture toughness by 58% for the PI/MoS2 composite. While neat polymers experienced minimal effects, some composites showed up to a 220% increase in wear rate. Cryogenic cyclic aging demonstrated that PEEK was more sensitive to aging than PI, with a 22% reduction in fracture toughness for PEEK and up to a 93% increase for PI. Tribological tests indicated increased abrasive wear for unreinforced polymers and pronounced adhesive wear for composites, leading to more homogeneous transfer film generation. In vacuum, the wear rate of aged graphite-reinforced PI increased dramatically by 10920%.The outcome of the presented research demonstrates the need for custom-designed polymer-based materials to fit specific demanding tribological applications, and consider cryogenic aging effect on polymer properties, which is not currently the case.
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