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- Boix, Virginia, et al.
(författare)
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Graphene as an Adsorption Template for Studying Double Bond Activation in Catalysis
- 2022
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Ingår i: Journal of Physical Chemistry C. - : American Chemical Society (ACS). - 1932-7447 .- 1932-7455. ; 126:33, s. 14116-14124
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Tidskriftsartikel (refereegranskat)abstract
- Hydrogenated graphene (H-Gr) is an extensively studied system not only because of its capabilities as a simplified model system for hydrocarbon chemistry but also because hydrogenation is a compelling method for Gr functionalization. However, knowledge of how H-Gr interacts with molecules at higher pressures and ambient conditions is lacking. Here we present experimental and theoretical evidence that room temperature O2exposure at millibar pressures leads to preferential removal of H dimers on H-functionalized graphene, leaving H clusters on the surface. Our density functional theory (DFT) analysis shows that the removal of H dimers is the result of water or hydrogen peroxide formation. For water formation, we show that the two H atoms in the dimer motif attack one end of the physisorbed O2molecule. Moreover, by comparing the reaction pathways in a vacuum with the ones on free-standing graphene and on the graphene/Ir(111) system, we find that the main role of graphene is to arrange the H atoms in geometrical positions, which facilitates the activation of the O═O double bond.
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2. |
- Schnadt, Joachim, et al.
(författare)
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Experimental and theoretical study of oxygen adsorption structures on Ag(111)
- 2009
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Ingår i: Physical Review B (Condensed Matter and Materials Physics). - 1098-0121. ; 80:7
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Tidskriftsartikel (refereegranskat)abstract
- The oxidized Ag(111) surface has been studied by a combination of experimental and theoretical methods, scanning tunneling microscopy, x-ray photoelectron spectroscopy, and density functional theory. A large variety of different surface structures is found, depending on the detailed preparation conditions. The observed structures fall into four classes: (a) individually chemisorbed atomic oxygen atoms, (b) three different oxygen overlayer structures, including the well-known p(4x4) phase, formed from the same Ag-6 and Ag-10 building blocks, (c) a c(4x8) structure not previously observed, and (d) at higher oxygen coverages structures characterized by stripes along the high-symmetry directions of the Ag(111) substrate. Our analysis provides a detailed explanation of the atomic-scale geometry of the Ag-6/Ag-10 building block structures and the c(4x8) and stripe structures are discussed in detail. The observation of many different and co-existing structures implies that the O/Ag(111) system is characterized by a significantly larger degree of complexity than previously anticipated, and this will impact our understanding of oxidation catalysis processes on Ag catalysts.
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3. |
- Schnadt, Joachim, et al.
(författare)
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Revisiting the structure of the p(4x4) surface oxide on Ag(111)
- 2006
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Ingår i: Physical Review Letters. - 1079-7114. ; 96
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Tidskriftsartikel (refereegranskat)abstract
- Scanning tunneling microscopy (STM) and density-functional theory are used to reexamine the structure of the renowned p(4×4)-O/Ag(111) surface oxide. The accepted structural model [C. I. Carlisle et al., Phys. Rev. Lett. 84, 3899 (2000)] is incompatible with the enhanced resolution of the current STM measurements. An "Ag6 model" is proposed that is more stable than its predecessor and accounts for the coexistence of the p(4×4) and a novel c(3×5sqrt(3))rect phase. This coexistence is an indication of the dynamic complexity of the system that until now has not been appreciated.
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