| 1. |
- Arellano, Santiago, 1981, et al.
(författare)
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Synoptic analysis of a decade of daily measurements of SO2 emission in the troposphere from volcanoes of the global ground-based Network for Observation of Volcanic and Atmospheric Change
- 2021
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Ingår i: Earth System Science Data. - : Copernicus GmbH. - 1866-3516 .- 1866-3508. ; 13:3, s. 1167-1188
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Tidskriftsartikel (refereegranskat)abstract
- Volcanic plumes are common and far-reaching manifestations of volcanic activity during and between eruptions. Observations of the rate of emission and composition of volcanic plumes are essential to recognize and, in some cases, predict the state of volcanic activity. Measurements of the size and location of the plumes are important to assess the impact of the emission from sporadic or localized events to persistent or widespread processes of climatic and environmental importance. These observations provide information on volatile budgets on Earth, chemical evolution of magmas, and atmospheric circulation and dynamics. Space-based observations during the last decades have given us a global view of Earth's volcanic emission, particularly of sulfur dioxide (SO2). Although none of the satellite missions were intended to be used for measurement of volcanic gas emission, specially adapted algorithms have produced time-averaged global emission budgets. These have confirmed that tropospheric plumes, produced from persistent degassing of weak sources, dominate the total emission of volcanic SO2. Although space-based observations have provided this global insight into some aspects of Earth's volcanism, it still has important limitations. The magnitude and short-term variability of lower-atmosphere emissions, historically less accessible from space, remain largely uncertain. Operational monitoring of volcanic plumes, at scales relevant for adequate surveillance, has been facilitated through the use of ground-based scanning differential optical absorption spectrometer (ScanDOAS) instruments since the beginning of this century, largely due to the coordinated effort of the Network for Observation of Volcanic and Atmospheric Change (NOVAC). In this study, we present a compilation of results of homogenized post-analysis of measurements of SO2 flux and plume parameters obtained during the period March 2005 to January 2017 of 32 volcanoes in NOVAC. This inventory opens a window into the short-term emission patterns of a diverse set of volcanoes in terms of magma composition, geographical location, magnitude of emission, and style of eruptive activity. We find that passive volcanic degassing is by no means a stationary process in time and that large sub-daily variability is observed in the flux of volcanic gases, which has implications for emission budgets produced using short-term, sporadic observations. The use of a standard evaluation method allows for intercomparison between different volcanoes and between ground- and space-based measurements of the same volcanoes. The emission of several weakly degassing volcanoes, undetected by satellites, is presented for the first time. We also compare our results with those reported in the literature, providing ranges of variability in emission not accessible in the past. The open-access data repository introduced in this article will enable further exploitation of this unique dataset, with a focus on volcanological research, risk assessment, satellite-sensor validation, and improved quantification of the prevalent tropospheric component of global volcanic emission. Datasets for each volcano are made available at https://novac.chalmers.se (last access: 1 October 2020) under the CC-BY 4 license or through the DOI (digital object identifier) links provided in Table 1.
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| 2. |
- Galle, Bo, 1952, et al.
(författare)
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Network for Observation of Volcanic and Atmospheric Change (NOVAC)-A global network for volcanic gas monitoring: Network layout and instrument description
- 2010
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Ingår i: Journal of Geophysical Research. - 0148-0227 .- 2156-2202. ; 115:D5, s. Art. no. D05304-
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Tidskriftsartikel (refereegranskat)abstract
- This paper presents the global project Network for Observation of Volcanic and Atmospheric Change (NOVAC), the aim of which is automatic gas emission monitoring at active volcanoes worldwide. Data from the network will be used primarily for volcanic risk assessment but also for geophysical research, studies of atmospheric change, and ground validation of satellite instruments. A novel type of instrument, the scanning miniaturized differential optical absorption spectroscopy (Mini-DOAS) instrument, is applied in the network to measure volcanic gas emissions by UV absorption spectroscopy. The instrument is set up 5-10 km downwind of the volcano under study, and typically two to four instruments are deployed at each volcano in order to cover different wind directions and to facilitate measurements of plume height and plume direction. Two different versions of the instrument have been developed. Version I was designed to be a robust and simple instrument for measurement of volcanic SO2 emissions at high time resolution with minimal power consumption. Version II was designed to allow the best possible spectroscopy and enhanced flexibility in regard to measurement geometry at the cost of larger complexity, power consumption, and price. In this paper the project is described, as well as the developed software, the hardware of the two instrument versions, measurement strategies, data communication, and archiving routines. As of April 2009 a total of 46 instruments have been installed at 18 volcanoes worldwide. As a typical example, the installation at Tungurahua volcano in Ecuador is described, together with some results from the first 21 months of operation at this volcano.
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| 3. |
- Johansson, Mattias Erik, 1980, et al.
(författare)
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Mobile mini-DOAS measurement of the outflow of NO2 and HCHO from Mexico City
- 2009
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Ingår i: Atmospheric Chemistry and Physics. - : Copernicus GmbH. - 1680-7316 .- 1680-7324. ; 9, s. 5647-5653
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Tidskriftsartikel (refereegranskat)abstract
- We here present the results from mobile measurements using two ground-based zenith viewing Differential Optical Absorption Spectroscopy (DOAS) instruments. The measurement was performed in a cross-section of the plume from the Mexico City Metropolitan Area (MCMA) on 10 March 2006 as part of the MILAGRO field campaign. The two instruments operated in the UV and the visible wavelength region respectively and have been used to derive the differential vertical columns of HCHO and NO2 above the measurement route. This is the first time the mobile mini-DOAS instrument has been able to measure HCHO, one of the chemically most important and interesting gases in the polluted urban atmosphere.Using a mass-averaged wind speed and wind direction from the WRF model the instantaneous flux of HCHO and NO2 has been calculated from the measurements and the results are compared to the CAMx chemical model. The calculated flux through the measured cross-section was 1.9 (1.5–2.2) kg/s of HCHO and 4.4 (4.0–5.0) kg/s of NO2 using the UV instrument and 3.66 (3.63–3.73) kg/s of NO2 using the visible light instrument. The modeled values from CAMx for the outflow of both NO2 and HCHO, 1.1 and 3.6 kg/s, respectively, show a reasonable agreement with the measurement derived fluxes.
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| 4. |
- Johansson, Mattias Erik, 1980, et al.
(författare)
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The Dual-Beam mini-DOAS technique - measurements of volcanic gas emission, plume height and plume speed with a single instrument
- 2009
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Ingår i: Bulletin of Volcanology. - 0258-8900 .- 1432-0819. ; 71, s. 747-751
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Tidskriftsartikel (refereegranskat)abstract
- The largest error in determining volcanic gas fluxes using ground based optical remote sensing instruments is typically the determination of the plume speed, and in the case of fixed scanning instruments also the plume height. We here present a newly developed technique capable of measuring plume height, plume speed and gas flux using one single instrument by simultaneously collecting scattered sunlight in two directions. The angle between the two measurement directions is fixed, removing the need for time consuming in-field calibrations. The plume height and gas flux is measured by traversing the plume and the plume speed by performing a stationary measurement underneath the plume. The instrument was tested in a field campaign in May 2005 at Mt. Etna, Italy, where the measured results are compared to wind fields derived from a meso-scale meteorological model (MM5). The test and comparison show that the instrument is functioning and capable of estimating wind speed at the plume height.
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| 5. |
- Johansson, Mattias Erik, 1980, et al.
(författare)
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Tomographic reconstruction of gas plumes using scanning DOAS
- 2009
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Ingår i: Bulletin of Volcanology. - : Springer Science and Business Media LLC. - 0258-8900 .- 1432-0819. ; 71:10, s. 1169-1178
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Tidskriftsartikel (refereegranskat)abstract
- This paper presents a method to reconstruct the gas distribution inside a vertical cross section of a gas plume by combining data from two or more scanning DOAS instruments using a tomographic algorithm. The method can be applied to gas plumes from any single, elevated point source, such as a volcano or industrial chimney. Such two-dimensional concentration distributions may prove to be useful for example in plume chemistry, dispersion and environmental impact studies. Here we show the case with one scanning DOAS instrument located on each side of the plume, which is the easiest and most economic setup as well as the most useful in routine monitoring of e.g. volcanic gas emissions. The paper investigates the conditions under which tomographic reconstructions can be performed and discusses limitations of this setup. The proposed method has been studied theoretically by numerical simulations and has been experimentally tested during two field campaigns, with measurements of SO2 emissions from a volcano and a power plant. The simulations show that, under good measurement conditions, the algorithm presented performs well, which is further confirmed by the experimental results.
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| 6. |
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| 7. |
- Rivera, Claudia, 1976, et al.
(författare)
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Validation of optical remote sensing measurement strategies applied to industrial gas emissions
- 2009
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Ingår i: International Journal of Remote Sensing. - : Informa UK Limited. - 1366-5901 .- 0143-1161. ; 30:12, s. 3191-3204
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Tidskriftsartikel (refereegranskat)abstract
- In May 2004 a field-campaign was conducted at a power plant in Spain, aiming at validating the use of a miniaturized, fibre-optic, ultraviolet, differential optical absorption spectrometer (mini-DOAS) instrument for sulphur dioxide flux (SO2) quantification. Emissions were determined by integrating the total number of molecules in a vertical cross-section of the gas plume, and multiplying them by the wind component at plume height. Calculated wind data was compared with balloon soundings. Plume height, computed from a tomographic reconstruction of the plume was compared with stereo-photogrammetric methods and a plume rise model. Finally, SO2 fluxes were compared to emissions reported by the power station. Although the meteorological conditions during the field-campaign were adverse, with large fluctuations in wind-speed and wind-direction, the optical measurements performed proved to be practically feasible and compared well with the techniques used for the validation. SO2 fluxes derived by mini-DOAS were within 7% of the ones reported by the power station.
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| 8. |
- De Gouw, J. A., et al.
(författare)
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Airborne Measurements of Ethene from Industrial Sources Using Laser Photo-Acoustic Spectroscopy
- 2009
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Ingår i: Environmental Science & Technology. - : American Chemical Society (ACS). - 0013-936X .- 1520-5851. ; 43:7, s. 2437-2442
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Tidskriftsartikel (refereegranskat)abstract
- A laser photoacoustic spectroscopy (LPAS) instrument was developed and used for aircraft measurements of ethene from industrial sources near Houston, Texas. The instrument provided 20 s measurements with a detection limit of less than 0.7 ppbv. Data from this instrument and from the GC-FID analysis of air samples collected in flight agreed within 15% on average. Ethene fluxes from the Mt. Belvieu chemical complex to the northeast of Houston were quantified during 10 different flights. The average flux was 520 +/- 140 kg h(-1) in agreement with independent results from solar occultation flux (SOF) measurements, and roughly an order of magnitude higher than regulatory emission inventories indicate. This study shows that ethene emissions are routinely at levels that qualify as emission upsets, which need to be reported to regional air quality managers.
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| 9. |
- Grutter, M., et al.
(författare)
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SO2 emissions from Popocatépetl volcano: emission rates and plume imaging using optical remote sensing techniques
- 2008
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Ingår i: Atmospheric Chemistry and Physics. - : Copernicus GmbH. - 1680-7316 .- 1680-7324. ; 8, s. 6655-6663
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Tidskriftsartikel (refereegranskat)abstract
- Sulfur dioxide emissions from the Popocatépetl volcano in central Mexico were measured during the MILAGRO field campaign in March 2006. A stationary scanning DOAS (Differential Optical Absorption Spectrometer) was used to monitor the SO2 emissions from the volcano and the results were compared with traverses done with a COSPEC from the ground and a DOAS instrument on board an ultra-light aircraft. Daytime evolutions as well as day-to-day variation of the SO2 emissions are reported. A value of 2.45±1.39 Gg/day of SO2 is reported from all the daily averages obtained during the month of March 2006, with large variation in maximum and minimum daily averages of 5.97 and 0.56 Gg/day, respectively. The large short-term fluctuations in the SO2 emissions obtained could be confirmed through 2-D visualizations of the SO2 plume measured with a scanning imaging infrared spectrometer. This instrument, based on the passive detection of thermal radiation from the volcanic gas and analysis with FTIR spectrometry, is used for the first time for plume visualization of a specific volcanic gas. A 48-h forward trajectory analysis indicates that the volcanic plume was predominantly directed towards the Puebla/Tlaxcala region (63%), followed by the Mexico City and Cuernavaca/Cuautla regions with 19 and 18% occurrences, respectively. 25% of the modeled trajectories going towards the Puebla region reached altitudes lower than 4000 m a.s.l. but all trajectories remained over this altitude for the other two regions.
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| 10. |
- Kern, Christoph, et al.
(författare)
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Halogen oxide measurements at Masaya Volcano, Nicaragua using active long path differential optical absorption spectroscopy
- 2009
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Ingår i: Bulletin of Volcanology. - 0258-8900 .- 1432-0819. ; 71, s. 659-670
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Tidskriftsartikel (refereegranskat)abstract
- Active Long Path Differential Optical Absorption Spectroscopy (LP-DOAS) measurements of halogen oxides were conducted at Masaya Volcano, in Nicaragua from April 14 to 26, 2007. The active LP-DOAS system allowed night-time halogen measurements and reduced the ClO detection limit by an order of magnitude when compared to previous passive DOAS measurements, as wavelengths below 300 nm could be used for the DOAS retrievals. BrO was detected with an average BrO/SO2 molecular ratio of approximately 3 × 10−5 during the day. However, BrO values were below the detection limit of the instrument for all night-time measurements, a strong indication that BrO is not directly emitted, but rather the result of photochemical formation in the plume itself according to the autocatalytic “bromine explosion” mechanism. Despite the increased sensitivity, both ClO and OClO could not be detected. The achieved upper limits for the X/SO2 ratios were 5 × 10−3 and 7 × 10−6, respectively. A rough calculation suggests that ClO and OClO should be present at similar abundances in volcanic plumes. Since the DOAS technique is orders of magnitude more sensitive for OClO than for ClO, this indicates that OClO should always be detectable in plumes in which ClO is found. However, further LP-DOAS studies are needed to conclusively clarify the role of chlorine oxides in volcanic plumes.
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