TRANSITION STRUCTURES IN VACUO AND THE THEORY OF ENZYME CATALYSIS - RUBISCOS CATALYTIC MECHANISM - A PARADIGMATIC CASE

• The molecular mechanism of Rubisco is discussed from the theoretical perspective provided by saddle points of index 1 (SPi-1) for the enolization, carboxylation and oxygenation of Rubisco's substrate, D-ribulose-1,5-bisphosphate, by using 3,4-dihydroxy-2-

Nyckelord

SIMPLE THEORETICAL-MODEL; MEYER-SCHUSTER REACTION; RHF-SCF-MO; STATE THEORY; RIBULOSE-1;5-BISPHOSPHATE CARBOXYLASE; CRYSTAL-STRUCTURE; HYDRIDE TRANSFER; CARBON-DIOXIDE; ENEDIOL MOIETY; ACTIVE-SITE

Publikations- och innehållstyp

ref (ämneskategori)

art (ämneskategori)