Transition structures of carbon dioxide fixation, hydration and C2 inversion for a model of Rubisco catalyzed reaction

• Using a model enediol intermediate, a reaction mechanism for the carboxylation followed by hydration, bond-breaking and inversion of configuration at C2 has been mapped as a set of transition structures with intermediary species. A 3-carbon molecular mode

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RIBULOSE-BISPHOSPHATE CARBOXYLASE; CRYSTAL-STRUCTURE; ACTIVE-SITE; RIBULOSE-1;5-BISPHOSPHATE CARBOXYLASE/OXYGENASE; 1;5-BISPHOSPHATE CARBOXYLASE; ENZYME CATALYSIS; OXYGENASE; RESOLUTION; SPINACH; ENOLIZATION

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