| 1. |
- Gorski, Krzysztof, et al.
(författare)
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The interplay of intersystem crossing and internal conversion in quadrupolar tetraarylpyrrolo[3,2-b]pyrroles
- 2024
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Ingår i: Journal of Materials Chemistry C. - : ROYAL SOC CHEMISTRY. - 2050-7526 .- 2050-7534.
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Tidskriftsartikel (refereegranskat)abstract
- Adding nitro groups to aromatic compounds usually quenches their fluorescence via intersystem crossing (ISC) or internal conversion (IC). Herein, we investigated centrosymmetric 1,4-dihydropyrrolo[3,2-b]pyrroles linked to variously substituted nitro-heteroaryls. A 1,4-orientation of the nitro substituent versus the electron rich 1,4-dihydropyrrolo[3,2-b]pyrrole core invokes a strong fluorescence in non-polar solvents and intense two-photon absorption while a 1,3-orientation of push-pull substituents results in a dramatic hypsochromic shift of absorption, weak, bathochromically shifted emission and weak two-photon absorption. The combined experimental and computational study indicates that the primary responsible factors are: (1) the difference in electron density distribution in the LUMO; (2) the difference in mu 10. IC is a dominant mechanism of non-radiative dissipation of energy in all these dyes but as long as the distribution of electron density within the HOMO and LUMO is delocalized on the 1,4-dihydropyrrolo[3,2-b]pyrrole core as well as on the nitroaromatic moieties its rate is slower than the fluorescence rate in non-polar solvents.
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| 2. |
- Mehboob, Fozia, et al.
(författare)
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Synergizing Transfer Learning and Multi-Agent Systems for Thermal Parametrization in Induction Traction Motors
- 2024
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Ingår i: Applied Sciences. - : MDPI. - 2076-3417. ; 14:11
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Tidskriftsartikel (refereegranskat)abstract
- Maintaining optimal temperatures in the critical parts of an induction traction motor is crucial for railway propulsion systems. A reduced-order lumped-parameter thermal network (LPTN) model enables computably inexpensive, accurate temperature estimation; however, it requires empirically based parameter estimation exercises. The calibration process is typically performed in labs in a controlled experimental setting, which is associated with a lot of supervised human efforts. However, the exploration of machine learning (ML) techniques in varied domains has enabled the model parameterization in the drive system outside the laboratory settings. This paper presents an innovative use of a multi-agent reinforcement learning (MARL) approach for the parametrization of an LPTN model. First, a set of reinforcement learning agents are trained to estimate the optimized thermal parameters using the simulated data in several driving cycles (DCs). The selection of a reinforcement learning agent and the level of neurons in the RL model is made based on variability of the driving cycle data. Furthermore, transfer learning is performed on a new driving cycle data collected on the measurement setup. Statistical analysis and clustering techniques are proposed for the selection of an RL agent that has been pre-trained on the historical data. It is established that by synergizing within reinforcement learning techniques, it is possible to refine and adjust the RL learning models to effectively capture the complexities of thermal dynamics. The proposed MARL framework shows its capability to accurately reflect the motor's thermal behavior under various driving conditions. The transfer learning usage in the proposed approach could yield significant improvement in the accuracy of temperature prediction in the new driving cycles data. This approach is proposed with the aim of developing more adaptive and efficient thermal management strategies for railway propulsion systems.
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| 3. |
- Shen, Shen, et al.
(författare)
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Edible Long-Afterglow Photoluminescent Materials for Bioimaging
- 2024
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Ingår i: Advanced Materials. - : WILEY-V C H VERLAG GMBH. - 0935-9648 .- 1521-4095.
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Tidskriftsartikel (refereegranskat)abstract
- Confining luminophores into modified hydrophilic matrices or polymers is a straightforward and widely used approach for afterglow bioimaging. However, the afterglow quantum yield and lifetime of the related material remain unsatisfactory, severely limiting the using effect especially for deep-tissue time-resolved imaging. This fact largely stems from the dilemma between material biocompatibility and the quenching effect of water environment. Herein an in situ metathesis promoted doping strategy is presented, namely, mixing approximate to 10-3 weight ratio of organic-emitter multicarboxylates with inorganic salt reactants, followed by metathesis reactions to prepare a series of hydrophilic but water-insoluble organic-inorganic doping afterglow materials. This strategy leads to the formation of edible long-afterglow photoluminescent materials with superior biocompatibility and excellent bioimaging effect. The phosphorescence quantum yield of the materials can reach dozens of percent (the highest case: 66.24%), together with the photoluminescent lifetime lasting for coupes of seconds. Specifically, a long-afterglow barium meal formed by coronene salt emitter and BaSO4 matrix is applied into animal experiments by gavage, and bright stomach afterglow imaging is observed by instruments or mobile phone after ceasing the photoexcitation with deep tissue penetration. This strategy allows a flexible dosage of the materials during bioimaging, facilitating the development of real-time probing and theranostic technology. A universal strategy is proposed to construct edible photoluminescent long-afterglow materials by embedding luminophore multicarboxylates into a series of inorganic salt lattices. Particularly, edible afterglow barium meal formed by coronene salt doped BaSO4 can be applied into gastrointestinal afterglow imaging captured by instruments or mobile phone. image
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| 4. |
- Szymanski, Bartosz, et al.
(författare)
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The effect of rigidity on the emission of quadrupolar strongly polarized dyes
- 2024
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Ingår i: New Journal of Chemistry. - : ROYAL SOC CHEMISTRY. - 1144-0546 .- 1369-9261.
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Tidskriftsartikel (refereegranskat)abstract
- Hybrid dyes comprising 1,4-dihydropyrrolo[3,2-b]pyrrole and two strongly electron-withdrawing benzoxadiazole substituents, differing in their level of planarization, offer an insightful window into the interplay between internal conversion and intersystem crossing as relaxation pathways from the excited state. The emission intensity is strong for non-fused systems whilst it is minimal for fused dyes. Computational evaluation has revealed that internal conversion, and not inter-system crossing, is the main non-radiative process for planar, fused quadrupolar dyes. Planarization of the pyrrolopyrrole chromophore switches the mechanism of non-radiative deactivation from intersystem crossing to internal conversion.
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| 5. |
- Ye, Danfeng, et al.
(författare)
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Deoxygenation-Promoted Aggregation-Induced TADF-RTP Dual Emission for High-Contrast Channel-Selectable Hypoxia Probing
- 2024
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Ingår i: The Journal of Physical Chemistry C. - : AMER CHEMICAL SOC. - 1932-7447 .- 1932-7455.
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Tidskriftsartikel (refereegranskat)abstract
- Thermally activated delayed fluorescence (TADF) and room-temperature phosphorescence (RTP) are two highly applicable emissive processes due to their time-resolved characteristics and their ability to respond to external stimuli. They have recently been integrated for comprehensive use in some solid-state luminogens; however, there remains a lack of molecular systems that can integrate them in the solution aggregated state, which considerably limits relevant biological applications. In this study, we present a molecular design enabling aggregation-induced TADF-RTP dual emission in the solution aggregated state, relying on the coexistence of T-1-to-S-1 and T-1-to-S-0 electronic processes in push-pull structures. This dual emission feature constitutes a broad spectral band with full width at half-maximum up to 175 nm, providing the ability to select different channels for biological detection and imaging. Moreover, deoxygenation is shown to promote molecular aggregation, leading to a significantly strengthened dual emission that enables a high-contrast hypoxia probing effect. These results not only reveal new photophysical mechanisms on organic molecules but also expand the detection functionality of luminescent materials in the biological field.
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