| 1. |
- Muschitiello, Francesco, et al.
(författare)
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New evidence of Holocene atmospheric circulation dynamics based on lake sediments from southern Sweden : a link to the Siberian High
- 2013
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Ingår i: Quaternary Science Reviews. - : Elsevier BV. - 0277-3791 .- 1873-457X. ; 77, s. 113-124
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Tidskriftsartikel (refereegranskat)abstract
- Oxygen (delta O-18) and carbon (delta C-13) isotope records of calcitic carbonate components (Chara sp. algal encrustations and Bithynia tentaculata gastropod opercula) from a lake-sediment succession on the Baltic Sea island of Gotland, south-eastern Sweden, have been obtained to investigate regional climate dynamics during the Holocene. The hydrological sensitivity of the small lake, particularly in terms of spring snowmelt contribution to the local water budget, provides a means of tracing past changes in the influence of snow-bearing easterly winds across the Baltic Sea Proper, which signifies the wintertime strength of the Siberian High. Repeated episodic depletions in O-18 at the centennial scale correlate with events of increased potassium concentration in the GISP2 ice-core record from Greenland, which indicates a coupling to large-scale fluctuations in atmospheric circulation patterns. A corresponding correlation with simultaneous depletions in C-13 suggests repeated responses of the local lake hydrology to snow-rich winters through decreasing water residence time, perhaps augmented by methanogenesis due to prolonged ice-cover seasons under the influence of an expanding Siberian High. Frequency analysis of the isotopic records reveals well-defined fluctuations at quasi-500-520-, 670-, 830- and 1430-yr periodicities, and a gradually stronger impact of Polar air outbreaks across the southern Baltic Sea region with time after ca 6000 cal. BP.
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| 2. |
- Schouten, Stefan, et al.
(författare)
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An interlaboratory study of TEX86 and BIT analysis of sediments, extracts, and standard mixtures
- 2013
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 14:12, s. 5263-5285
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Tidskriftsartikel (refereegranskat)abstract
- Two commonly used proxies based on the distribution of glycerol dialkyl glycerol tetraethers (GDGTs) are the TEX86 (TetraEther indeX of 86 carbon atoms) paleothermometer for sea surface temperature reconstructions and the BIT (Branched Isoprenoid Tetraether) index for reconstructing soil organic matter input to the ocean. An initial round-robin study of two sediment extracts, in which 15 laboratories participated, showed relatively consistent TEX86 values (reproducibility +/- 3-4 degrees C when translated to temperature) but a large spread in BIT measurements (reproducibility +/- 0.41 on a scale of 0-1). Here we report results of a second round-robin study with 35 laboratories in which three sediments, one sediment extract, and two mixtures of pure, isolated GDGTs were analyzed. The results for TEX86 and BIT index showed improvement compared to the previous round-robin study. The reproducibility, indicating interlaboratory variation, of TEX86 values ranged from 1.3 to 3.0 degrees C when translated to temperature. These results are similar to those of other temperature proxies used in paleoceanography. Comparison of the results obtained from one of the three sediments showed that TEX86 and BIT indices are not significantly affected by interlaboratory differences in sediment extraction techniques. BIT values of the sediments and extracts were at the extremes of the index with values close to 0 or 1, and showed good reproducibility (ranging from 0.013 to 0.042). However, the measured BIT values for the two GDGT mixtures, with known molar ratios of crenarchaeol and branched GDGTs, had intermediate BIT values and showed poor reproducibility and a large overestimation of the true (i.e., molar-based) BIT index. The latter is likely due to, among other factors, the higher mass spectrometric response of branched GDGTs compared to crenarchaeol, which also varies among mass spectrometers. Correction for this different mass spectrometric response showed a considerable improvement in the reproducibility of BIT index measurements among laboratories, as well as a substantially improved estimation of molar-based BIT values. This suggests that standard mixtures should be used in order to obtain consistent, and molar-based, BIT values.
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