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- Aggarwal, Ruchi, et al.
(författare)
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Nitrogen-Doped Carbon Nanoflakes by Acidic Charring of Microcrystalline Cellulose and Urea for the Rapid Removal of Imidacloprid from Water
- 2024
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Ingår i: ACS Applied Nano Materials. - 2574-0970. ; 7:1, s. 1-10
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Forskningsöversikt (refereegranskat)abstract
- Herein, cellulose as a natural biomass along with urea was acid-charred to synthesize nitrogen-doped carbon nanoflakes (N-CNF). The as-prepared N-CNF was used to rapidly remove the effluent of agricultural waste containing an Imidacloprid (IMD) insecticide. The adsorption data fit well to nonlinearly in the Sips adsorption model, which is a mixed Langmuir-Freundlich model with an adsorption capacity of ∼104.9 mg g-1. The adsorption follows pseudo-second-order kinetics linearly and nonlinearly, and thermodynamic parameters reveal that the adsorption process was spontaneous and endothermic. The effect of pH and the interference of ions was also checked. Further, spiking of IMD in different soil, lake, and tap wastewater samples was also done to enhance the practical applicability of removing IMD by N-CNF. The antibacterial properties of N-CNF were checked on both Gram-negative and Gram-positive bacterial strains as Escherichia coli and Bacillus subtilus, respectively, where they showed nontoxic behavior up to the concentration of 2 mg mL-1
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- Sharma, Sumit, 1990-, et al.
(författare)
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Droplet navigation on metastable hydrophobic and superhydrophobic nonwoven materials
- 2024
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Ingår i: Colloids and Surfaces A. - 0927-7757 .- 1873-4359. ; 683
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Tidskriftsartikel (refereegranskat)abstract
- Rendering any surface non-wettable requires it to be clean and dry after the droplet is deposited or impacted. Leveraging and quantifying the non-periodic or random topology non-wettable is intricate as the Cassie-Baxter state competes with the Wenzel or impaled state, which becomes further challenging for irregular and heterogeneous nonwoven materials. Herein, we report the fundamental insights of the impalement dynamics of droplets on metastable nonwovens and self-similar nonwoven-titanate nanostructured materials (SS-Ti-NMs) using laser scanning confocal microscopy in three dimensions. Our results represent the first example of liquid imbibition in metastable nonwovens and SS-Ti-NMs involving a complex interplay between a triumvirate of factors – the number of fibres in the defined cross-sectional area (volume), pore features, and intrinsic wetting properties of the constituent entities. Predictive models of the apparent contact angle and breakthrough pressure for nonwovens and their SS-Ti-NMs have been proposed based on micro- and nano-scale structural parameters. Enabled by X-ray microcomputed tomography analysis, a key set of three-dimensional fibre and structural parameters of nonwovens has been unveiled, which played a vital role in validating the predictive models of apparent contact angles.
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