| 1. |
- Lizundia, Erlantz, et al.
(författare)
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Multifunctional lignin-based nanocomposites and nanohybrids
- 2021
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Ingår i: Green Chemistry. - : Royal Society of Chemistry (RSC). - 1463-9262 .- 1463-9270. ; 23:18, s. 6698-6760
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Forskningsöversikt (refereegranskat)abstract
- Significant progress in lignins valorization and development of high-performance sustainable materials have been achieved in recent years. Reports related to lignin utilization indicate excellent prospects considering green chemistry, chemical engineering, energy, materials and polymer science, physical chemistry, biochemistry, among others. To fully realize such potential, one of the most promising routes involves lignin uses in nanocomposites and nanohybrid assemblies, where synergistic interactions are highly beneficial. This review first discusses the interfacial assembly of lignins with polysaccharides, proteins and other biopolymers, for instance, in the synthesis of nanocomposites. To give a wide perspective, we consider the subject of hybridization with metal and metal oxide nanoparticles, as well as uses as precursor of carbon materials and the assembly with other biobased nanoparticles, for instance to form nanohybrids. We provide cues to understand the fundamental aspects related to lignins, their self-assembly and supramolecular organization, all of which are critical in nanocomposites and nanohybrids. We highlight the possibilities of lignin in the fields of flame retardancy, food packaging, plant protection, electroactive materials, energy storage and health sciences. The most recent outcomes are evaluated given the importance of lignin extraction, within established and emerging biorefineries. We consider the benefit of lignin compared to synthetic counterparts. Bridging the gap between fundamental and application-driven research, this account offers critical insights as far as the potential of lignin as one of the frontrunners in the uptake of bioeconomy concepts and its application in value-added products.
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| 2. |
- Moreno, Adrian, et al.
(författare)
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Access to tough and transparent nanocomposites via Pickering emulsion polymerization using biocatalytic hybrid lignin nanoparticles as functional surfactants dagger
- 2021
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Ingår i: Green Chemistry. - : Royal Society of Chemistry (RSC). - 1463-9262 .- 1463-9270. ; 23:8, s. 3001-3014
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Tidskriftsartikel (refereegranskat)abstract
- Weak interfacial binding of lignin within synthetic polymer composites results in unsatisfactory mechanical properties that limit their application prospects. In the present work, polystyrene (PS) and poly(butyl methacrylate) (PBMA) nanocomposites containing lignin nanoparticles (LNPs) are produced by simple melting of polymeric latex dispersions obtained from free radical polymerization of oil-in-water Pickering emulsions stabilized by hybrid LNPs coated with chitosan and glucose oxidase. Owing to the formation of viscous polymer melts, the hybrid LNPs ended up uniformly dispersed within the polymeric matrices, which gave the polymeric nanocomposites markedly improved tensile strength without sacrificing their elasticity in comparison to pure PS and PBMA. Consequently, the composites reinforced with 15 wt% of the hybrid particles showed improvement in toughness by a factor of 3.5 and 15 compared to those of the corresponding pristine PS and PBMA. In addition, the presence of the hybrid particles conferred the nanocomposites with commendable UV-blocking and antioxidant properties which are relevant for protective packaging and coating applications. Overall, our results show a new and green route with excellent material economy (overall mass yield up to 91%) to obtain strong and transparent polymeric nanocomposites reinforced with up to 30 wt% of LNPs, which is expected to attract renewed interest in lignin-polymer composites for a broad range of applications.
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| 3. |
- Moreno, Adrian, et al.
(författare)
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Catalyst-Free Synthesis of Lignin Vitrimers with Tunable Mechanical Properties : Circular Polymers and Recoverable Adhesives
- 2021
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Ingår i: ACS Applied Materials and Interfaces. - : American Chemical Society (ACS). - 1944-8244 .- 1944-8252. ; 13:48, s. 57952-57961
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Tidskriftsartikel (refereegranskat)abstract
- Biobased circular materials are alternatives to fossil-based engineering plastics, but simple and material-efficient synthetic routes are needed for industrial scalability. Here, a series of lignin-based vitrimers built on dynamic acetal covalent networks with a gel content exceeding 95% were successfully prepared in a one-pot, thermally activated, and catalyst-free “click” addition of softwood kraft lignin (SKL) to poly(ethylene glycol) divinyl ether (PDV). The variation of the content of lignin from 28 to 50 wt % was used to demonstrate that the mechanical properties of the vitrimers can be widely tuned in a facile way. The lowest lignin content (28 wt %) showed a tensile strength of 3.3 MPa with 35% elongation at break, while the corresponding values were 50.9 MPa and 1.0% for the vitrimer containing 50 wt % of lignin. These lignin-based vitrimers also exhibited excellent performance as recoverable adhesives for different substrates such as aluminum and wood, with a lap shear test strength of 6.0 and 2.6 MPa, respectively. In addition, recyclability of the vitrimer adhesives showed preservation of the adhesion performance exceeding 90%, indicating a promising potential for their use in sustainable circular materials.
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| 4. |
- Moreno, Adrian, et al.
(författare)
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Unravelling the Hydration Barrier of Lignin Oleate Nanoparticles for Acid- and Base-Catalyzed Functionalization in Dispersion State
- 2021
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Ingår i: Angewandte Chemie International Edition. - : Wiley. - 1433-7851 .- 1521-3773. ; 60:38, s. 20897-20905
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Tidskriftsartikel (refereegranskat)abstract
- Lignin nanoparticles (LNPs) are promising renewable nanomaterials with applications ranging from biomedicine to water purification. However, the instability of LNPs under acidic and basic conditions severely limits their functionalization for improved performance. Here, we show that controlling the degree of esterification can significantly improve the stability of lignin oleate nanoparticles (OLNPs) in acidic and basic aqueous dispersions. The high stability of OLNPs is attributed to the alkyl chains accumulated in the shell of the particle, which delays protonation/deprotonation of carboxylic acid and phenolic hydroxyl groups. Owing to the enhanced stability, acid- and base-catalyzed functionalization of OLNPs at pH 2.0 and pH 12.0 via oxirane ring-opening reactions were successfully performed. We also demonstrated these new functionalized particles as efficient pH-switchable dye adsorbents and anticorrosive particulate coatings.
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| 5. |
- Rivière, Guillaume N., et al.
(författare)
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Toward waste valorization by converting bioethanol production residues into nanoparticles and nanocomposite films
- 2021
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Ingår i: Sustainable Materials and Technologies. - : Elsevier BV. - 2214-9937. ; 28
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Tidskriftsartikel (refereegranskat)abstract
- A “waste-valorization” approach was developed to transform recalcitrant hydrolysis lignin (HL) from second-generation bioethanol production into multifunctional bio-based products. The hydrolysis lignin (HL) was extracted with aqueous acetone, yielding two fractions enriched in lignin and cellulose, respectively. The soluble hydrolysis lignin (SHL) was converted into anionic and cationic colloidal lignin particles (CLPs and c-CLPs). The insoluble cellulose-rich fraction was transformed into lignocellulosic nanofibrils that were further combined with CLPs or c-CLPs to obtain nanocomposite films with tailored mechanical properties, oxygen permeability and antioxidant properties. To enable prospective applications of lignin in nanocomposite films and beyond, CLPs and c-CLPs were also produced from a soda lignin (SL) and the influence of the lignin type on the particle size and ecotoxicity was evaluated. Finally, the carbon footprint of the entire process from hydrolysis lignin to films was assessed and an integration to industrial scale was considered to reduce the energy consumption. While most previous work utilizes purified lignin and pristine and often purified cellulose fibers to produce nanomaterials, this work provides a proof of concept for utilizing the recalcitrant lignin-rich side stream of the bioethanol process as raw material for functional nanomaterials and renewable composites.
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| 6. |
- Zhao, Bin, et al.
(författare)
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Lignin-Based Porous Supraparticles for Carbon Capture
- 2021
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Ingår i: ACS Nano. - : American Chemical Society (ACS). - 1936-0851 .- 1936-086X. ; 15:4, s. 6774-6786
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Tidskriftsartikel (refereegranskat)abstract
- Multiscale carbon supraparticles (SPs) are synthesized by soft-templating lignin nano- and microbeads bound with cellulose nanofibrils (CNFs). The interparticle connectivity and nanoscale network in the SPs are studied after oxidative thermostabilization of the lignin/CNF constructs. The carbon SPs are formed by controlled sintering during carbonization and develop high mechanical strength (58 N.mm(-3)) and surface area (1152 m(2). g(-1)). Given their features, the carbon SPs offer hierarchical access to adsorption sites that are well suited for CO2 capture (77 mg CO2.g(-1)), while presenting a relatively low pressure drop (similar to 33 kPa.m(-1) calculated for a packed fixed-bed column). The introduced lignin-derived SPs address the limitations associated with mass transport (diffusion of adsorbates within channels) and kinetics of systems that are otherwise based on nanoparticles. Moreover, the carbon SPs do not require doping with heteroatoms (as tested for N) for effective CO2 uptake (at 1 bar CO2 and 40 degrees C) and are suitable for regeneration, following multiple adsorption/desorption cycles. Overall, we demonstrate porous SP carbon systems of low cost (precursor, fabrication, and processing) and superior activity (gas sorption and capture).
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