| 1. |
- Claesson, Lillemor, 1976-
(författare)
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Fluid-rock interaction in two seismically active areas : The Tjörnes Fracture Zone, northern Iceland and the Shillong Plateau, northeastern India
- 2007
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Hydrogeochemical monitoring can improve our understanding of fluid-rock interaction, and may detect anomalies that are precursory to- or caused by- earthquakes. In this study, hydrogeochemical monitoring was carried out in two distinct tectonic settings, to study coupling between hydrogeochemical changes and seismic activity. The Tjörnes Fracture Zone, north Iceland (HU-01), and the Shillong Plateau, northeastern India (Silver Drop), are two seismically active areas with differing geology. Hydrogeochemical monitoring included regular groundwater sampling with subsequent major and trace element analysis and supporting stable isotope analysis at HU-01 only. Transition metal concentrations anomalies were detected at HU-01 prior to a MW 5.8 earthquake. Concentration increases of many major elements were detected after this earthquake. Hydrogeochemical recovery took place during the subsequent two years. The preseismic anomalies are interpreted as the result of increased fluid-rock interaction due to preseismic fracturing whereas the postseismic changes are attributed to source switching and/or mixing of fluids enabled by fault unsealing. The two-year recovery is probably related to the gradual sealing off of a fluid source. Pre- and post-seismic hydrogeochemical shifts (e.g. Na/Si, Ba/Sr) were detected at Silver Drop coinciding with two MW > 5 earthquakes. These shifts are likely due to changes in the type of feldspar weathering. A basalt dissolution experiment was carried out in order to understand the preseismic changes at HU-01. Rates and dissolution mechanisms interpreted from this experiment confirm that the metal anomalies at HU-01 could be induced by transient exposure of weakly altered basalt to groundwater interaction caused by microfracturing. Finally, from this study it can be concluded that a seismic event need not cause a hydrogeochemical shift, but a hydrogeochemical shift was always associated with a seismic event.
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| 2. |
- Claesson, Lillemor, et al.
(författare)
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The timescale and mechanisms of fault sealing and water-rock interaction after an earthquake
- 2007
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Ingår i: Geofluids. ; 7, s. 427-440
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Tidskriftsartikel (populärvet., debatt m.m.)abstract
- Hydrogeochemical monitoring of a basalt-hosted aquifer, which contains Ice Age meteoric water and is situatedat 1220 m below sea level in the Tjornes Fracture Zone, northern Iceland, has been ongoing since July 2002.Based on hydrogeochemical changes following an earthquake of magnitude (Mw) 5.8 on 16 September 2002, weconstrained the timescales of post-seismic fault sealing and water–rock interaction. We interpret that the earthquakeruptured a hydrological barrier, permitting a rapid influx of chemically and isotopically distinct Ice Agemeteoric water from a second aquifer. During the two subsequent years, we monitored a chemical and isotopicrecovery towards pre-earthquake aquifer compositions, which we interpret to have been mainly facilitated byfault-sealing processes. This recovery was interrupted in November 2004 by a second rupturing event, which wasprobably induced by two minor earthquakes and which reopened the pathway to the second aquifer. We concludethat the timescale of fault sealing was approximately 2 years and that the approach to isotopic equilibrium(from global meteoric water line) was approximately 18% after >10^4 years. Key words: earthquake, fault sealing, hydrogeochemistry, Iceland, Tjornes Fracture Zone, water–rock interaction
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| 3. |
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| 4. |
- Eliaeson, Karin, et al.
(författare)
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Relationships of geochemistry and multiple sclerosis
- 2009
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Rapport (övrigt vetenskapligt/konstnärligt)abstract
- The main aim of this study has been to investigate how registers and databases of geochemistry can be combined with registers of patient data in epidemiological studies. By testing the hypothesis that Multiple Sclerosis (MS) varies with geography and investigating if the variation can be explained by natural variability of zinc in different media, difficulties have been identified and recommendations for future epidemiological studies with similar scope are given. Multiple sclerosis (MS) is a chronic neurological illness that affects nerve cells in the central nervous system (CNS). It belongs to a group of illnesses called autoimmune diseases where the immune system attacks the body's own tissue. The onset of autoimmune reactions is not fully understood. Autoimmune diseases are believed to be multifactorial where both intrinsic factors (e.g. genetics, age, hormones) and environmental factors (e.g. infections, diet, drugs, chemicals etc.) may contribute to the induction, development and progression of the disease. There is a general believe that the epidemiological pattern of MS vary with geography, but even though the systematic study of MS started in 1929 the comparison of prevalence studies over the world still is very difficult and the results are not reliable. Iron, zinc, manganese, copper and molybdenum are examples of important building blocks for almost all living organisms and are thus termed essential elements. They originally derive from the Earth's crust and are taken up in organisms from soil, air and water. For some metals, no biological, nutritional or biochemical function has been established (yet) and they are thus termed non-essentials. The level of exposure to essential and non-essential elements is of crucial importance for the effect on living organisms. A too high dose can be toxic while a too low dose of essential elements will cause deficiency and consequent higher vulnerability for the exposure to toxic compounds or non-essential elements. In this study we have initially focused to check if the occurrence of MS could be correlated to background levels of zinc (Zn) since zinc is an element that participates in several important reactions in the body. We used the Swedish MS-register, which includes almost all MS-patients in Sweden. The best resolution on where the patients live is given on post code areas. Spatially distributed census data over postcode areas, valid for December 2005 and compiled by Official Statistics of Sweden, Statistics Sweden (SCB), were used in this study. Geochemical data from soil (till), stream-water and groundwater from the Swedish Geological Survey have been compiled into postcode areas. The analyzed data on the distribution of MS-patients indicate that a geographical pattern could be found with higher prevalence of MS in the county of Västerbotten and clusters around larges cities. No north -south or east-west gradient of the prevalence was found. However, visual interpretation of prevalence measures is strongly biased towards large post code areas, masking the variation of prevalence measures of small areas. This effect is striking in larger cities always having a large number of small post code areas. Combination of the patient registers and the geochemical registers was evaluated with multivariate analysis (MVA) and as a univariate study for zinc solely, but no correlation between the prevalence of MS and the occurrence of natural background levels of elements were found. Registers were analyzed both separately and together, but none of these models increased the degree to which variance was explained. This does not mean that no relationship between MS and geochemistry is possible but that correlations could not be found with the data, methods and models used in this project. The most important conclusion from this study is that to combine patient data with any kind of exposure data with a geographical variation, the administrative division (i.e. parishes, post code areas etc) are less appropriate. Divisions with respect to natural (geographical) borders such as catchment areas would be more useful for epidemiological purposes where a geographic component is of interest. To fulfil this, population data for catchment areas is needed. The density of the patient data and the exposure data is also of crucial importance. Moreover, there must be a variation in the exposure data large enough to result in a difference between areas. It is recommended that also the areas where no disease is found to be included in epidemiological studies. In these regions high or low levels of elements can also be present. The use of average values over districts is problematic. A high density of sampling in an area does not necessarily mean that the calculated mean value is representative for the whole area. How well an average value for a district describes the actual value depends both on the natural variability of substances in the media as well as the sampling density (i.e. high variance but many samples could give the same average value as low variance and few samples).
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| 5. |
- Engström, Anna, 1975-
(författare)
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Deformation and fluid-flow in magma-poor margins : A study of the Tasna Ocean-Continent transition, SE Switzerland
- 2006
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- In this study, interaction between fluids and deformation during the final stages of magma-poor rifting was investigated. The Tasna Ocean-Continent transition, located in the Swiss Alps, was studied and a large data set was obtained from profiles oriented perpendicular to two detachment faults. One of these juxtaposed serpentinized mantle against continental crust and the other exhumed both mantle and continental crust to the seafloor. Deformation associated with detachment faulting showed many common features but also some phenomena which were unique to each fault, confirming their sequential activity and differing roles in the exhumation process. Oxygen isotopes indicated the presence of both pervasive and channeled fluid phases, either accompanying or post-dating serpentinization. Deformation in the fault zone occurred in previously serpentinized mantle indicating that serpentinization pre-dated final exhumation. Most strain localization and displacement occurred in fault cores which are narrow zones beneath the detachments. These are underlain by wide zones characterized by more distributed strain. Transitional fabrics as well as reactivated and/or overprinted deformation structures indicated that the final phase of rifting is complex. Fault cores acted as fluid conduits or barriers. Thus, the most deformed zones may become the least permeable. Hence the coupling between deformation and fluid flow is complex in a study area subjected to several phases of deformation and fluid flow. Finally the importance of serpentinization in the evolution of magma-poor rifting was investigated. It was found that serpentinization is the consequence rather than the reason for strain localization at magma-poor margins. However, serpentinization may be an important process which can accelerate exhumation rates in the very latest stages of magma-poor rifting. The pre-existing deformation history of the crust may also be of importance for the development and location of margins.
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| 6. |
- Engström, Anna, et al.
(författare)
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Isotopic and petrological evidence of fluid-rock interaction at a Tethyan ocean-continent transition in the Alps : implications for tectonic processes and carbon transferduring early ocean formation
- 2007
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Ingår i: Geofluids. - : Wiley. - 1468-8115 .- 1468-8123. ; 7:4, s. 401-414
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Tidskriftsartikel (refereegranskat)abstract
- We report overprinting stable isotope evidence of fluid–rock interaction below two detachment faults along which mantle rocks were exhumed to the seafloor, between the respective landward and seaward limits of oceanic and continental crust, at a Tethyan ocean–continent transition (OCT). This OCT, which is presently exposed in the Tasna nappe (south-eastern Switzerland) is considered an on-land analogue of the well-studied Iberian OCT. We compare our results with the fault architecture (fault core–damage zone–protolith) described by Caine et al. [Geology (1996) Vol. 24, pp. 1025–1028]. We confirm the existence of a sharp boundary between the fault core and damage zone based on isotopic data, but the boundary between the damage zone and protolith is gradational. We identify evidence for: (1) pervasive isotopic modification to 8.4 ± 0.1‰ which accompanied or post-dated serpentinization of these mantle rocks at an estimated temperature of 67–109°C, (2) either (i) partial isolation of some highly strained regions [fault core(s) and mylonite] from this pervasive isotopic modification, because of permeability reduction (Caine et al.) or (ii) subsequent isotopic modification caused by structurally channelled flow of warm fluids within these highly strained regions, because of permeability enhancement, and (3) isotopic modification, which is associated with extensive calcification at T = 54–100°C, primarily beneath the younger of the two detachment faults and post-dating initial serpentinization. By comparing the volumetric extent of calcification with an experimentally verified model for calcite precipitation in veins, we conclude that calcification could have occurred in response to seawater infiltration, with a calculated flux rate of 0.1–0.2 m year−1 and a minimum duration of 0.2–4.0 × 104 years. The associated time-averaged uptake flux of carbon during this period was 8–120 mol m−2 year−1. By comparison with the estimated area of exhumed mantle rocks at the Iberian OCT, we calculate a maximum annual uptake flux for carbon of 2–30 Tg year−1. This is an order of magnitude greater than that for carbon exchange at the mid-ocean ridges and 0.1–1.4% of the global oceanic uptake flux for carbon.
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| 7. |
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| 8. |
- Hode Vuorinen, Jaana, 1974-
(författare)
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The Alnö alkaline and carbonatitic complex, east central Sweden - a petrogenetic study
- 2005
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- The Alnö complex on the central Swedish east coast is composed of a main composite intrusion (the main intrusion) and four smaller satellite intrusions (Söråker, Sälskär, Långharsholmen and Båräng) distributed around the main intrusion on Alnö Island and on the mainland north of the island. The major rock types exposed within the complex are melilitolite, pyroxenite, ijolite series (melteigite-ijolite-urtite), nepheline syenite, carbonatite and alnöite dykes. Melilitolite is only exposed within the Söråker intrusion. The intrusive sequence is melilitolite → pyroxenite → ijolite series → nepheline syenite → carbonatite → alnöite.Mineralogical, whole rock geochemical and radiogenic isotope (Nd-Sr-Pb) studies of exposed rocks from the Alnö alkaline complex, east central Sweden, were performed in order to investigate the genetic relationships between the diverse rock-types, and to evaluate the contributions from mantle and crustal components in the genesis of the complex. Most analysed samples fall within the depleted quadrant in a eNd-eSr diagram, similar to carbonatites and alkaline silicate rocks from other complexes, indicating derivation of parental magma(s) from a source that had experienced time-integrated depletion in LIL elements. Contamination by local crust is indicated by Sr and Pb isotope data, but is geographically restricted to samples collected from the outer parts of the main intrusion and from satellite intrusions. This localized contamination is attributed to selective hydrothermal element leaching of surrounding bedrock during fenitization. Nd- and Sr-isotope data separates the carbonatites into two groups (group I and II), each related to a specific set of silicate rock types. The overlap of group II carbonatites with ijolite and nepheline syenite could indicate a common origin through liquid immiscibility but this hypothesis cannot be confirmed by trace element data because initial concentrations are obscured by fractionation processes. Interestingly, results from AFC-modelling suggest that production of ijolite residual magma requires addition of a small volume (2.4 %) of carbonatite component to the parental magma, whereas formation of nepheline syenite residuals requires removal of an almost equal amount of carbonatite (1.5 %) to yield a statistically significant result. AFC-modelling further suggests that the various silicate rock types exposed within the complex are related to the same parental olivine-melilitite magma through crystal fractionation of olivine, melilite, clinopyroxene, nepheline, Ti-andradite and minor phases. These results agree with compositional trends exhibited by clinopyroxene and Ti-andradite from the silicate rocks of the main intrusion, which suggests co-genesis of pyroxenite, ijolite series rocks and nepheline syenite. Production of ijolite-like residual liquids can be achieved by <40% fractionation whereas production of nepheline syenite residuals requires >80% fractionation.An investigation of the origin of silicate minerals in carbonatites suggest that most silicate minerals observed in the carbonatites on Alnö Island are derived from surrounding wall-rock and/or produced through corrosive interaction between carbonatite liquid and assimilated phases. This leads to ambiguities when addressing the possible genetic link between carbonatites and associated silicate rocks as occurrences of identical “liquidus” phases in inferred immiscible liquids may not actually be such.
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| 9. |
- Mård Karlsson, Johanna, 1979-, et al.
(författare)
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Reconstructions of the coastal impact of the 2004 Indian Ocean tsunami in the Khao Lak area, Thailand
- 2009
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Ingår i: Journal of Geophysical Research. - 0148-0227 .- 2156-2202. ; 114, s. C10023-
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Tidskriftsartikel (refereegranskat)abstract
- Khao Lak, SW Thailand was severely affected by the tsunami on 26 December 2004. Here we present reconstructions of its coastal impact in this area. These are based on (1) eyewitness reports alone and (2) eyewitness reports supported by videos and photos of the tsunami and the damage it caused, field measurements, and satellite imagery. On the basis of eyewitness reports, we estimated that the sea began retreating at 1000 local time (LT) and, based also on photos, that the tsunami arrived at 1026-1029 LT. On the basis of videos of the tsunami, we estimated an offshore wave direction of 083 +/- 3 degrees and on the basis of the paths by which eyewitnesses were carried, we estimated an onshore direction of 088 +/- 6 degrees. On the basis of videos, we calculated that the velocity of the wavefront on its final approach was 33 +/- 4 km/h. We obtained tsunami heights of 7.3 +/- 0.8 m (relative to ground level) on the basis of eyewitness reports and 8.0 +/- 0.6 m (relative to mean sea level) on the basis of field and photographic data. On the basis of eyewitness reports and photos, we concluded that Khao Lak experienced at least two main waves with a period >40 min. From eyewitness reports and satellite imagery, we measured maximum inundation <= 0.5 km in the southern part of the area, which is confined by a steeply sloping hinterland, and <= 1.5 km in the more gently sloping northern part. Comparison between these reconstructions supports the reliability of eyewitness reports as a source of quantitative data, and comparison with the numerical simulation by Ioualalen et al. (2007) supports the validity of the simulation.
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| 10. |
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