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- Langa, Malose M., et al.
(author)
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Chromite chemistry of a massive chromitite seam in the northern limb of the Bushveld Igneous Complex, South Africa: correlation with the UG-2 in the eastern and western limbs and evidence of variable assimilation of footwall rocks
- 2021
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In: Mineralium Deposita. - : Springer Science and Business Media LLC. - 0026-4598 .- 1432-1866. ; 56:1, s. 31-44
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Journal article (peer-reviewed)abstract
- The Bushveld Igneous Complex (BIC) is known for its laterally extensive platinum group element–bearing layers, the most famous being the Merensky Reef and the UG-2 chromitite in the eastern and western limbs of the complex. In the northern limb, the Platreef mineralization and a thick chromitite seam below it (referred to as the “UG-2 equivalent” or UG-2E) have been proposed to be the stratigraphic equivalents of the Merensky Reef and the UG-2, respectively. In this study, we compare a suite of UG-2E samples from the Turfspruit project with a UG-2 reference suite from the western limb using petrography, electron probe microanalysis, laser ablation-inductively coupled plasma-mass spectrometry, and Mössbauer spectroscopy. The results show that (a) in Mg# vs. Cr# diagrams, UG-2E chromites have a distinct compositional field; however, when samples of similar chromite modal abundance (≥ 80%) are used, the UG-2E chromites overlap the field that characterizes UG-2 chromites; (b) the UG-2E is more variable in chromite modal abundance than the UG-2; and (c) variations in Mg# and Fe3+/ΣFe in the UG-2E indicate contamination of the magma by metasedimentary rocks of the Duitschland Formation (Transvaal Supergroup) during emplacement, followed by partial re-equilibration of chromite grains with a trapped melt. Thus, we conclude that for chromite modes higher than 80%, the chromite composition retains enough information to allow correlation and that the UG-2E in the northern limb is very likely the UG-2 chromitite.
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| 2. |
- Lenaz, Davide, et al.
(author)
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The Effects of High-Grade Metamorphism on Cr-Spinel from the Archean Sittampundi Complex, South India
- 2021
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In: Minerals. - : MDPI AG. - 2075-163X. ; 11:12, s. 1-13
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Journal article (peer-reviewed)abstract
- We investigated the crystal and structural behavior of Cr-bearing spinels from the Archean chromitites of Sittampundi (India), which had been subjected to very high-grade metamorphism. The structural data show that their oxygen positional parameters are among the highest ever recorded for Cr-bearing spinels with similar Cr# and Mg# and very similar to those found for other Archean occurrences. The general agreement between electron microprobe and Mössbauer data indicates that the analyzed spinels are stoichiometric. It is therefore most likely that the PH2O and Ptotal values as well as both the oxygen fugacity and the temperature reached during high-grade metamorphism inhibited the possibility of the non-stoichiometry of chromites, contrary to what can happen in ophiolites, where non-stoichiometry has recently been documented.
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| 4. |
- Schmiedel, Tobias, et al.
(author)
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Emplacement and Segment Geometry of Large, High-Viscosity Magmatic Sheets
- 2021
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In: Minerals. - : MDPI AG. - 2075-163X. ; 11:10
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Journal article (peer-reviewed)abstract
- Understanding magma transport in sheet intrusions is crucial to interpreting volcanic unrest. Studies of dyke emplacement and geometry focus predominantly on low-viscosity, mafic dykes. Here, we present an in-depth study of two high-viscosity dykes (106 Pa·s) in the Chachahuén volcano, Argentina, the Great Dyke and the Sosa Dyke. To quantify dyke geometries, magma flow indicators, and magma viscosity, we combine photogrammetry, microstructural analysis, igneous petrology, Fourier-Transform-Infrared-Spectroscopy, and Anisotropy of Magnetic Susceptibility (AMS). Our results show that the dykes consist of 3 to 8 mappable segments up to 2 km long. Segments often end in a bifurcation, and segment tips are predominantly oval, but elliptical tips occur in the outermost segments of the Great Dyke. Furthermore, variations in host rocks have no observable impact on dyke geometry. AMS fabrics and other flow indicators in the Sosa Dyke show lateral magma flow in contrast to the vertical flow suggested by the segment geometries. A comparison with segment geometries of low-viscosity dykes shows that our high-viscosity dykes follow the same geometrical trend. In fact, the data compilation supports that dyke segment and tip geometries reflect different stages in dyke emplacement, questioning the current usage for final sheet geometries as proxies for emplacement mechanism.
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