| 1. |
- Baresel, Christian, et al.
(författare)
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Functionalized magnetic particles for water treatment
- 2019
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Ingår i: Heliyon. - : Elsevier BV. - 2405-8440. ; 5:8
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Tidskriftsartikel (refereegranskat)abstract
- In this study, we have taken the concept of water treatment by functionalized magnetic particles one step forward by integrating the technology into a complete proof of concept, which included the preparation of surface modified beads, their use as highly selective absorbents for heavy metals ions (Zinc, Nickel), and their performance in terms of magnetic separation. The separation characteristics were studied both through experiments and by simulations. The data gathered from these experimental works enabled the elaboration of various scenarios for Life Cycle Analysis (LCA). The LCA showed that the environmental impact of the system is highly dependent on the recovery rate of the magnetic particles. The absolute impact on climate change varied significantly among the scenarios studied and the recovery rates. The results support the hypothesis that chelation specificity, magnetic separation and bead recovery should be optimized to specific targets and applications.
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| 2. |
- Bender, P., et al.
(författare)
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Structural and magnetic properties of multi-core nanoparticles analysed using a generalised numerical inversion method
- 2017
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Ingår i: Scientific Reports. - : Springer Science and Business Media LLC. - 2045-2322 .- 2045-2322. ; 7
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Tidskriftsartikel (refereegranskat)abstract
- The structural and magnetic properties of magnetic multi-core particles were determined by numerical inversion of small angle scattering and isothermal magnetisation data. The investigated particles consist of iron oxide nanoparticle cores (9 nm) embedded in poly(styrene) spheres (160 nm). A thorough physical characterisation of the particles included transmission electron microscopy, X-ray diffraction and asymmetrical flow field-flow fractionation. Their structure was ultimately disclosed by an indirect Fourier transform of static light scattering, small angle X-ray scattering and small angle neutron scattering data of the colloidal dispersion. The extracted pair distance distribution functions clearly indicated that the cores were mostly accumulated in the outer surface layers of the poly(styrene) spheres. To investigate the magnetic properties, the isothermal magnetisation curves of the multicore particles (immobilised and dispersed in water) were analysed. The study stands out by applying the same numerical approach to extract the apparent moment distributions of the particles as for the indirect Fourier transform. It could be shown that the main peak of the apparent moment distributions correlated to the expected intrinsic moment distribution of the cores. Additional peaks were observed which signaled deviations of the isothermal magnetisation behavior from the non-interacting case, indicating weak dipolar interactions.
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| 3. |
- Fall, Andreas, et al.
(författare)
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Hybrid Materials of Nanocellulose and Graphene
- 2019
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Ingår i: <em>International Conference on Nanotechnology for Renewable Materials 2019</em>. - : TAPPI Press. ; , s. 1069-1080
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Konferensbidrag (refereegranskat)
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| 4. |
- Gavilán, Helena, et al.
(författare)
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Colloidal Flower-Shaped Iron Oxide Nanoparticles : Synthesis Strategies and Coatings
- 2017
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Ingår i: Particle & particle systems characterization. - : Wiley. - 0934-0866 .- 1521-4117. ; 34:7
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Tidskriftsartikel (refereegranskat)abstract
- The assembly of magnetic cores into regular structures may notably influence the properties displayed by a magnetic colloid. Here, key synthesis parameters driving the self-assembly process capable of organizing colloidal magnetic cores into highly regular and reproducible multi-core nanoparticles are determined. In addition, a self-consistent picture that explains the collective magnetic properties exhibited by these complex assemblies is achieved through structural, colloidal, and magnetic means. For this purpose, different strategies to obtain flower-shaped iron oxide assemblies in the size range 25–100 nm are examined. The routes are based on the partial oxidation of Fe(OH)2, polyol-mediated synthesis or the reduction of iron acetylacetonate. The nanoparticles are functionalized either with dextran, citric acid, or alternatively embedded in polystyrene and their long-term stability is assessed. The core size is measured, calculated, and modeled using both structural and magnetic means, while the Debye model and multi-core extended model are used to study interparticle interactions. This is the first step toward standardized protocols of synthesis and characterization of flower-shaped nanoparticles.
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| 5. |
- Lobov, Gleb, et al.
(författare)
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Dynamic manipulation of optical anisotropy of suspended Poly-3-hexylthiophene nanofibers
- 2016
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Ingår i: Advanced Optical Materials. - : Wiley. - 2162-7568 .- 2195-1071. ; 4:10, s. 1651-1656
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Tidskriftsartikel (refereegranskat)abstract
- Poly-3-hexylthiophene (P3HT) nanofibers are 1D crystalline semiconducting nanostructures, which are known for their application in photovoltaics. Due to the internal arrangement, P3HT nanofibers possess optical anisotropy, which can be enhanced on a macroscale if nanofibers are aligned. Alternating electric field, applied to a solution with dispersed nanofibers, causes their alignment and serves as a method to produce solid layers with ordered nanofibers. The transmission ellipsometry measurements demonstrate the dichroic absorption and birefringence of ordered nanofibers in a wide spectral range of 400–1700 nm. Moreover, the length of nanofibers has a crucial impact on their degree of alignment. Using electric birefringence technique, it is shown that external electric field applied to the solution with P3HT nanofibers can cause direct birefringence modulation. Dynamic alignment of dispersed nanofibers changes the refractive index of the solution and, therefore, the polarization of transmitted light. A reversible reorientation of nanofibers is organized by using a quadrupole configuration of poling electrodes. With further development, the described method can be used in the area of active optical fiber components, lab-on-chip or sensors. It also reveals the potential of 1D conducting polymeric structures as objects whose highly anisotropic properties can be implemented in electro-optical applications..
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| 6. |
- Lobov, Gleb, et al.
(författare)
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Optical birefringence from P3HT nanofibers in alternating electric field
- 2016
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Ingår i: Optics InfoBase Conference Papers. - : OSA - The Optical Society. - 9781943580194
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Konferensbidrag (refereegranskat)abstract
- AC poling allowing to control the orientation of P3HT nanofibers, result in strong optical birefringence with promising implementation in a novel type of optical modulator, without necessary embedding into any hosting matrix, e.g. liquid crystal.
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| 7. |
- Lobov, G. S., et al.
(författare)
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Direct birefringence and transmission modulation via dynamic alignment of P3HT nanofibers in an advanced opto-fluidic component
- 2017
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Ingår i: Optical Materials Express. - 2159-3930. ; 7:1, s. 52-61
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Tidskriftsartikel (refereegranskat)abstract
- Poly-3-hexylthiophene (P3HT) nanofibers are semiconducting high-aspect ratio nanostructures with anisotropic absorption and birefringence properties found at different regions of the optical spectrum. In addition, P3HT nanofibers possess an ability to be aligned by an external electric field, while being dispersed in a liquid. In this manuscript we show that such collective ordering of nanofibers, similar to liquid crystal material, significantly changes the properties of transmitted light. With a specially fabricated opto-fluidic component, we monitored the phase and transmission modulation of light propagating through the solution of P3HT nanofibers, being placed in the electric field with strength up to 0.1 V/μm. This report describes a technique for light modulation, which can be implemented in optical fiber-based devices or on-chip integrated components.
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| 8. |
- Lobov, Gleb S., et al.
(författare)
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Electric field induced optical anisotropy of P3HT nanofibers in a liquid solution
- 2015
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Ingår i: Optical Materials Express. - : Optical Society of America. - 2159-3930. ; 5:11, s. 2642-2647
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Tidskriftsartikel (refereegranskat)abstract
- The nanofiber morphology of regioregular Poly-3- hexylthiophene (P3HT) is a 1D crystalline structure organized by π - π stacking of the backbone chains. In this study, we report the impact of electric field on the orientation and optical properties of P3HT nanofibers dispersed in liquid solution. We demonstrate that alternating electric field aligns nanofibers, whereas static electric field forces them to migrate towards the cathode. The alignment of nanofibers introduces anisotropic optical properties, which can be dynamically manipulated until the solvent has evaporated. Time resolved spectroscopic measurements revealed that the electro-optical response time decreases significantly with the magnitude of applied electric field. Thus, for electric field 1.3 V ·μm-1 the response time was measured as low as 20 ms, while for 0.65 V ·μm-1 it was 110-150 ms. Observed phenomenon is the first mention of P3HT supramolecules associated with electrooptical effect. Proposed method provides real time control over the orientation of nanofibers, which is a starting point for a novel practical implementation. With further development P3HT nanofibers can be used individually as an anisotropic solution or as an active component in a guest-host system.
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| 9. |
- Lobov, Gleb S., et al.
(författare)
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Electro-optical response of P3HT nanofibers in liquid solution
- 2015
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Ingår i: Asia Communications and Photonics Conference 2015. - : Optical Society of America. - 9781943580064
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Konferensbidrag (refereegranskat)abstract
- AC electric poling introduces in P3HT nanofibers anisotropic electro-optical response and birefringence. Along with birefringence, such material exhibits strong amplitude modulation which makes it more efficient alternative to liquid crystals.
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| 10. |
- Lobov, Gleb S., et al.
(författare)
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Size Impact of Ordered P3HT Nanofibers on Optical Anisotropy
- 2016
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Ingår i: Macromolecular Chemistry and Physics. - : John Wiley & Sons. - 1022-1352 .- 1521-3935. ; 217:9, s. 1089-1095
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Tidskriftsartikel (refereegranskat)abstract
- Poly-3-hexylthiophene (P3HT) nanofibers are 1D crystalline structures with semiconductor properties. When P3HT nanofi bers are dispersed in nonconducting solvent, they react to external alternate electric field by aligning along the field lines. This can be used to create layers of ordered nanofi bers and is referred to as alternating current poling method. P3HT nanofi bers with three different size distributions are fabricated, using self-assembly mechanism in marginal solvents, and used for the alignment studies. Anisotropic absorption of oriented 2 mu m long nanofi bers exponentially increases with the magnitude of applied field to a certain asymptotic limit at 0.8 V mu m(-1), while 100-500 nm long nanofi bers respond to electric field negligibly. Effective optical birefringence of oriented 2 mu m long nanofi bers is calculated, based on the phase shift at 633 nm and the average layer thickness, to be 0.41. These results combined with further studies on real-time control over orientation of P3HT nanofi bers in liquid solution or host system are promising in terms of exploiting them in electroabsorptive and electrorefractive applications.
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