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- Hakonen, Aron, 1970, et al.
(författare)
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Dimer-on-mirror SERS substrates with attogram sensitivity fabricated by colloidal lithography.
- 2015
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Ingår i: Nanoscale. - : Royal Society of Chemistry (RSC). - 2040-3364 .- 2040-3372. ; 7:21
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Tidskriftsartikel (refereegranskat)abstract
- Nanoplasmonic substrates with optimized field-enhancement properties are a key component in the continued development of surface-enhanced Raman scattering (SERS) molecular analysis but are challenging to produce inexpensively in large scale. We used a facile and cost-effective bottom-up technique, colloidal hole-mask lithography, to produce macroscopic dimer-on-mirror gold nanostructures. The optimized structures exhibit excellent SERS performance, as exemplified by detection of 2.5 and 50 attograms of BPE, a common SERS probe, using Raman microscopy and a simple handheld device, respectively. The corresponding Raman enhancement factor is of the order 10(11), which compares favourably to previously reported record performance values.
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2. |
- Ogier, Robin, 1987, et al.
(författare)
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Near-Complete Photon Spin Selectivity in a Metasurface of Anisotropic Plasmonic Antennas
- 2015
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Ingår i: Physical Review X. - : American Physical Society. - 2160-3308. ; 5:4
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Tidskriftsartikel (refereegranskat)abstract
- Simple chiroptically active metamaterials are difficult to realize in practice but could pave the way for a range of important applications, such as sensitive optical biosensors, asymmetric catalysis, and novel polarization manipulation devices. We show that a metasurface based on a random arrangement of anisotropic but aligned gold nanoparticles can exhibit an almost perfect selectivity towards incident photon spin for evanescent excitation with visible to near-infrared light. The experimentally attained reflection contrast between left- and right-handed circularly polarized light peaks at similar to 90%, in excellent agreement with analytical theory. These results are important for the development of future photonic and plasmonic polarization-based technologies.
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