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Sökning: WFRF:(Tao Jian) > (2007-2009)

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1.
  • Clark, Andrew G., et al. (författare)
  • Evolution of genes and genomes on the Drosophila phylogeny
  • 2007
  • Ingår i: Nature. - : Springer Science and Business Media LLC. - 0028-0836 .- 1476-4687. ; 450:7167, s. 203-218
  • Tidskriftsartikel (refereegranskat)abstract
    • Comparative analysis of multiple genomes in a phylogenetic framework dramatically improves the precision and sensitivity of evolutionary inference, producing more robust results than single-genome analyses can provide. The genomes of 12 Drosophila species, ten of which are presented here for the first time (sechellia, simulans, yakuba, erecta, ananassae, persimilis, willistoni, mojavensis, virilis and grimshawi), illustrate how rates and patterns of sequence divergence across taxa can illuminate evolutionary processes on a genomic scale. These genome sequences augment the formidable genetic tools that have made Drosophila melanogaster a pre-eminent model for animal genetics, and will further catalyse fundamental research on mechanisms of development, cell biology, genetics, disease, neurobiology, behaviour, physiology and evolution. Despite remarkable similarities among these Drosophila species, we identified many putatively non-neutral changes in protein-coding genes, non-coding RNA genes, and cis-regulatory regions. These may prove to underlie differences in the ecology and behaviour of these diverse species.
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2.
  • Tian, Jian-jun, et al. (författare)
  • Influence of heat treatment on fracture and magnetic properties of radially oriented Sm 2 Co 17 permanent magnets
  • 2007
  • Ingår i: Transactions of Nonferrous Metals Society of China. - 1003-6326 .- 2210-3384. ; 17:3, s. 491-495
  • Tidskriftsartikel (refereegranskat)abstract
    • The quenching, fracture and aging treatment of radially oriented Sm2Co17 ring magnets were investigated. The results indicate that the ring magnets have obvious anisotropy of thermal expansion, which easily leads to the splits of the magnets during quenching. The fracture is brittle cleavage fracture. The difference (δa) of the expansion coefficient reaches the maximum value at 800–850 °C. So, various quenching processes at different steps are adopted in order to reduce the splits. When the magnets are aged. 1:5 phase precipitates from the 2:17 matrix phase and forms a cellular microstructure with 2:17 phase. BHmax and 3Hc reach the maximum value 226 kJ/m3 and 2170 kA/m after being aged at 850 °C for 4 h and 8 h, respectively. The aging treatment at 850 °C has little influence on remanence(Br), which can always keep a high value (≥1.0 T). Through appropriate heat treatment, the ring magnets have uniform cellular microstructure and excellent magnetic properties: Br1.0T, 3Hc≥2 100 kA/m, BHmax≥220 kJ/m3.
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3.
  • Zhao, Guang-Jiu, et al. (författare)
  • Photoinduced intramolecular charge transfer and S-2 fluorescence in thiophene-pi-conjugated donor-acceptor systems : Experimental and TDDFT studies
  • 2008
  • Ingår i: Chemistry - A European Journal. - : Wiley. - 0947-6539 .- 1521-3765. ; 14:23, s. 6935-6947
  • Tidskriftsartikel (refereegranskat)abstract
    • Experimental and theoretical methods were used to study newly synthesized thiophene-pi-cojugated donor-acceptor compounds, which were found to exhibit efficient intramolecular charge-transfer emission in polar solvents with relatively large Stokes shifts and strong solvatochromism. To gain insight into the solvatochromic behavior of these compounds, the dependence of the spectra on solvent polarity was studied on the basis of Lippert-Mataga models. We found that intramolecular charge transfer in these donor-acceptor systems is significantly dependent on the electron-with-drawing substituents at the thienyl 2-position. The dependence of the absorption and emission spectra of these compounds in methanol on the concentration of trifluoroacetic acid was used to confirm intramolecular charge-tranfer emission. Moreover, the calculated absorption and emission energies, which are in accordance with the experimental values, suggested that fluorescence can be emitted from different geometric confirmations. In addition, a novel S-2 fluorescence phenomenon for some of these compounds was also be observed. The fluorescence excitation spectra were used to confirm the S-2 fluorescence. We demonstrate that S-2 fluorescence can be explained by the calculated energy gap between the S-2 and S-1 states of these molecules. Furthermore, nonlinear optical behavior of the thiophene-pi-conjugated compound with diethylcyanomethylphosphonate substituents was predicted in theory.
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